响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能

王鹏辰; 莫娟; 谢汝桢; 蒋文举

doi:10.12030/j.cjee.201608078

环境工程学报

响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能

, , ,

王鹏辰, 莫娟, 谢汝桢, 蒋文举. 响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能[J]. 环境工程学报, 2017, 11(11): 6109-6116. doi: 10.12030/j.cjee.201608078

引用本文:

王鹏辰, 莫娟, 谢汝桢, 蒋文举. 响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能[J]. 环境工程学报, 2017, 11(11): 6109-6116. doi: 10.12030/j.cjee.201608078

WANG Pengchen, MO Juan, XIE Ruzhen, JIANG Wenju. Cypress sawdust based activated carbon preparation and its adsorptive capacity towards macromolecule dye (AR88):Optimization by surface methodology[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6109-6116. doi: 10.12030/j.cjee.201608078

Citation:

WANG Pengchen, MO Juan, XIE Ruzhen, JIANG Wenju. Cypress sawdust based activated carbon preparation and its adsorptive capacity towards macromolecule dye (AR88):Optimization by surface methodology[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6109-6116. doi: 10.12030/j.cjee.201608078

响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能

1.
四川大学建筑与环境学院, 成都 610065
2.
国家烟气脱硫工程技术研究中心, 成都 610065
基金项目:
中图分类号: X705

Cypress sawdust based activated carbon preparation and its adsorptive capacity towards macromolecule dye (AR88):Optimization by surface methodology

1.
College of Architecture and Environment, Sichuan University, Chengdu 610065, China
2.
National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065, China
Fund Project:

摘要: 以家具制造废弃物——柏木屑为原料，以磷酸为活化剂，采用微波加热方式，选用响应曲面分析法中心复合设计（CCD）对柏木屑活性炭（AC）制备因素进行优化，结果表明，活性炭最佳制备条件为磷酸/柏木屑质量浸渍比1.94：1，辐照时间8.84 min，微波功率474.98 W，所得活性炭的碘吸附值为945.41 mg·g-1，得率为42.57%。将最优条件制备所得的柏木屑微波活性炭用于大分子染料酸性红88（AR88）的吸附特性研究，实验结果表明，AR88的去除率随着活性炭的投加量增加而升高，活性炭的吸附容量随着AR88浓度的升高而增加。活性炭对AR88的吸附符合Langmuir吸附等温模型，理论最大吸附量为322.58 mg·g-1。对柏木屑微波活性炭物化性质分析表明其表面存在大量无规则孔隙，比表面积、孔容和平均孔径分别为1 312 m2·g-1和0.896 cm3·g-1和2.88 nm。根据吸附结果和表征结果得知，柏木屑微波活性炭是一种具有潜力的高效吸附剂，能有效去除水中的AR88。
- 柏木屑 /
- 微波加热 /
- 响应曲面 /
- 酸性红88 /
- 吸附性能
Abstract: Activated carbon (AC) was prepared from furniture manufacturing waste, specifically from cypress sawdust, by phosphoric acid activation in a microwave oven. The response surface methodology (RSM) and center composite design (CCD) were used to optimize the preparation process of activated carbon. The optimal preparation conditions were:phosphoric acid/sawdust impregnation ratio of 1.94:1, irradiation time of 8.84 min, and microwave power of 474.98 W. Under these conditions, the iodine value and the yield of the activated carbon were 945.41 mg·g-1 and 42.57%, respectively. Acid red 88 (AR88) was chosen as the target pollutant to study the adsorption performance of the activated carbon produced at optimal conditions. The results showed that the AR88 removal efficiency increased with AC dosage and the AC removal capacity toward AR88 increased with higher initial AR88 concentration. The adsorption process fit well with the Langmuir model, with the largest adsorption amount of 322.58 mg·g-1. The carbon characterization shows irregular porosity on the carbon surface. The BET value, pore volume, and mean diameter were 1 312 m2·g-1,0.896 cm3·g-1, and 2.88 nm, respectively. Cypress sawdust-based microwave-induced activated carbon is a promising and efficient adsorbent for removing AR88 from aqueous solutions.
- cypress sawdust /
- microwave heated /
- response surface methodology /
- AR88 /
- adsorption capacity

