基于碱液预处理的泡沫浮选法分离PVC/PET

扶娟, 赵钺, 刘珺, 徐开伟, 李彦鹏. 基于碱液预处理的泡沫浮选法分离PVC/PET[J]. 环境工程学报, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210
引用本文: 扶娟, 赵钺, 刘珺, 徐开伟, 李彦鹏. 基于碱液预处理的泡沫浮选法分离PVC/PET[J]. 环境工程学报, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210
FU Juan, ZHAO Yue, LIU Jun, XU Kaiwei, LI Yanpeng. Separation of PVC/PET by froth flotation with alkaline pretreatment[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210
Citation: FU Juan, ZHAO Yue, LIU Jun, XU Kaiwei, LI Yanpeng. Separation of PVC/PET by froth flotation with alkaline pretreatment[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210

基于碱液预处理的泡沫浮选法分离PVC/PET

  • 基金项目:

    国家自然科学基金资助项目(51208059,41230314)

    中央高校基本科研业务费专项(310829163406,310829172001)

  • 中图分类号: X705

Separation of PVC/PET by froth flotation with alkaline pretreatment

  • Fund Project:
  • 摘要: 为优化聚氯乙烯(PVC)和聚对苯二甲酸乙二醇酯(PET)废旧混合塑料的浮选分离效果,采用碱液预处理的方式,结合松油醇(TP)作为浮选药剂,以PVC在上浮产物中的回收率及纯度为考核指标,详细考察了不同参数对浮选效果的影响。结果表明:分离PVC/PET混合物的最优工艺为NaOH质量分数2%,预处理时间15 min,预处理温度70℃,TP浓度35 mg·L-1,浮选时间2 min。在上述最优工艺参数下,混合物中PVC作为上浮产物的回收率和纯度分别可达83%和100%。实验结果对PVC/PET分选的实际应用具有重要的指导意义。
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  • [1] 佚名. 2015中国塑料制品产量与进出口数据[J]. 塑料科技, 2016,44(5):45
    [2] 王晖.再生资源的物理化学分选塑料浮选体系中的界面相互作用[D].长沙:中南大学,2007
    [3] 中蓝晨光化工研究院有限公司,塑料工业编辑部.2013-2014年世界塑料工业进展[J].塑料工业,2015,43(3):1-40
    [4] TORRES N, ROBIN J J, BOUTEVIN B. Study of thermal and mechanical properties of virgin and recycled poly(ethylene terephthalate) before and after injection molding[J]. European Polymer Journal,2000,36(10):2075-2080
    [5] PACI M, MANTIA P L F. Influence of small amounts of polyvinylchloride on the recycling of polyethyleneterephthalate[J]. Polymer Degradation & Stability,1999,63(1):11-14
    [6] PAWLAK A, PLUTA M, MORAWIEC J, et al. Characterization of scrap poly(ethylene terephthalate)[J]. European Polymer Journal,2000,36(9):1875-1884
    [7] SISSON E A. Process for separating polyethylene terephthalate from polyvinyl chloride:US5120768[P].1992-06-09
    [8] DEIRINGER G, EDELMANN G, RAUXLOH B. Process for the separation of plastics by flotation:US5248041[P].1993-09-28
    [9] 董领锋, 袁英. 采用排液法测量多孔材料的密度[J]. 粉末冶金材料科学与工程,1998,3(1):77-80
    [10] MANCINI S D, ZANIN M. Recyclability of PET from virgin resin[J]. Materials Research,1999,2(1):33-38
    [11] CAPARANGA A R, BASILIA B A, DAGBAY K B, et al. Factors affecting degradation of polyethylene terephthalate (PET) during pre-flotation conditioning[J]. Waste Management,2009, 29(9):2425-2428
    [12] MARTIN N, SKYARLA J, SISOL M. A possibility of using the flotation process to separate plastics[J].International Journal of Engineering,2011,3:275-278
    [13] WANG C Q, WANG H, LIU Y N. Separation of polyethylene terephthalate from municipal waste plastics by froth flotation for recycling industry[J]. Waste Management,2015,35:42-47
    [14] WANG C Q, WANG H, LIU Q, et al. Separation of polycarbonate and acrylonitrile-butadiene-styrene waste plastics by froth flotation combined with ammonia pretreatment[J]. Waste Management,2014, 34(12):2656-2661
    [15] WANG C Q, WANG H, WU B X, et al. Boiling treatment of ABS and PS plastics for flotation separation[J]. Waste Management,2014,34(7):1206-1210
    [16] LI Y P, YANG L W, ZHU T T, et al. Biosurfactants as alternatives to chemosynthetic surfactants in controlling bubble behavior in the flotation process[J]. Journal of Surfactants & Detergents,2012,16(3):409-419
    [17] LI Y, ZHU T, LIU Y, et al. Effects of surfactant on bubble hydrodynamic behavior under flotation-related conditions in wastewater[J]. Water Science & Technology,2012,65(6):1060-1066
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出版历程
  • 收稿日期:  2017-01-03
  • 刊出日期:  2017-11-15

基于碱液预处理的泡沫浮选法分离PVC/PET

  • 1. 长安大学环境科学与工程学院, 西安 710064
基金项目:

国家自然科学基金资助项目(51208059,41230314)

中央高校基本科研业务费专项(310829163406,310829172001)

摘要: 为优化聚氯乙烯(PVC)和聚对苯二甲酸乙二醇酯(PET)废旧混合塑料的浮选分离效果,采用碱液预处理的方式,结合松油醇(TP)作为浮选药剂,以PVC在上浮产物中的回收率及纯度为考核指标,详细考察了不同参数对浮选效果的影响。结果表明:分离PVC/PET混合物的最优工艺为NaOH质量分数2%,预处理时间15 min,预处理温度70℃,TP浓度35 mg·L-1,浮选时间2 min。在上述最优工艺参数下,混合物中PVC作为上浮产物的回收率和纯度分别可达83%和100%。实验结果对PVC/PET分选的实际应用具有重要的指导意义。

English Abstract

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