芬顿试剂氧化-PAC吸附工艺处理电厂排污水

杨毅, 顾平, 徐思雯, 孟凡怡, 董丽华, 张光辉. 芬顿试剂氧化-PAC吸附工艺处理电厂排污水[J]. 环境工程学报, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002
引用本文: 杨毅, 顾平, 徐思雯, 孟凡怡, 董丽华, 张光辉. 芬顿试剂氧化-PAC吸附工艺处理电厂排污水[J]. 环境工程学报, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002
YANG Yi, GU Ping, XU Siwen, MENG Fanyi, DONG Lihua, ZHANG Guanghui. Treatment of power plant recirculating cooling drainage by Fenton’s reagent preoxidation combined with powdered activated carbon adsorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002
Citation: YANG Yi, GU Ping, XU Siwen, MENG Fanyi, DONG Lihua, ZHANG Guanghui. Treatment of power plant recirculating cooling drainage by Fenton’s reagent preoxidation combined with powdered activated carbon adsorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002

芬顿试剂氧化-PAC吸附工艺处理电厂排污水

  • 基金项目:

Treatment of power plant recirculating cooling drainage by Fenton’s reagent preoxidation combined with powdered activated carbon adsorption

  • Fund Project:
  • 摘要: 开发了芬顿试剂预氧化-粉末活性炭(PAC)吸附组合工艺处理电厂循环冷却排污水。首先分别研究了芬顿试剂氧化法和粉末活性炭吸附法对有机物的去除效果,发现2种工艺在最佳处理条件时仍存在处理效果较差、药剂费用高等问题。因此,开发了芬顿试剂预氧化-PAC吸附组合工艺,研究了该工艺的影响因素,并进行小试实验。结果表明,该组合工艺在不改变原水的初始pH、H2O2与Fe2+的摩尔比为1以及H2O2的投加浓度为25 mg·L-1时得到最佳的预处理条件。在最佳预氧化条件下投加0.15 g·L-1的PAC进行了4级逆流吸附小试实验,结果表明:该工艺处理效果稳定、药剂费用低,出水满足排放要求。
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  • [1] 张竞杰, 冯国柱, 张智刚, 等.火电厂循环冷却排污水的污染减排与回用技术[J].内蒙古电力技术, 2015,3(S2):49-52
    [2] 王国栋.循环冷却水排污水的处理[C]∥中国土木工程学会全国排水委员会.中国土木工程学会全国排水委员会2015年年会论文集.杭州, 2015:299-302
    [3] 杨伟, 刘芳, 高雅, 等.循环水排污水中残余阻垢剂对反渗透膜性能的影响[J].化工进展,2015,4(2):565-570
    [4] 易斌, 杨春平, 郭俊元, 等.活性炭吸附-Fenton氧化处理高盐有机废水[J].环境工程学报,2013,7(3):903-907
    [5] 叶少帆, 吴志超, 王志伟, 等.Fenton氧化-活性炭吸附协同深度处理垃圾渗滤液的研究[J].环境工程学报,2010,4(6):1363-1367
    [6] ZHU X B, TIAN J P, LIU R, et al.Optimization of Fenton and electro-Fenton oxidation of biologically treated coking wastewater using response surface methodology[J].Separation and Purification Technology,2011,1(3):444-450
    [7] BLANCO J, TORRADES F, VARGA M, et al.Fenton and biological-Fenton coupled processes for textile wastewater treatment and reuse[J].Desalination,2011,6(1):394-399
    [8] BIANCO B, MICHELIS I D, VEGLIO F.Fenton treatment of complex industrial wastewater: Optimization of process conditions by surface response method[J].Journal of Hazardous Materials, 2011,6(2/3):1733-1738
    [9] CHEN S, SUN D Z, CHUNG J S.Treatment of pesticide wastewater by moving-bed biofilm reactor combined with Fenton-coagulation pretreatment[J].Journal of Hazardous Materials,2007,4(1/2):577-584
    [10] 涂响, 魏健, 李斌, 等.Fenton氧化和絮凝作用对干法腈纶聚合废水中有机物的去除[J].环境工程技术学报,2014,4(1):53-59
    [11] MOCHIZUKI T, KUBOTA M, MATSUDA H, et al.Adsorption behaviors of ammonia and hydrogen sulfide on activated carbon prepared from petroleum coke by KOH chemical activation[J].Fuel Processing Technology,2016,4:164-169
    [12] 胡佳欣.芬顿-活性炭吸附深度处理褐煤提质废水技术研究[D].长春: 吉林大学, 2016