[1]	崔维, 王仕兴, 彭金辉, 等. 微波能技术在贵金属领域的应用与发展[J]. 稀有金属, 2015, 39(7):652-659
[2]	吴春华, 赵黔榕, 张加研, 等. 微波辐照核桃壳磷酸法制备活性炭的研究[J]. 西南林学院学报, 2006, 26(5):74-76
[3]	樊希安, 彭金辉, 王尧, 等. 微波辐射棉秆制备优质活性炭研究[J]. 资源开发与市场, 2003, 19(5):275-277
[4]	夏洪应, 彭金辉, 杨坤彬, 等. 微波辐射紫茎泽兰制备优质活性炭的研究[J]. 离子交换与吸附, 2008, 24(1):16-24
[5]	朱艳丽, 彭金辉, 张利波, 等. 微波辐射氢氧化钾法制备黄麻杆活性炭工艺[J]. 云南化工, 2005, 32(3):11-13
[6]	彭金辉, 樊希安, 王尧, 等. 微波辐射竹节磷酸法制备活性炭的研究[J]. 林产化学与工业, 2004, 24(1):91-94
[7]	AHMED M J, THEYDAN S K. Optimization of microwave preparation conditions for activated carbon from Albizia lebbeck seed pods for methylene blue dye adsorption[J]. Journal of Analytical and Applied Pyrolysis, 2014, 105(5):199-208
[8]	蔺丽丽, 蒋文举, 金燕, 等. 微波法制备污泥活性炭研究[J]. 环境工程学报, 2007, 1(4):119-122
[9]	FOO K Y, HAMEED B H. Coconut husk derived activated carbon via microwave induced activation:Effects of activation agents, preparation parameters and adsorption performance[J]. Chemical Engineering Journal, 2012, 184(2):57-65
[10]	高建培, 黄斌, 张利波. 微波加热烟杆制备活性炭处理含铜废水[J]. 工业加热, 2007, 36(3):4-6
[11]	CHAYID M A, AHMED M J. Amoxicillin adsorption on microwave prepared activated carbon from Arundo donax, Linn:Isotherms, kinetics, and thermodynamics studies[J].Journal of Environmental Chemical Engineering, 2015,3(3):1592-1601
[12]	王玉新, 苏伟, 周亚平. 不同磷酸活化工艺过程对活性炭孔结构的影响[J]. 炭素技术, 2009, 28(1):17-21
[13]	HOSEINZADEH HESAS R, ARAMI-NIYA A, WAN DAUD W M A, et al. Preparation of granular activated carbon from oil palm shell by microwave-induced chemical activation:Optimisation using surface response methodology[J]. Chemical Engineering Research and Design, 2013, 91(12):2447-2456
[14]	梁昕, 宁寻安, 林朝萍, 等. CCD响应曲面法优化印染污泥木屑基活性炭制备[J]. 环境工程学报, 2014, 8(11):4937-4942
[15]	朱光真, 邓先伦, 刘晓敏. 催化活化法制备高丁烷工作容量颗粒活性炭[J]. 功能材料, 2011, 42(S5):884-887
[16]	黄宏霞, 徐运清, 余丹萍. 木屑活性炭的制备及其对水中酸性红的吸附研究[J]. 湖北工程学院学报, 2013, 33(6):75-78
[17]	LANGMUIR I. The adsorption of gases on plane surfaces of glass, mica and platinum.[J]. Journal of the American Chemical Society, 1918, 40(9):1361-1403
[18]	HALL K R, EAGLETON L C, ACRIVOS A, et al. Pore-and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions[J]. Industrial & Engineering Chemistry Fundamentals, 1966, 5(2):212-223

点击查看大图

计量

文章访问数: 1467
HTML全文浏览数: 1187
PDF下载数: 235
施引文献: 0

响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能

1. 四川大学建筑与环境学院, 成都 610065
2. 国家烟气脱硫工程技术研究中心, 成都 610065

收稿日期: 2016-10-17

基金项目:

关键词:

摘要: 以家具制造废弃物——柏木屑为原料，以磷酸为活化剂，采用微波加热方式，选用响应曲面分析法中心复合设计（CCD）对柏木屑活性炭（AC）制备因素进行优化，结果表明，活性炭最佳制备条件为磷酸/柏木屑质量浸渍比1.94：1，辐照时间8.84 min，微波功率474.98 W，所得活性炭的碘吸附值为945.41 mg·g-1，得率为42.57%。将最优条件制备所得的柏木屑微波活性炭用于大分子染料酸性红88（AR88）的吸附特性研究，实验结果表明，AR88的去除率随着活性炭的投加量增加而升高，活性炭的吸附容量随着AR88浓度的升高而增加。活性炭对AR88的吸附符合Langmuir吸附等温模型，理论最大吸附量为322.58 mg·g-1。对柏木屑微波活性炭物化性质分析表明其表面存在大量无规则孔隙，比表面积、孔容和平均孔径分别为1 312 m2·g-1和0.896 cm3·g-1和2.88 nm。根据吸附结果和表征结果得知，柏木屑微波活性炭是一种具有潜力的高效吸附剂，能有效去除水中的AR88。

English Abstract

Cypress sawdust based activated carbon preparation and its adsorptive capacity towards macromolecule dye (AR88):Optimization by surface methodology

1. College of Architecture and Environment, Sichuan University, Chengdu 610065, China
2. National Engineering Research Center for Flue Gas Desulfurization, Chengdu 610065, China

Received Date: 2016-10-17

Fund Project:

Keywords:

Abstract: Activated carbon (AC) was prepared from furniture manufacturing waste, specifically from cypress sawdust, by phosphoric acid activation in a microwave oven. The response surface methodology (RSM) and center composite design (CCD) were used to optimize the preparation process of activated carbon. The optimal preparation conditions were:phosphoric acid/sawdust impregnation ratio of 1.94:1, irradiation time of 8.84 min, and microwave power of 474.98 W. Under these conditions, the iodine value and the yield of the activated carbon were 945.41 mg·g-1 and 42.57%, respectively. Acid red 88 (AR88) was chosen as the target pollutant to study the adsorption performance of the activated carbon produced at optimal conditions. The results showed that the AR88 removal efficiency increased with AC dosage and the AC removal capacity toward AR88 increased with higher initial AR88 concentration. The adsorption process fit well with the Langmuir model, with the largest adsorption amount of 322.58 mg·g-1. The carbon characterization shows irregular porosity on the carbon surface. The BET value, pore volume, and mean diameter were 1 312 m2·g-1,0.896 cm3·g-1, and 2.88 nm, respectively. Cypress sawdust-based microwave-induced activated carbon is a promising and efficient adsorbent for removing AR88 from aqueous solutions.

全文HTML

参考文献 (18)

下载: 全尺寸图片幻灯片

返回文章

用微信扫码二维码

分享至好友和朋友圈

响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能

Cypress sawdust based activated carbon preparation and its adsorptive capacity towards macromolecule dye (AR88):Optimization by surface methodology

计量

出版历程

响应曲面优化柏木屑微波活性炭的制备及其吸附AR88性能

English Abstract

Cypress sawdust based activated carbon preparation and its adsorptive capacity towards macromolecule dye (AR88):Optimization by surface methodology

全文HTML

目录