Fenton试剂法降解餐厨垃圾异味

狄彦强, 刘杰民, 刘思园, 颜鲁春, 冯振华. Fenton试剂法降解餐厨垃圾异味[J]. 环境工程学报, 2013, 7(4): 1445-1450.
引用本文: 狄彦强, 刘杰民, 刘思园, 颜鲁春, 冯振华. Fenton试剂法降解餐厨垃圾异味[J]. 环境工程学报, 2013, 7(4): 1445-1450.
Di Yanqiang, Liu Jiemin, Liu Siyuan, Yan Luchun, Feng Zhenhua. Treating food waste odor by Fenton reagent method[J]. Chinese Journal of Environmental Engineering, 2013, 7(4): 1445-1450.
Citation: Di Yanqiang, Liu Jiemin, Liu Siyuan, Yan Luchun, Feng Zhenhua. Treating food waste odor by Fenton reagent method[J]. Chinese Journal of Environmental Engineering, 2013, 7(4): 1445-1450.

Fenton试剂法降解餐厨垃圾异味

  • 基金项目:

    国家自然科学基金资助项目(20877008,21277011)

    新世纪优秀人才支持计划资助(NCET-09-0218)

    中央高校基础科研业务费(FRF-TP-10-004B, FRF-BR-11-017B)

    国家高技术研究发展计划(863)项目(2012AA030302)

    北京市自然科学基金资助项目(8092021)

