Li Yumei, Chen Lirong, Du Mingzhan. Preparation of coagulant from fly ash and its application in Yellow River water treatment[J]. Chinese Journal of Environmental Engineering, 2013, 7(4): 1346-1350.
Citation: Li Yumei, Chen Lirong, Du Mingzhan. Preparation of coagulant from fly ash and its application in Yellow River water treatment[J]. Chinese Journal of Environmental Engineering, 2013, 7(4): 1346-1350.

Preparation of coagulant from fly ash and its application in Yellow River water treatment

  • Received Date: 05/06/2012
    Accepted Date: 21/02/2012
    Available Online: 09/04/2013
    Fund Project:
  • Coagulant was prepared with fly ash and iron mud, adding a certain amount of NaCl as cosolvent at room temperature. Effect of ratio of HCl to fly ash and HCl concentration on Fe3+ and Al3+ dissolution rate and coagulation performance on Yellow River water were investigated. The result showed that the optimal dissolution conditions of Fe3+ and Al3+ were HCl to fly ash ratio of 3 mL/g and HCl concentration of 4 mol/L. At the same time, Fe3+ concentration was 11.81 g/L with dissolution rate of 28.1%. Al3+ concentration was 1.86 g/L with dissolution rate of 5.2%. Furthermore, the optimal coagulation effect to Yellow River water was attained at dosage of 2.38 mL/L, sedimentation time of 30 min, pH 6.2~7.5, and the removal efficiency of turbidity, SS and CODMn could reach about 89.7%, 83.6% and 62.3%, respectively, so the water treatment effect of coagulant here is better than that of PAC and FC from market. AS co-exist of Fe3+ and Al3+ can better play their respective advantages, the coagulation effect can be enhanced.
  • [1] 刘转年,赵西成,田平安,等.粉煤灰基混凝剂制备及处理印钞废水研.环境工程学报,2009,3(4):621-624 Liu Zhuannian,Zhao Xicheng,Tian Pingan, et al. Study on preparation of coal fly ahs based coagulant and its use in bank note printing wastewater treatment. Chinese Journal of Environmental Engineering, 2009,3(4):621-624(in Chinese)

    Google Scholar Pub Med

    [2] 李亚强,汤凤,胡凯,等.酸溶粉煤灰制备混凝剂及处理污水效果.哈尔滨工业大学学报,2008,40(8):1238-1241 Li Yanqiang,Tang Feng,Hu Kai, et al. Production of fly ash-based coagulant and its application in sewage treatment.Journal of Harbin Insttute of Technology, 2008,40(8):1238-1241(in Chinese)

    Google Scholar Pub Med

    [3] 马悦红.粉煤灰特性及综合利用.西北电力技术,2004,32(3):45-48 Ma Yuehong. Fly-ash character and its utilization. Northwest China Electric Power, 2004,32(3):45-48(in Chinese)

    Google Scholar Pub Med

    [4] 陈文道.粉煤灰综合利用技术现状.化学工业与工程技术,1997,18(4):23-27 Chen Wendao. Status of coal-ash comprehensive utilization. Journal of Chemical Industry & Engineering, 1997,18(4):23-27(in Chinese)

    Google Scholar Pub Med

    [5] 李亚强,胡凯,赵庆良,等.酸浸粉煤灰制备复合混凝剂及其处理生活污水的效果研究.环境科学,2007,28(11):2507-2514 Li Yanqiang, Hu Kai, Zhao Qingliang, et al. Preparation of a composite coagulant from fly ash and its application in domestic wastewater treatment.Environmental Science,2007,28(11):2507-2514(in Chinese)

    Google Scholar Pub Med

    [6] 国家环境保护总局.水和废水监测分析方法(第4版).北京:中国环境科学出版社,2002

    Google Scholar Pub Med

    [7] 武汉大学化学与分子科学学院实验中心.分析化学实验.武汉:武汉大学出版社,2003

    Google Scholar Pub Med

    [8] 徐佩瑶,丁志农.粉煤灰、硫铁矿渣制备聚铁铝硅混凝剂及应用研究.环境工程,2000,18(2):46-49 Xu Peiyao,Ding Zhinong. Study of preparation and application of polybengala-alumina-silica coagulant using fly ash and pyrite residue. Environmental Engineering, 2000,18(2):46-49(in Chinese)

    Google Scholar Pub Med

    [9] Seidel A., Zinnels Y. Mechanism and kinetics of aluminum and iron leaching from coal fly ash by sulfuric acid. Chemical Engineering Science,1998,53(22):3835-3852

    Google Scholar Pub Med

    [10] 钱觉时,王智,吴传明.粉煤灰的矿物组成(中).粉煤灰综合利用,2001,(2):40-41 Qian Jueshi, Wang Zhi,Wu Chuanming. Mineral composition of fly ash (the second part). Fly Ash Comprehensive Utilization,2001,(2):40-41(in Chinese)

    Google Scholar Pub Med

    [11] 李亚强,胡凯,赵庆良,等.粉煤灰制备聚硫酸铝铁混凝剂及处理乳品废水的效果.给水排水,2008,34(5):210-214 Li Yanqiang, Hu Kai,Zhao Qingliang, et al. Poly sulfate aluminum ferric coagulant prepared with fly ash and the effect of treatment of milk wastewater. Water & Wastewater Engineering, 2008,34(5):210-214(in Chinese)

    Google Scholar Pub Med

    [12] 徐晓军.化学絮凝剂作用原理.北京:科学出版社,2002.124-129

    Google Scholar Pub Med

    [13] Hiemenz P. C.胶体与表面化学原理.北京:北京大学出版社,1986

    Google Scholar Pub Med

    [14] 曹百川,高宝玉,许春华,等.pH对铁盐混凝剂处理黄河水效果及生成絮体的影响.科学通报,2010,55(9):758-763 Cao Baichuan,Gao Baoyu,Xu Chunhua, et al. Effect of pH on the iron salt coagulant in the Yellow River treatment and flocs generation. Chinese Science Bulletin, 2010,55(9):758-763(in Chinese)

    Google Scholar Pub Med

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Preparation of coagulant from fly ash and its application in Yellow River water treatment

Fund Project:

Abstract: Coagulant was prepared with fly ash and iron mud, adding a certain amount of NaCl as cosolvent at room temperature. Effect of ratio of HCl to fly ash and HCl concentration on Fe3+ and Al3+ dissolution rate and coagulation performance on Yellow River water were investigated. The result showed that the optimal dissolution conditions of Fe3+ and Al3+ were HCl to fly ash ratio of 3 mL/g and HCl concentration of 4 mol/L. At the same time, Fe3+ concentration was 11.81 g/L with dissolution rate of 28.1%. Al3+ concentration was 1.86 g/L with dissolution rate of 5.2%. Furthermore, the optimal coagulation effect to Yellow River water was attained at dosage of 2.38 mL/L, sedimentation time of 30 min, pH 6.2~7.5, and the removal efficiency of turbidity, SS and CODMn could reach about 89.7%, 83.6% and 62.3%, respectively, so the water treatment effect of coagulant here is better than that of PAC and FC from market. AS co-exist of Fe3+ and Al3+ can better play their respective advantages, the coagulation effect can be enhanced.

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