Guo Tingting, Liu Ruiping, Yi Xiu, Chen Guixia, Hu Chengzhi. Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 836-842.
Citation: Guo Tingting, Liu Ruiping, Yi Xiu, Chen Guixia, Hu Chengzhi. Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 836-842.

Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity

  • Received Date: 04/05/2012
    Accepted Date: 22/11/2011
    Available Online: 18/03/2013
    Fund Project:
  • To minimize the residual aluminum (Al) levels in the effluent of a drinking water treatment plant (DWTP) with reservoirs source water of high alkalinity,the coagulation performances and the residual Al concentrations using three flocculants,with different basicity (B) and Alb content,were investigated under varibale Al doses and pH. The results indicate that the basicity and Alb content significantly affect coagulation behaviors.The removal efficiency of DOC and turbidity increases with elevated doses of AlCl3 (B=0), PACl-1 (B = 1.2), and PACl-2 (B = 2.2). The concentrations of total Al and dissolved Al are the lowest at Al doses of 1.5~2.0 mg/L for three flocculants.As for the PACl-2, which is prepared by this DWTP, both strategies of decreasing the basicity of flocculant and adjusting the solution pH to 7~7.5 are useful to enhance the coagulation performances and to decrease the residual Al levels. Moreover, the adjustment of flocculant preparation is preferred in the future application.
  • [1] 黄岁樑,臧常娟,杜胜蓝,等. pH、溶解氧、叶绿素a 之间相关性研究.Ⅰ:养殖水体. 环境工程学报,2011,5 (6):7-8 Huang Suiliang,Zang Changjuan,Du Shenglan,et al.Study on the relationships among pH, dissolved oxygen and chlorophyll a Ⅰ: Aquaculture water. Chinese Journal of Environmental Engineering,2011,5(6):1201-1208(in Chinese)

    Google Scholar Pub Med

    [2] 崔福义,胡明成,张燕,等. 我国部分城市饮用水中铝含量调查. 中国给水排水,2002,18 Cui F.Y., Hu M.C., Zhang Y., et al. Investigation on aluminum concentration in drinking water in part of China’s cities. China Water Wastewater, 2002,18:5-8(in Chinese)

    Google Scholar Pub Med

    [3] 蒋绍阶,梁建军. 净水中残余铝的危害与控制. 重庆建筑大学学报,1999,21(6): 121-123 Jiang Shaojie, Liang Jianjun. Hazard and control of residual aluminum in drinking water. Journal of Chongqing Jianzhu University,1996,21(6),121-123(in Chinese)

    Google Scholar Pub Med

    [4] Srinivasan P.T.,Viraraghavan T.,Surbramanian K.S. Aluminum in drinking water: An overview. Water SA,1999,25 (1):47-56

    Google Scholar Pub Med

    [5] Berthon G. Aluminum speciation in relation to aluminum bioavailability,metabolism and toxicity. Coord. Chem. Rev.,2002, 228 (2):319-341

    Google Scholar Pub Med

    [6] 汪光焘.城市供水行业2000年技术进步发展规划.北京:中国建筑工业出版社,1999

    Google Scholar Pub Med

    [7] 崔福义,李名锐,王志红,等.饮用水中铝的危害、来源及现状.哈尔滨建筑大学学报,1997,30(6):51-54 Cui Fuyi,Li Mingrui,Wang Zhihong,et al. The harm,resource and status of aluminum in drinking water. Journal of Harbin University of Civil Engineering and Architecture,1997,30(6):51-54 (in Chinese)

    Google Scholar Pub Med

    [8] Shi B.,Wei Q., Wang D.,et al. Coagulation of humic acid: the performance of preformed and non-preformed Al species. Colloids Surf. A, 2007,296(7):141-148

    Google Scholar Pub Med

    [9] Zhonglian Yang,Bao Yu Gao, Qin Yan Yue,et al. Effect of pH on the coagulation performance of Al-based coagulants and residual aluminum speciation during the treatment of humic acid-kaolin synthetic water. Journal of Hazardous Materials,2010,178 (2): 596-603

    Google Scholar Pub Med

    [10] Steve Kvech,Marc Edwards. Solubility controls on aluminum in drinking water at relatively low and high pH. Water Research,2002,36(2): 4356-4368

    Google Scholar Pub Med

    [11] 胡承志. 富含Al13与活性氯絮凝剂的电解制备及性能研究. 北京:中国科学院生态环境研究中心博士学位论文, 2006 Hu Chengzhi. Electrochemical preparation and examination of a coagulant containing high content of Al13 and active chlorine. Beijing: Doctor Dissertation of Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences,2006 (in Chinese)

    Google Scholar Pub Med

    [12] Yan M.,Wang D.,Qu J.,et al. Relative importance of hydrolyzed Al(Ⅲ) species (Ala, Alb, and Alc) during coagulation with polyaluminum chloride: A case study with the typical micro-polluted source waters. J. Colloid Interface Sci.,2007,316 (7):482-489

    Google Scholar Pub Med

    [13] Bertsch P.M., Thomas G. W., Barnhisel R. I. Characterization hydroxy-aluminum solutions by aluminum-27 nuclear magnetic resonance spectroscopy. Soil Sci.Soc.Am.J,1986, 50(6):825-830

    Google Scholar Pub Med

    [14] He Zhao, Huijuan Liu,Jiuhui Qu. Effect of pH on the aluminum salts hydrolysis during coagulation process:Formation and decomposition of polymeric aluminum species. Journal of Colloid and Interface Science,2009,330 (9):105-112

    Google Scholar Pub Med

    [15] Chengzhi Hu,Huijuan Liu,Jiuhui Qu,et al. Coagulation behavior of aluminum salts in eutrophic water:Significance of Al13 species and pH control. Environment Science & Technology,2006,40(1):325-331

    Google Scholar Pub Med

    [16] 赵赫. 混凝去除消毒副产物前驱体的形态匹配机制研究. 北京:中国科学院生态环境研究中心博士学位论文,2009 Zhao He. Mechanism of disinfection byproduct precursors control by aluminum coagulation based on speciation matching. Beijing: Doctor Dissertation of Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences,2009 (in Chinese)

    Google Scholar Pub Med

    [17] 王志红,崔福义. pH值和水温对残余铝的影响试验研究. 广东工业大学学报, 2003,20(3):71-75 Wang Zhihong, Cui Fuyi. Correlation of water temperature and ph value with residual aluminum in water plant. Journal of Guangdong University of Technology, 2003,20(3):71-75(in Chinese)

    Google Scholar Pub Med

    [18] 汤鸿霄. 无机高分子絮凝理论与絮凝剂. 北京:中国建筑工业大学出版社,2006

    Google Scholar Pub Med

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Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity

Fund Project:

Abstract: To minimize the residual aluminum (Al) levels in the effluent of a drinking water treatment plant (DWTP) with reservoirs source water of high alkalinity,the coagulation performances and the residual Al concentrations using three flocculants,with different basicity (B) and Alb content,were investigated under varibale Al doses and pH. The results indicate that the basicity and Alb content significantly affect coagulation behaviors.The removal efficiency of DOC and turbidity increases with elevated doses of AlCl3 (B=0), PACl-1 (B = 1.2), and PACl-2 (B = 2.2). The concentrations of total Al and dissolved Al are the lowest at Al doses of 1.5~2.0 mg/L for three flocculants.As for the PACl-2, which is prepared by this DWTP, both strategies of decreasing the basicity of flocculant and adjusting the solution pH to 7~7.5 are useful to enhance the coagulation performances and to decrease the residual Al levels. Moreover, the adjustment of flocculant preparation is preferred in the future application.

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