Enhancement of sludge anaerobic digestion by adding trace element Fe and Ni
- Received Date: 20/12/2016
- Accepted Date: 16/11/2016
- Available Online: 26/08/2017
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Key words:
- sludge anaerobic digestion /
- trace elements /
- FeCl2 /
- NiCl2 /
- hydrolysis /
- acidification
Abstract: The use of large amount of fossil energy has caused serious environment and energy problems. Sludge anaerobic digestion has been considered as a potential method to solve above problems. However, conventional sludge anaerobic digestion has some drawbacks such as low efficiency and long sludge retention time. This paper investigated effects of adding trace elements Fe and Ni on biogas production and organic matters removal during sludge anaerobic digestion. As for biogas production, results showed that when FeCl2 concentration was added below 400 mg·L-1, biogas production was higher than that of control. The highest biogas yield of 414.6 mL·g-1(VSadded) was obtained at the adding dosage of 25 mg·L-1, which was 28 mL·g-1(VSadded) higher than that of control. Cumulative biogas production increased with the increase of NiCl2 addition dosages in the range of 0~5 mg·L-1. The highest biogas yield of 389.5 mL·g-1(VSadded) were obtained at the NiCl2 adding dosage of 5 mg·L-1. At the optimal condition, the enhancement of biogas by adding FeCl2 was higher than that by adding NiCl2. As for organic matters removal, the volatile solids removal was slight improved by adding 25 mg·L-1 FeCl2 compared with control, and then decreased with the increase of FeCl2 addition dosage. The volatile solids removal was decreased with the increase of NiCl2 addition dosage compared with control. The best adding dosage of FeCl2 was 25 mg·L-1 during sludge anaerobic digestion based on biogas yield, volatile solids removal and cost. The soluble chemical oxygen demand and volatile fatty acids concentrations were improved by 15.3% and 39.2% with the addition of 25 mg·L-1 FeCl2, which provided a better substrate condition for biogas production.