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石墨烯复合改性海绵的制备及其吸油性能

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杜国勇, 朱成旺, 曾文强, 任燕玲, 蒋昕, 郑惠芸, 蒋小萍. 石墨烯复合改性海绵的制备及其吸油性能[J]. 环境工程学报, 2018, 12(3): 741-750. doi: 10.12030/j.cjee.201709029
引用本文: 杜国勇, 朱成旺, 曾文强, 任燕玲, 蒋昕, 郑惠芸, 蒋小萍. 石墨烯复合改性海绵的制备及其吸油性能[J]. 环境工程学报, 2018, 12(3): 741-750. doi: 10.12030/j.cjee.201709029
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DU Guoyong, ZHU Chengwang, ZENG Wenqiang, REN Yanling, JIANG Xin, ZHENG Huiyun, JIANG Xiaoping. Preparation and oil absorption properties of graphene composite modified sponge[J]. Chinese Journal of Environmental Engineering, 2018, 12(3): 741-750. doi: 10.12030/j.cjee.201709029
Citation: DU Guoyong, ZHU Chengwang, ZENG Wenqiang, REN Yanling, JIANG Xin, ZHENG Huiyun, JIANG Xiaoping. Preparation and oil absorption properties of graphene composite modified sponge[J]. Chinese Journal of Environmental Engineering, 2018, 12(3): 741-750. doi: 10.12030/j.cjee.201709029
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石墨烯复合改性海绵的制备及其吸油性能

  • 1.

    西南石油大学化学化工学院，成都 610500

  • 2.

    川庆钻探工程有限公司安全环保质量监督检测研究院，广汉 618300

  • 基金项目:

    国家科技重大专项课题“废弃物处理与利用技术”（2016ZX05040-003）

Preparation and oil absorption properties of graphene composite modified sponge

  • 1.

    School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China

  • 2.

    Supervision and Testing Institute for Safety and Environment and Quality, Chuanqing Drilling Engineering Co.Ltd.， Guanghan 618300, China

  • Fund Project:

