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基于碱液预处理的泡沫浮选法分离PVC/PET

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扶娟, 赵钺, 刘珺, 徐开伟, 李彦鹏. 基于碱液预处理的泡沫浮选法分离PVC/PET[J]. 环境工程学报, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210
引用本文: 扶娟, 赵钺, 刘珺, 徐开伟, 李彦鹏. 基于碱液预处理的泡沫浮选法分离PVC/PET[J]. 环境工程学报, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210
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FU Juan, ZHAO Yue, LIU Jun, XU Kaiwei, LI Yanpeng. Separation of PVC/PET by froth flotation with alkaline pretreatment[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210
Citation: FU Juan, ZHAO Yue, LIU Jun, XU Kaiwei, LI Yanpeng. Separation of PVC/PET by froth flotation with alkaline pretreatment[J]. Chinese Journal of Environmental Engineering, 2017, 11(11): 6124-6129. doi: 10.12030/j.cjee.201610210
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基于碱液预处理的泡沫浮选法分离PVC/PET

  • 1.

    长安大学环境科学与工程学院, 西安 710064

  • 基金项目:

    国家自然科学基金资助项目（51208059，41230314）

    中央高校基本科研业务费专项（310829163406，310829172001）

  • 中图分类号: X705

Separation of PVC/PET by froth flotation with alkaline pretreatment

  • 1.

    School of Environmental Science and Engineering, Chang'an University, Xi'an 710064, China

  • Fund Project:

  • 摘要: 为优化聚氯乙烯（PVC）和聚对苯二甲酸乙二醇酯（PET）废旧混合塑料的浮选分离效果，采用碱液预处理的方式，结合松油醇（TP）作为浮选药剂，以PVC在上浮产物中的回收率及纯度为考核指标，详细考察了不同参数对浮选效果的影响。结果表明：分离PVC/PET混合物的最优工艺为NaOH质量分数2%，预处理时间15 min，预处理温度70℃，TP浓度35 mg·L-1，浮选时间2 min。在上述最优工艺参数下，混合物中PVC作为上浮产物的回收率和纯度分别可达83%和100%。实验结果对PVC/PET分选的实际应用具有重要的指导意义。
    Abstract: In order to optimize the effect of separation by froth flotation of the mixed plastic poyvinyl chloride(PVC) and polyethylene terephthalate (PET), using the method of treatment with alkaline, combined with terpineol (TP) as a flotation reagents.To clearify the mechanism influenced by different parameters, the recovery and purity of PVC in froth product were chosen as performance indicators. Results showed that the optimal process for the separation of PVC and PET was achieved under sodium hydroxide concentration of 2%, pretreatment time of 15 min,temperature of 70℃,terpineol concentration of 35 mg·L-1 and flotation time of 2 min.In these conditions, the flotation recovery and purity of PVC in floating product were 83% and 100%,respectively. These results showed a significance meaning for improving the efficiency of separation of mixed PVC/PET.
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  • [1] 佚名. 2015中国塑料制品产量与进出口数据[J]. 塑料科技, 2016,44(5):45
    [2] 王晖.再生资源的物理化学分选塑料浮选体系中的界面相互作用[D].长沙:中南大学,2007
    [3] 中蓝晨光化工研究院有限公司,塑料工业编辑部.2013-2014年世界塑料工业进展[J].塑料工业,2015,43(3):1-40
    [4] TORRES N, ROBIN J J, BOUTEVIN B. Study of thermal and mechanical properties of virgin and recycled poly(ethylene terephthalate) before and after injection molding[J]. European Polymer Journal,2000,36(10):2075-2080
    [5] PACI M, MANTIA P L F. Influence of small amounts of polyvinylchloride on the recycling of polyethyleneterephthalate[J]. Polymer Degradation & Stability,1999,63(1):11-14
    [6] PAWLAK A, PLUTA M, MORAWIEC J, et al. Characterization of scrap poly(ethylene terephthalate)[J]. European Polymer Journal,2000,36(9):1875-1884
    [7] SISSON E A. Process for separating polyethylene terephthalate from polyvinyl chloride:US5120768[P].1992-06-09
    [8] DEIRINGER G, EDELMANN G, RAUXLOH B. Process for the separation of plastics by flotation:US5248041[P].1993-09-28
    [9] 董领锋, 袁英. 采用排液法测量多孔材料的密度[J]. 粉末冶金材料科学与工程,1998,3(1):77-80
    [10] MANCINI S D, ZANIN M. Recyclability of PET from virgin resin[J]. Materials Research,1999,2(1):33-38
    [11] CAPARANGA A R, BASILIA B A, DAGBAY K B, et al. Factors affecting degradation of polyethylene terephthalate (PET) during pre-flotation conditioning[J]. Waste Management,2009, 29(9):2425-2428
    [12] MARTIN N, SKYARLA J, SISOL M. A possibility of using the flotation process to separate plastics[J].International Journal of Engineering,2011,3:275-278
    [13] WANG C Q, WANG H, LIU Y N. Separation of polyethylene terephthalate from municipal waste plastics by froth flotation for recycling industry[J]. Waste Management,2015,35:42-47
    [14] WANG C Q, WANG H, LIU Q, et al. Separation of polycarbonate and acrylonitrile-butadiene-styrene waste plastics by froth flotation combined with ammonia pretreatment[J]. Waste Management,2014, 34(12):2656-2661
    [15] WANG C Q, WANG H, WU B X, et al. Boiling treatment of ABS and PS plastics for flotation separation[J]. Waste Management,2014,34(7):1206-1210
    [16] LI Y P, YANG L W, ZHU T T, et al. Biosurfactants as alternatives to chemosynthetic surfactants in controlling bubble behavior in the flotation process[J]. Journal of Surfactants & Detergents,2012,16(3):409-419
    [17] LI Y, ZHU T, LIU Y, et al. Effects of surfactant on bubble hydrodynamic behavior under flotation-related conditions in wastewater[J]. Water Science & Technology,2012,65(6):1060-1066
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  • 收稿日期:  2017-01-03
  • 刊出日期:  2017-11-15

基于碱液预处理的泡沫浮选法分离PVC/PET

  • 1. 长安大学环境科学与工程学院, 西安 710064
  • 收稿日期:  2017-01-03
基金项目:

国家自然科学基金资助项目（51208059，41230314）

中央高校基本科研业务费专项（310829163406，310829172001）

摘要: 为优化聚氯乙烯（PVC）和聚对苯二甲酸乙二醇酯（PET）废旧混合塑料的浮选分离效果，采用碱液预处理的方式，结合松油醇（TP）作为浮选药剂，以PVC在上浮产物中的回收率及纯度为考核指标，详细考察了不同参数对浮选效果的影响。结果表明：分离PVC/PET混合物的最优工艺为NaOH质量分数2%，预处理时间15 min，预处理温度70℃，TP浓度35 mg·L-1，浮选时间2 min。在上述最优工艺参数下，混合物中PVC作为上浮产物的回收率和纯度分别可达83%和100%。实验结果对PVC/PET分选的实际应用具有重要的指导意义。

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