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2017 Volume 11 Issue 9
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HUO Xiaonan, WANG Lei, ZHU Zhenya, JIANG Jialiang, LI Qingqing, XU Yawei. Modification of polyvinylidene fluoride composite membrane by graphene oxide and its antifouling properties[J]. Chinese Journal of Environmental Engineering, 2017, 11(9): 4923-4931. doi: 10.12030/j.cjee.201611077
Citation: HUO Xiaonan, WANG Lei, ZHU Zhenya, JIANG Jialiang, LI Qingqing, XU Yawei. Modification of polyvinylidene fluoride composite membrane by graphene oxide and its antifouling properties[J]. Chinese Journal of Environmental Engineering, 2017, 11(9): 4923-4931. doi: 10.12030/j.cjee.201611077
shu

Modification of polyvinylidene fluoride composite membrane by graphene oxide and its antifouling properties

  • 1.

    School of Environmental & Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China

  • 2.

    Key Laboratory of Membrane Separation of Shaanxi Province, Xi'an University of Architecture and Technology, Xi'an 710055, China

  • 3.

    School of Water Resources and Environment, Hebei GEO University, Shijiazhuang 050031, China

  • 4.

    Key Laboratory of Sustained Development and Utilization of Water Resources in Hebei Province, Shijiazhuang 050031, China

  • Received Date: 19/01/2017
    Accepted Date: 11/11/2016
    Available Online: 26/08/2017
    Fund Project:
  • The graphene oxide (GO) with two-dimensional structure was prepared through a modified Hummers' method.GO/PVP/PVDF composite ulrrafiltration(UF) membrane were prepared with polyvinylidene fluoride(PVDF),polyvinylpyrrolidone(PVP) and GO by general phase inversion method.The pure water flux,contact angle,pollutant rejection,SEM and AFM images,Zeta potential and interaction force between composite membrane and BSA were measured.Results show that with the increase of GO in the composite membrane,the content of hydrophilic functional groups in the composite membrane surface effectively increased,contact angle decreased from 74.61°(M0) to 66.39°(M2),while pure water flux increased by 33%.The image analyses by scanning electron microscopy (SEM) and atomic force microscopy (AFM) exhibited that the finger-like pores of the GO/PVP/PVDF membrane were broadened and surface roughness reduced from 23.79 (M0) to 20.2 (M3) with a smoother surface.Moreover,with the introducing of GO,the interaction force between composite membrane and BSA changed from 2.47 mN·m-1 to 0.13 mN·m-1.The results testify that GO/PVP/PVDF composite UF membrane has a superior antifouling propensities compared to traditional PVDF UF membrane.
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    1. 王成达，朱世东，赵乾臻，王国强. 氧化石墨烯改性聚偏氟乙烯分离膜的制备、性能及应用. 应用化工. 2024(04): 930-935 .
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Modification of polyvinylidene fluoride composite membrane by graphene oxide and its antifouling properties

  • Received Date: 19/01/2017
  • Accepted Date: 11/11/2016
  • Available Online: 26/08/2017
Fund Project:

Abstract: The graphene oxide (GO) with two-dimensional structure was prepared through a modified Hummers' method.GO/PVP/PVDF composite ulrrafiltration(UF) membrane were prepared with polyvinylidene fluoride(PVDF),polyvinylpyrrolidone(PVP) and GO by general phase inversion method.The pure water flux,contact angle,pollutant rejection,SEM and AFM images,Zeta potential and interaction force between composite membrane and BSA were measured.Results show that with the increase of GO in the composite membrane,the content of hydrophilic functional groups in the composite membrane surface effectively increased,contact angle decreased from 74.61°(M0) to 66.39°(M2),while pure water flux increased by 33%.The image analyses by scanning electron microscopy (SEM) and atomic force microscopy (AFM) exhibited that the finger-like pores of the GO/PVP/PVDF membrane were broadened and surface roughness reduced from 23.79 (M0) to 20.2 (M3) with a smoother surface.Moreover,with the introducing of GO,the interaction force between composite membrane and BSA changed from 2.47 mN·m-1 to 0.13 mN·m-1.The results testify that GO/PVP/PVDF composite UF membrane has a superior antifouling propensities compared to traditional PVDF UF membrane.

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