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固定化排硫硫杆菌对气体中H2S去除特性

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许海朋, 李岩, 牧辉, 金付强, 华栋梁, 陈冠益. 固定化排硫硫杆菌对气体中H2S去除特性[J]. 环境工程学报, 2018, 12(11): 3109-3115. doi: 10.12030/j.cjee.201806040
引用本文: 许海朋, 李岩, 牧辉, 金付强, 华栋梁, 陈冠益. 固定化排硫硫杆菌对气体中H2S去除特性[J]. 环境工程学报, 2018, 12(11): 3109-3115. doi: 10.12030/j.cjee.201806040
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XU Haipeng, LI Yan, MU Hui, JIN Fuqiang, HUA Dongliang, CHEN Guanyi. Removal of H2S by Tiobacillus thioparus immobilized on different matrices[J]. Chinese Journal of Environmental Engineering, 2018, 12(11): 3109-3115. doi: 10.12030/j.cjee.201806040
Citation: XU Haipeng, LI Yan, MU Hui, JIN Fuqiang, HUA Dongliang, CHEN Guanyi. Removal of H2S by Tiobacillus thioparus immobilized on different matrices[J]. Chinese Journal of Environmental Engineering, 2018, 12(11): 3109-3115. doi: 10.12030/j.cjee.201806040
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固定化排硫硫杆菌对气体中H2S去除特性

  • 1.

    天津大学环境科学与工程学院，天津 300072

  • 2.

    山东省科学院能源研究所，济南 250014

  • 基金项目:

    山东省重点研发计划（2016GSF117037）

    山东省科技发展计划项目（2017GSF17117）

Removal of H2S by Tiobacillus thioparus immobilized on different matrices

  • 1.

    School of Environment Science and Engineering,Tianjin University, Tianjin 300072,China

  • 2.

    Energy Research Institute of Shandong Academy of Sciences, Jinan 250014,China

  • Fund Project:

