玻璃分相法脱除CRT屏玻璃中重金属钡

邢明飞, 傅泽刚, 王净宇, 高志东, 张志远. 玻璃分相法脱除CRT屏玻璃中重金属钡[J]. 环境工程学报, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184
引用本文: 邢明飞, 傅泽刚, 王净宇, 高志东, 张志远. 玻璃分相法脱除CRT屏玻璃中重金属钡[J]. 环境工程学报, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184
XING Mingfei, FU Zegang, WANG Jingyu, GAO Zhidong, ZHANG Zhiyuan. Barium recovery from CRT panel glass through phase separation process[J]. Chinese Journal of Environmental Engineering, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184
Citation: XING Mingfei, FU Zegang, WANG Jingyu, GAO Zhidong, ZHANG Zhiyuan. Barium recovery from CRT panel glass through phase separation process[J]. Chinese Journal of Environmental Engineering, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184

玻璃分相法脱除CRT屏玻璃中重金属钡

  • 基金项目:

    国家自然科学基金资助项目(51508165)

    河南省教育厅科学技术研究重点项目(13140055)

    河南省高校矿山环境保护与生态修复省级重点实验室培育基地开放基金资助项目(KF2014-02)

Barium recovery from CRT panel glass through phase separation process

  • Fund Project:
  • 摘要: 玻璃分相的方法可以将重金属钡从CRT屏玻璃中高效脱除。该方法将CRT屏玻璃与一定量的B2O3混合后在空气气氛下进行热分相处理。在热分相处理过程中,屏玻璃中的B2O3与SiO2逐渐分离,形成2个独立的相(富B2O3相和富SiO2相)。CRT屏玻璃中的重金属钡和其他碱金属氧化物在分相过程中主要富集在呈网状连通结构富B2O3相中。将分相处理产物经5 mol?L-1的硝酸在90 °C条件下浸泡30 min,即可将富B2O3相以及其中包含的重金属钡一并去除,得到SiO2含量超过95%的高硅氧玻璃粉末。实验结果表明,当反应温度为1 100 °C,B2O3添加量为30%,保温时间为30 min时,钡的脱除率可以达到98.84%,为废弃CRT屏玻璃无害化处理与资源化利用提供了一条新的途径。
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    [2] XU O, LI G, HE W, et al.Cathode ray tube (CRT) recycling: Current capabilities in China and research progress[J].Waste Management,2012,32(8):1566-1574 10.1016/j.wasman.2012.03.009
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    [5] 王喆,刘少卿,陈晓民,等.废旧阴极射线管(CRT)显示器玻壳进入土壤后铅的释放及转化[J].环境科学,2009,30(6):1855-1859
    [6] MEAR F O, YOT P G, KOLOBOV A V,et al.Local structure around lead, barium and strontium in waste cathode-ray tube glasses[J].Journal of Non-Crystalline Solids, 2007,353(52/53/54):4640-4646 10.1016/j.jnoncrysol.2007.07.009
    [7] LEE J S, YOO H M, PARK S W,et al.Recycling of cathode ray tube panel glasses as aggregates of concrete blocks and clay bricks[J].Jouranl of Material Cycles and Waste Management,2016,18(3):552-562
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    [11] 陈梦君,张付申,朱建新.真空碳热还原法无害化处理废弃阴极射线管锥玻璃的研究[J].环境工程学报, 2009,3(1):156-160
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  • 刊出日期:  2018-10-11
邢明飞, 傅泽刚, 王净宇, 高志东, 张志远. 玻璃分相法脱除CRT屏玻璃中重金属钡[J]. 环境工程学报, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184
引用本文: 邢明飞, 傅泽刚, 王净宇, 高志东, 张志远. 玻璃分相法脱除CRT屏玻璃中重金属钡[J]. 环境工程学报, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184
XING Mingfei, FU Zegang, WANG Jingyu, GAO Zhidong, ZHANG Zhiyuan. Barium recovery from CRT panel glass through phase separation process[J]. Chinese Journal of Environmental Engineering, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184
Citation: XING Mingfei, FU Zegang, WANG Jingyu, GAO Zhidong, ZHANG Zhiyuan. Barium recovery from CRT panel glass through phase separation process[J]. Chinese Journal of Environmental Engineering, 2018, 12(10): 2952-2958. doi: 10.12030/j.cjee.201804184

玻璃分相法脱除CRT屏玻璃中重金属钡

  • 1. 河南理工大学,河南省高校矿山环境保护与生态修复省级重点实验室培育基地,焦作 454000
  • 2. 河南理工大学资源环境学院,焦作 454000
  • 3. 河南省发展和改革委员会,郑州 450018
  • 4. 中国科学院生态环境研究中心,北京 100085
基金项目:

国家自然科学基金资助项目(51508165)

河南省教育厅科学技术研究重点项目(13140055)

河南省高校矿山环境保护与生态修复省级重点实验室培育基地开放基金资助项目(KF2014-02)

摘要: 玻璃分相的方法可以将重金属钡从CRT屏玻璃中高效脱除。该方法将CRT屏玻璃与一定量的B2O3混合后在空气气氛下进行热分相处理。在热分相处理过程中,屏玻璃中的B2O3与SiO2逐渐分离,形成2个独立的相(富B2O3相和富SiO2相)。CRT屏玻璃中的重金属钡和其他碱金属氧化物在分相过程中主要富集在呈网状连通结构富B2O3相中。将分相处理产物经5 mol?L-1的硝酸在90 °C条件下浸泡30 min,即可将富B2O3相以及其中包含的重金属钡一并去除,得到SiO2含量超过95%的高硅氧玻璃粉末。实验结果表明,当反应温度为1 100 °C,B2O3添加量为30%,保温时间为30 min时,钡的脱除率可以达到98.84%,为废弃CRT屏玻璃无害化处理与资源化利用提供了一条新的途径。

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