    [13] VARGAS A M M, CAZETTA A L, KUNITA M H, et al.Adsorption of methylene blue on activated carbon produced from flamboyant pods (Delonix regia): Study of adsorption isotherms and kinetic models[J].Chemical Engineering Journal,2011,8(2):722-730
    [14] WANG L W, TAMAINOT-TELTO Z, THORPE R, et al.Study of thermal conductivity, permeability, and adsorption performance of consolidated composite activated carbon adsorbent for refrigeration[J].Renewable Energy,2011,6(8):2062-2066
    [15] ZHANG S, SHAO T, KARANFIL T.The effects of dissolved natural organic matter on the adsorption of synthetic organic chemicals by activated carbons and carbon nanotubes[J].Water Research,2011,5(3):1378-1386
    [16] ZHANG Y.Rapid adsorption and degradation of nitrophenol solution with activated carbon and Fenton’s reagent[J].Chinese Journal of Environmental Engineering,2012,6(3):787-792
    [17] 杨鹏, 张伟军, 刘园园, 等.活性炭吸附和两级Fenton氧化组合工艺处理高盐对氨基苯酚生产废水[J].环境工程学报,2015,9(5):2232-2236
    [18] 国家环境保护总局.水和废水监测分析方法[M].4版.北京: 中国环境科学出版社, 2002:211-213
    [19] 李竞, 顾平, 张光辉.PAC四级逆流吸附/微滤组合工艺处理二级出水[J].中国给水排水,2016,2(19):76-79
    [20] WEI X Z, GU P, ZHANG G H.Reverse osmosis concentrate treatment by a PAC countercurrent four-stage adsorption/MF hybrid process[J].Desalination,2014,2(3):18-26
    [21] 刘成, 黄廷林, 赵建伟.混凝、粉末活性炭吸附对不同分子量有机物的去除[J].净水技术,2006,5(1):31-33
    [22] XIA C, LI J G, FANG G.Fenton oxidation of different molecular weights polyethylene glycols in wastewater[J].Advanced Materials Research,2014,4(1033):382-386
    [23] 张定定, 马冬梅, 汤志涛, 等.印染废水深度处理过程中有机污染物分子量的分布变化[J].环境化学,2014,3(7):1222-1228
    [24] 梅特卡夫和埃迪公司,乔巴诺格劳斯, 伯顿, 等.废水工程: 处理及回用[M].北京: 化学工业出版社, 2004:826-827
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  • 刊出日期:  2018-02-08
杨毅, 顾平, 徐思雯, 孟凡怡, 董丽华, 张光辉. 芬顿试剂氧化-PAC吸附工艺处理电厂排污水[J]. 环境工程学报, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002
引用本文: 杨毅, 顾平, 徐思雯, 孟凡怡, 董丽华, 张光辉. 芬顿试剂氧化-PAC吸附工艺处理电厂排污水[J]. 环境工程学报, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002
YANG Yi, GU Ping, XU Siwen, MENG Fanyi, DONG Lihua, ZHANG Guanghui. Treatment of power plant recirculating cooling drainage by Fenton’s reagent preoxidation combined with powdered activated carbon adsorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002
Citation: YANG Yi, GU Ping, XU Siwen, MENG Fanyi, DONG Lihua, ZHANG Guanghui. Treatment of power plant recirculating cooling drainage by Fenton’s reagent preoxidation combined with powdered activated carbon adsorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(2): 536-543. doi: 10.12030/j.cjee.201707002

芬顿试剂氧化-PAC吸附工艺处理电厂排污水

  • 1. 天津大学环境科学与工程学院,天津 300350
基金项目:

摘要: 开发了芬顿试剂预氧化-粉末活性炭(PAC)吸附组合工艺处理电厂循环冷却排污水。首先分别研究了芬顿试剂氧化法和粉末活性炭吸附法对有机物的去除效果,发现2种工艺在最佳处理条件时仍存在处理效果较差、药剂费用高等问题。因此,开发了芬顿试剂预氧化-PAC吸附组合工艺,研究了该工艺的影响因素,并进行小试实验。结果表明,该组合工艺在不改变原水的初始pH、H2O2与Fe2+的摩尔比为1以及H2O2的投加浓度为25 mg·L-1时得到最佳的预处理条件。在最佳预氧化条件下投加0.15 g·L-1的PAC进行了4级逆流吸附小试实验,结果表明:该工艺处理效果稳定、药剂费用低,出水满足排放要求。

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