  • 摘要: 为提高生物滴滤塔净化气体中H2S的运行效率，分别采用活性炭、陶粒、聚丙烯空心球3种填料，以排硫硫杆菌（Tiobacillus thioparus）接种生物滴滤塔处理含H2S气体，研究了进气H2S浓度、气体停留时间等参数对生物滴滤塔去除H2S性能的影响。结果表明，采用排硫硫杆菌接种生物滴滤塔处理含H2S气体，挂膜速度快，系统运行稳定且脱硫效率高。3种填料中活性炭填料脱硫效果最好，固定进气H2S浓度1.5 g·m-3，停留时间高于23 s时，H2S去除率可以达到94.4%以上，H2S去除负荷达333.16 g·（m3·h）-1。动力学分析表明，活性炭生物滴滤塔最大H2S去除负荷为666.7 g·（m3·h）-1，饱和常数为0.87 g·m-3。随着实验的进行，填料塔的压力降会因为生物膜的生长和单质硫的积累逐渐增加，严重时导致气体完全堵塞，需要进行鼓泡反冲以除去积累的单质硫。
    Abstract: A biotrickling filter system with Tiobacillus thioparus immobilized on the packing media, such as spherical active carbon, ceramsite or polypropylene hollow ball, was used to eliminate H2S from gas stream. In this study, the effects of inlet H2S concentration and retention time on the H2S removal efficiency were investigated. It was found that the biotrickling filter system inoculated with Tiobacillus thioparus showed rapid biofilm formation, stable operation and high H2S removal capacity. Among three kinds of packing media, the spherical active carbon provided the highest H2S removal capacity. At influent H2S concentration of 1.5 g·m-3 and the retention time of longer than 23 s, both the removal efficiency and load of H2S were above 94.4% and 333.16 g·(m3·h)-1, respectively. The kinetic analysis showed that the maximum removal load and saturation constant of the biotrickling filter system filled with active carbon were 666.7 g·(m3·h)-1 and 0.87 g·m-3, respectively. The biotrickling filter needs to be back washed when the bed pressure drop is too high due to the bacteria overgrowth and sulfur accumulation.
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  • [1] ROTH S H, SKRAJNY B, REIFFENSTEIN R J.Alteration of the morphology and neurochemistry of the developing mammalian nervous system hydrogen sulphide[J].Clinical and Experimental Pharmacology and Physiology,1995,22:379–380 10.1111/j.1440-1681.1995.tb02024.x
    [2] 苗茂谦，宋智杰，仪慧兰，等. 生物法处理含H2S气体的研究进展[J]. 化工进展,2009,28(8):1289-1295
    [3] 张雄军，彭书传，朱承驻，等. 铁氧化物多孔陶粒生物滴滤塔净化硫化氢气体[J]. 环境工程学报, 2015,9(2):841-846
    [4] SYED M， SOREANU G，FALLETTA P,et al.Removal of hydrogen sulfide from gas streams using biological processes:A review[J].Canadian Biosystems Engineering,2006,48:1-14
    [5] ABATZOGLOU N， BOIVIN S.A review of biogas purification processes[J].Biofuels Bioproducts & Biorefining,2009,3(1):42–71 10.1002/bbb.117
    [6] 邓良伟，唐一，吴彦. 生物脱硫机理及其研究进展[J]. 上海环境科学,1998,17(5):35-39
    [7] 陈益清，尹娟，蔡旺锋，等. 不同挂膜方式生物滴滤塔处理含H2S恶臭气体[J]. 环境工程学报,2014,8(2):647-651
    [8] POKORNA D， ZABRANSKA J.Sulfur-oxidizing bacteria in environmental technology[J].Biotechnology Advances,2015,33(6):1246-1259 10.1016/j.biotechadv.2015.02.007
    [9] 葛洁. 生物滴滤塔净化H2S气体的菌种筛选、填料改性及反应动力学分析[D]. 西安：西安建筑科技大学,2011
    [10] AROCA G，URRUTIA H，NUNEZ D.Comparison on the removal of hydrogen sulfide in biotrickling filters inoculated with Thiobacillus thioparus and Acidithiobacillus thiooxidans[J].Electronic Journal of Biotechnology,2007,10(4):514-520 10.4067/S0717-34582007000400005
    [11] JIN Y，VEIGA M C，KENNES C.Autotrophic deodorization of hydrogen sulfide in a biotrickling filter[J].Journal of Chemical Technology & Biotechnology,2010,80(9):998-1004 10.1002/jctb.1275
    [12] 李亚新，储江林，池勇志. 无色硫细菌氧化SRB还原硫酸盐产物硫化氢生成单质硫[J]. 城市环境与城市生态,2002,15(5):4-7
    [13] KIMBERLEY T, VIKRAMA B, MEHDI N.Bacteria of the sulphur cycle: An overview of microbiology,biokinetics and their role in petroleum and mining industries[J].Biochemical Engineering Journal,2009,44:73–94 10.1016/j.bej.2008.12.011
    [14] LEE E Y，LEE N Y，CHO K S，et al.Removal of hydrogen sulfide by sulfate-resistant Acidithiobacillus thiooxidans AZ11[J].Journal of Bioscience & Bioengineering,2006,101(4):309-314 10.1263/jbb.101.309
    [15] RATTANAPAN C，BOONSAWANG P，KANTACHOTE D.Removal of H2S in down-flow GAC biofiltration using sulfide oxidizing bacteria from concentrated latex wastewater[J].Bioresource Technology,2009,100(1):125-130 10.1016/j.biortech.2008.05.049.
    [16] 陈益清，陈雷，伍健威，等. 填料对生物滴滤塔去除H2S的影响[J]. 环境工程学报,2016,10(7):3763-3767
    [17] 钱东升，房俊逸，陈东之，等. 板式生物滴滤塔高效净化硫化氢废气的研究[J]. 环境科学,2011,32(9):2786-2793
    [18] 陈雷，陈益清，李文龙，等. 喷淋条件对生物滴滤塔去除含H2S废气的影响[J]. 环境工程学报,2016,10(12):7168-7172 10.12030/j.cjee.201507093
    [19] 马艳玲. 固定化脱氮硫杆菌脱除硫化氢废气的研究[D]. 西安：西安交通大学,2006
    [20] OTTENGRAF S P, VAN DEN OERER A H.Kinetics of organic compound removal from waste gases with a biological filter[J].Biotechnology and Bioengineering,1983,25(12):3089–3102 10.1002/bit.260251222
    [21] WANI A H, LAU A K, BRANION R M.Biofiltration control of pulping odors-hydrogen sulfide: Performance,macrokinetics and coexistence effects of organo-sulfur species[J].Journal of Chemical Technology and Biotechnology,1999,74:9-16 10.1002/(SICI)1097-4660(199901)74:1<9::AID-JCTB981>3.0.CO;2-B
    [22] MA Y L，YANG B L，ZHAO J L.Removal of H2S by Thiobacillus denitrificans immobilized on different matrices[J].Bioresource Technology,2006,97(16):2041-2046 10.1016/j.biortech.2005.09.023
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  • 刊出日期:  2018-11-12

固定化排硫硫杆菌对气体中H2S去除特性

  • 1. 天津大学环境科学与工程学院，天津 300072
  • 2. 山东省科学院能源研究所，济南 250014
基金项目:

山东省重点研发计划（2016GSF117037）

山东省科技发展计划项目（2017GSF17117）

摘要: 为提高生物滴滤塔净化气体中H2S的运行效率，分别采用活性炭、陶粒、聚丙烯空心球3种填料，以排硫硫杆菌（Tiobacillus thioparus）接种生物滴滤塔处理含H2S气体，研究了进气H2S浓度、气体停留时间等参数对生物滴滤塔去除H2S性能的影响。结果表明，采用排硫硫杆菌接种生物滴滤塔处理含H2S气体，挂膜速度快，系统运行稳定且脱硫效率高。3种填料中活性炭填料脱硫效果最好，固定进气H2S浓度1.5 g·m-3，停留时间高于23 s时，H2S去除率可以达到94.4%以上，H2S去除负荷达333.16 g·（m3·h）-1。动力学分析表明，活性炭生物滴滤塔最大H2S去除负荷为666.7 g·（m3·h）-1，饱和常数为0.87 g·m-3。随着实验的进行，填料塔的压力降会因为生物膜的生长和单质硫的积累逐渐增加，严重时导致气体完全堵塞，需要进行鼓泡反冲以除去积累的单质硫。

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