  • 摘要: 将三聚氰胺海绵（MF）浸入氧化石墨烯（GO）悬浮液，经微波溶剂热还原反应后，用聚二甲基硅氧烷（PDMS）进一步修饰，得到超疏水亲油的石墨烯复合改性吸油海绵（rGO-PDMS-MF）。优化了GO和PDMS改性试剂的浓度，通过扫描电子显微镜（SEM）、傅里叶变换红外光谱仪（FTIR）及接触角（CA）测定仪对海绵结构和性质进行了表征，测试了海绵的饱和吸油性能、重复使用性能及油水分离性能。结果表明：GO悬浮液和PDMS溶液最适浓度分别为2.0 g·L-1和1.0%（质量分数）；所得海绵的接触角达151.5°，饱和吸油能力达45~110 g·g-1，可通过吸附-挤压方式重复使用10次以上；rGO-PDMS-MF海绵对油水体系具有良好的选择性，与泵装置结合后可以连续有效地将油从水面分离，再生使用后仍保持较高的浮油回收速率和较强的疏水性能。
    Abstract: The melamine sponge (MF) was immersed into graphene oxide (GO) suspension and modified further by polydimethylsiloxane (PDMS) after a microwave solvothermal reduction to prepare the superhydrophobic and lipophilic graphene composite modified sponge (rGO-PDMS-MF). The concentration of the GO and PDMS modified reagents were optimized, the structure and property of the sponge were characterized by scanning electron microscopy (SEM), fourier transform infrared spectrometer (FTIR) and contact-angle (CA) meter. The saturated absorption capacity, recyclability and oil/water separation capability of the rGO-PDMS-MF sponge were also tested. The results indicated that the optimum concentrations of the GO suspension and PDMS solution were 2.0 g·L-1 and 1.0% (mass fraction), respectively. The contact angle of the fabricated sponge was 151.5°, the saturated absorption capacity of the oils was ranged from 45 to 110 g·g-1, and it could be reused more than 10 times via absorption/squeezing processes. The rGO-PDMS-MF sponge possessed a good selectivity of the oil-water system, remarkably, the pumping device based on the sponge could collect the oil from a water surface in an efficient and continuous way, and the sponge still remained a high oil recovery rate and a strong hydrophobic property.
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  • [1] CHROPE M.Oil spill: Deep wounds[J].Nature News,2011,472(7342):152-154 10.1038/472152a
    [2] SCHROPE M.Deepwater horizon: A scientist at the centre of the spill[J].Nature News,2010,466(7307):680-684 10.1038/466680a
    [3] GUPTA S, TAI N H.Carbon materials as oil sorbents: A review on the synthesis and performance[J].Journal of Materials Chemistry A,2016,4(5):1550-1565 10.1039/C5TA08321D
    [4] 王文华, 邱金泉, 寇希元, 等. 吸油材料在海洋溢油处理中的应用研究进展[J]. 化工新型材料,2013,41(7):151-154 10.3969/j.issn.1006-3536.2013.07.051
    [5] KELLER A A, BROJE V.Improved mechanical oil spill recovery using an optimized geometry for the skimmer surface[J].Environmental Science & Technology,2006,40(24):7914-7918 10.1021/es061842m
    [6] CHAPMAN H, PURNELL K, LAW R J, et al.The use of chemical dispersants to combat oil spills at sea: A review of practice and research needs in Europe[J].Marine Pollution Bulletin,2007,54(7):827-838 10.1016/j.marpolbul.2007.03.012
    [7] GE J, YE Y D, YAO H B, et al.Pumping through porous hydrophobic/oleophilic materials: An alternative technology for oil spill remediation[J].Angewandte Chemie,2014,126(14):3686-3690 10.1002/anie.201310151
    [8] GUO J, WANG J, ZHANG S, et al.One-step modification of PU sponges for selective absorption of oil–water mixtures[J].New Journal of Chemistry,2017,41(1):90-96 10.1039/C6NJ03239G
    [9] MARGESIN R, SCHINNER F.Biodegradation and bioremediation of hydrocarbons in extreme environments[J].Applied Microbiology and Biotechnology,2001,56(5):650-663 10.1007/s002530100701
    [10] 刘生鹏, 高秋, 胡仙林, 等. 吸油材料的研究进展[J]. 武汉工程大学学报,2013,35(12):27-34 10.3969/j.issn.1674-2869.2013.12.006
    [11] LI X Y, XUE Y Y, ZOU M C, et al.Direct oil recovery from saturated carbon nanotube sponges[J].ACS Applied Materials & Interfaces,2016,8(19):12337-12343 10.1021/acsami.6b01623
    [12] SHA J, GAO C, LEE S K, et al.Preparation of three-dimensional graphene foams using powder metallurgy templates[J].ACS Nano,2015,10(1):1411-1416 10.1021/acsnano.5b06857
    [13] ZHAO J P, REN W C, CHENG H M.Graphene sponge for efficient and repeatable adsorption and desorption of water contaminations[J].Journal of Materials Chemistry,2012,22(38):20197-20202 10.1039/C2JM34128J
    [14] WAN S, BI H C, SUN L T.Graphene and carbon-based nanomaterials as highly efficient adsorbents for oils and organic solvents[J].Nanotechnology Reviews,2016,5(1):3-22 10.1515/ntrev-2015-0062
    [15] SOROUR M H, HANI H A, AL-BAZEDI G A, et al.Hydrophobic silica aerogels for oil spills clean-up, synthesis, characterization and preliminary performance evaluation[J].Journal of Porous Materials,2016,23(5):1401-1409 10.1007/s10934-016-0200-5
    [16] GE J, ZHAO H Y, ZHU H W, et al.Advanced sorbents for oil-spill cleanup: Recent advances and future perspectives[J].Advanced Materials,2016,28(47):10459-10490 10.1002/adma.201601812
    [17] DAI Z H, WENG C X, LIU L Q, et al.Multifunctional polymer-based graphene foams with buckled structure and negative Poisson’s ratio[J].Scientific Reports,2016,6:32989 10.1038/srep32989
    [18] HUANG S, LI X, JIAO Y, et al.Fabrication of a superhydrophobic, fire-resistant, and mechanical robust sponge upon polyphenol chemistry for efficiently absorbing oils/organic solvents[J].Industrial & Engineering Chemistry Research,2015,54(6):1842-1848 10.1021/ie504812p
    [19] DU X, LIU H Y, MAI Y W.Ultrafast synthesis of multifunctional N-doped graphene foam in an ethanol flame[J].ACS Nano,2015,10(1):453-462 10.1021/acsnano.5b05373
    [20] WANG B, LIANG W, GUO Z, et al.Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: A new strategy beyond nature[J].Chemical Society Reviews,2015,44(1):336-361 10.1039/C4CS00220B
    [21] GUO G L, LIU L B, DANG Z, et al.Recent progress of polyurethane-based materials for oil/water separation[J].Nano,2017,12(4):1730001 10.1142/S1793292017300018
    [22] 李朝宇,张潇,吕佳佳,等. 石墨烯/SiO2气凝胶对苯、甲苯水溶液的吸附[J]. 中国环境科学,2017,37(3):972-979 10.3969/j.issn.1000-6923.2017.03.021
    [23] ZHU H G, CHEN D Y, AN W, et al.A robust and cost-effective superhydrophobic graphene foam for efficient oil and organic solvent recovery[J].Small,2015,11(39):5222-5229 10.1002/smll.201501004
    [24] ZHAO J, GUO Q J, WANG X, et al.Recycle and reusable melamine sponge coated by graphene for highly efficient oil-absorption[J].Colloids and Surfaces A: Physicochemical and Engineering Aspects,2016,488:93-99 10.1016/j.colsurfa.2015.09.048
    [25] NGUYEN D D, TAI N H, LEE S B, et al.Superhydrophobic and superoleophilic properties of graphene-based sponges fabricated using a facile dip coating method[J].Energy & Environmental Science,2012,5(7):7908-7912 10.1039/C2EE21848H
    [26] 邓翠萍, 谢裕畴, 汪文思, 等. 磁性还原氧化石墨烯负载 Fe0 对罗丹明B的类芬顿降解[J]. 环境工程学报,2017,11(6):3499-3506 10.12030/j.cjee.201603138
    [27] TJANDRA R, LUI G, VEILLEUX A, et al.Introduction of an enhanced binding of reduced graphene oxide to polyurethane sponge for oil absorption[J].Industrial & Engineering Chemistry Research,2015,54(14):3657-3663 10.1021/acs.iecr.5b00748
    [28] SONG S, YANG H, SU C P, et al.Ultrasonic-microwave assisted synthesis of stable reduced graphene oxide modified melamine foam with superhydrophobicity and high oil adsorption capacities[J].Chemical Engineering Journal,2016,306:504-511 10.1016/j.cej.2016.07.086
    [29] BAGHBANZADEH M, CARBONE L, COZZOLI P D, et al.Microwave-assisted synthesis of colloidal inorganic nanocrystals[J].Angewandte Chemie International Edition,2011,50(48):11312-11359 10.1002/anie.201101274
    [30] HUMMERS J R W S, OFFEMAN R E.Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(6):1339-1339 10.1021/ja01539a017
    [31] PHAM V H, DICKERSON J H.Superhydrophobic silanized melamine sponges as high efficiency oil absorbent materials[J].ACS Applied Materials & Interfaces,2014,6(16):14181-14188 10.1021/am503503m
    [32] MARK J E.Some interesting things about polysiloxanes[J].Accounts of Chemical Research,2004,37(12):946-953 10.1021/ar030279z
    [33] TRAN D N H, KABIRI S, SIM T R, et al.Selective adsorption of oil–water mixtures using polydimethylsiloxane (PDMS)–graphene sponges[J].Environmental Science: Water Research & Technology,2015,1(3):298-305 10.1039/C5EW00035A
    [34] GE J, SHI L A, WANG Y C, et al.Joule-heated graphene-wrapped sponge enables fast clean-up of viscous crude-oil spill[J].Nature Nanotechnology,2017,12(5):434-440 10.1038/nnano.2017.33
    [35] JIANG Z R, GE J, ZHOU Y X, et al.Coating sponge with a hydrophobic porous coordination polymer containing a low-energy CF3-decorated surface for continuous pumping recovery of an oil spill from water[J].NPG Asia Materials,2016,8(3):e253 10.1038/am.2016.22
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  • 刊出日期:  2018-03-22