  • 中图分类号: X701

Treating food waste odor by Fenton reagent method

  • Fund Project:
  • 摘要: 自行设计Fenton试剂法降解还原性气体异味的反应器,研究了Fenton试剂法处理餐厨垃圾异味主要成分(苯、乙酸乙酯、苯乙烯)的降解效果。以苯为典型代表物,优化得出该实验的最佳反应条件为:pH=3,FeSO4·7H2O投加量为1 g/L液相,30%H2O2投加量为10 mL/L液相,紫外光源辅助。结果证明,Fenton试剂法处理单一异味气体的效果较理想,在前180 min内能达到90%以上,该法在处理气态异味污染物方面具有广阔的应用前景。
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  • [1] 王琪.我国城市生活垃圾处理现状及存在的问题.环境经济,2005,(10):23-29 Wang Q.Present situation of and problem existing in the urban domestic waste treatment in China.Environmental Economy,2005,(10):23-29(in Chinese)
    [2] 樊元生.我国城市生活垃圾产生和处理、处置现状.环境经济,2005,(10):9-12 Fan Y.S.Present situation of production, treatment and disposal of the urban domestic waste in China.Environmental Economy,2005,(10):9-12(in Chinese)
    [3] 中华人民共和国国家统计局.中国统计年鉴.北京:中国统计出版社,2010
    [4] 李国刚,曹杰山,汪志国.我国城市生活垃圾处理处置的现状与问题.环境保护,2002,(4):35-38 Li G. G.,Cao J. S.,Wang Z. G.Present situation of and problem existing in the urban domestic waste treatment and disposal in China.Environmental Protection,2002,(4):35-38(in Chinese)
    [5] Schuetz C.,Bonger J.,Chanton J.Comparative oxidation and net emissions of methane and selected nonmethane organic compounds in landfill cover soils.Environmental Science and Technology,2003,37(22):5150-5158
    [6] Zou S. C.,Lee S. C.,Chan C. Y.Characterization of ambient volatile organic compounds at a landfill site in Guangzhou,South China.Chemosphere,2003,51(9):1015-1022
    [7] 纪华.垃圾填埋场恶臭气体产气机制及其动态变化研究.北京:中国农业大学硕士学位论文,2004 Ji H.Malodor producing mechanism and the study on its dynamic changes in landfill.Beijing: Master’s Degree Thesis of China Agricultural University,2004
    [8] Hiroshi F.Environmental odor management in Japan.VDI Berichte,2004,1850:71-76
    [9] David F.UK air pollution legislation: A global comparison. Chemical Engineer,2004,(760):42-43
    [10] 李章良,黄建辉.Fenton试剂氧化机理及难降解有机工业废水处理研究进展.韶关学院学报(自然科学),2010,31(3):66-72 Li Z.L.,Huang J.H.Oxidation mechanism and research progress of Fenton reagent in the treatment of industrial waste water containing refractory organic pollutions.Journal of Shaoguan University (Natural Science),2010,31(3):66-72(in Chinese)
    [11] Oliveira R.,Cortez S.Evaluation of Fenton and ozone-based advanced oxidation processes as mature landfill leachate pre-treatments.Journal of Environmental Management,2011,92(3):749-755
    [12] Kremer M.L.Complex visas 'Free Radical’ mechanism for the catalytic decomposition of H2O2 by Fe3+.Int.J.Chem.Kinet.,1985,17(12):1229-1314
    [13] Win D.A.,Nimbus R. W.,Deserters M. F.,et al.A kinetic investigation of intermediates formed during the Fenton reagent mediated degradation of N-nitrosodimethy amine: Evidence for an oxidative Pathway not involving hydroxyl radical.Chem.Rev.Toxico.,1991,4(5):510-512
    [14] Ruppert G.,Bauer R.,Heisler G.The photo-Fenton reaction an effective photochemical wastewater treatment process.Photochem. Photobiol,A:Chem.,1993,73(1):75-78
    [15] 谢银德,陈锋,何建军,等.Photo-Fenton反应研究进展.感光科学与光化学,2000,18(4):357-365 Xie Y.D.,Chen F.,He J.J.,et al.Recent advance in Photo-Fenton reaction.Photographic Science and Photochemistry,2000,18(4):357-365(in Chinese)
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出版历程
  • 收稿日期:  2012-10-03
  • 刊出日期:  2013-04-09
狄彦强, 刘杰民, 刘思园, 颜鲁春, 冯振华. Fenton试剂法降解餐厨垃圾异味[J]. 环境工程学报, 2013, 7(4): 1445-1450.
引用本文: 狄彦强, 刘杰民, 刘思园, 颜鲁春, 冯振华. Fenton试剂法降解餐厨垃圾异味[J]. 环境工程学报, 2013, 7(4): 1445-1450.
Di Yanqiang, Liu Jiemin, Liu Siyuan, Yan Luchun, Feng Zhenhua. Treating food waste odor by Fenton reagent method[J]. Chinese Journal of Environmental Engineering, 2013, 7(4): 1445-1450.
Citation: Di Yanqiang, Liu Jiemin, Liu Siyuan, Yan Luchun, Feng Zhenhua. Treating food waste odor by Fenton reagent method[J]. Chinese Journal of Environmental Engineering, 2013, 7(4): 1445-1450.

Fenton试剂法降解餐厨垃圾异味

  • 1.  北京科技大学化学与生物工程学院,北京 100083
  • 2.  中国建筑科学研究院,北京100013
基金项目:

国家自然科学基金资助项目(20877008,21277011)

新世纪优秀人才支持计划资助(NCET-09-0218)

中央高校基础科研业务费(FRF-TP-10-004B, FRF-BR-11-017B)

国家高技术研究发展计划(863)项目(2012AA030302)

北京市自然科学基金资助项目(8092021)

摘要: 自行设计Fenton试剂法降解还原性气体异味的反应器,研究了Fenton试剂法处理餐厨垃圾异味主要成分(苯、乙酸乙酯、苯乙烯)的降解效果。以苯为典型代表物,优化得出该实验的最佳反应条件为:pH=3,FeSO4·7H2O投加量为1 g/L液相,30%H2O2投加量为10 mL/L液相,紫外光源辅助。结果证明,Fenton试剂法处理单一异味气体的效果较理想,在前180 min内能达到90%以上,该法在处理气态异味污染物方面具有广阔的应用前景。

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