石墨烯复合改性海绵的制备及其吸油性能

  • 1. 西南石油大学化学化工学院，成都 610500
  • 2. 川庆钻探工程有限公司安全环保质量监督检测研究院，广汉 618300
基金项目:

国家科技重大专项课题“废弃物处理与利用技术”（2016ZX05040-003）

摘要: 将三聚氰胺海绵（MF）浸入氧化石墨烯（GO）悬浮液，经微波溶剂热还原反应后，用聚二甲基硅氧烷（PDMS）进一步修饰，得到超疏水亲油的石墨烯复合改性吸油海绵（rGO-PDMS-MF）。优化了GO和PDMS改性试剂的浓度，通过扫描电子显微镜（SEM）、傅里叶变换红外光谱仪（FTIR）及接触角（CA）测定仪对海绵结构和性质进行了表征，测试了海绵的饱和吸油性能、重复使用性能及油水分离性能。结果表明：GO悬浮液和PDMS溶液最适浓度分别为2.0 g·L-1和1.0%（质量分数）；所得海绵的接触角达151.5°，饱和吸油能力达45~110 g·g-1，可通过吸附-挤压方式重复使用10次以上；rGO-PDMS-MF海绵对油水体系具有良好的选择性，与泵装置结合后可以连续有效地将油从水面分离，再生使用后仍保持较高的浮油回收速率和较强的疏水性能。

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