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Chu Jinyu, Zhong Lei. Photocatalytic degradation of methylene blue via side-glowing optical fiber under visible light[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 1035-1039.
Citation: Chu Jinyu, Zhong Lei. Photocatalytic degradation of methylene blue via side-glowing optical fiber under visible light[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 1035-1039.
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Photocatalytic degradation of methylene blue via side-glowing optical fiber under visible light

  • 1.

    Branch Center of State Key Laboratory of Urban Water Resource and Environment, School of Environment, Jiangsu University, Zhenjiang 212013, China

  • Received Date: 11/10/2011
    Accepted Date: 12/07/2011
    Available Online: 18/03/2013
    Fund Project:
  • The photocatalytic system of side-glowing optical fibers (SOFs) was used to treat dyeing wastewater with high concentration and chroma. In this study, methylene blue (MB) was chosen as goal degradant. Ag+/TiO2 powder was prepared by sol-gel method, and characterized by ultraviolet visible spectroscopy of solid diffuse reflectance (UV-Vis DRS), X-ray diffraction (XRD). Ag+/TiO2 catalytic activity under the visible light irradiation was evaluated. The authors investigated different reaction conditions between quartz core and plastic side-glowing optical fiber system. The impact factors include the dosage of catalyst, quantity of optical fiber, illumination intensity, and pH and so on. The changes of MB degradation efficiency was discussed. The results show that the MB was degraded by more than 90% within 8 h under the conditions that the dosage of Ag+/TiO2 was 11.67 g/L, initial concentration of MB was 20 mg/L, the quality of SOFs was 500, pH was about 11 and the external light source was 300 W.
  • [1] 蔡铁军, 吕晓萌, 邓谦, 等.复合催化剂PWn/TiO2光催化降解甲醛反应的研究.环境科学学报,2005,25(5):618-622Cai Tiejun, Lü Xiaomeng, Deng Qian, et al. Study on the photodegradation of formaldehyde with PWn/TiO2 composite catalysts. Acta Scientiae Circumstantiae, 2005, 25(5): 618-622 (in Chinese)

    Google Scholar Pub Med

    [2] 邓谦, 吕晓萌, 蔡铁军, 等.磷钨酸表面修饰TiO2光催化降解空气污染物.中国环境科学, 2005,25(3):375-379Deng Qian, Lü Xiaomeng, Cai Tiejun, et al. Photocatalytic degradation of air pollutant over TiO2 modified with phosphatotungstic acid. China Environmental Science, 2005, 25(3): 375-379 (in Chinese)

    Google Scholar Pub Med

    [3] 孙奉玉, 吴鸣, 李文钊,等.二氧化钛表面光学特性与催化活性的关系.催化学报,1998,19(2):121-124Sun Fengyu, Wu Ming, Li Wenzhao, et al. Relationship between optical surface properties and photocatalytic activity of titanium dioxide. Chinese Journal of Catalysis, 1998, 19(2): 121-124 (in Chinese)

    Google Scholar Pub Med

    [4] Chia-Hsin Li, yung-Hsu Heish, Wan-Ting Chiu, et al. Study on preparation and photocatalysis performance of Ag/TiO2 and Pt/TiO2 photocatalysis. Separation and Purification Technology, 2007,58(1): 148-151

    Google Scholar Pub Med

    [5] 刘守新,曲振平,韩秀文,等. Ag担载对TiO2光催化活性的影响.催化学报,2004,25(2):133-137Liu Shouxin, Qu Zhenping, Han Xiuwen, et al. Effect of sliver deposition on photocatalytic activity of TiO2. Chinese Journal of Catalysis, 2004, 25(2): 133-137(in Chinese)

    Google Scholar Pub Med

    [6] Xiao hong S. Li.,Glen E. Fryxell, Chongmin Wang, et al. The synthesis of Ag-doped mesoporous TiO2. Microporous and Mesoporous Materials, 2008, 111(1-3): 639-642

    Google Scholar Pub Med

    [7] Pratap Reddy M., Venugopal A., Subrahmanyam M. Hydroxyapatite supported Ag-TiO2, as Escherichia coli disinfection photocatalyst. Water Research, 2007, 41(2): 379-386

    Google Scholar Pub Med

    [8] Subramanian V., Wolf E. Kamat P. V. Semiconductor-metal composite nanostructure. To what extent do metal nanoparticles improve the photocatalytic activity of TiO2 films. Physical Chemistry B, 2001, 105(46): 11439-11446

    Google Scholar Pub Med

    [9] Schwitzgebel J., Ekerdt J. G., Gerischer H., et al. Role of the oxygen molecule and of the photogenerated electron in TiO2-photocatalyzed air oxidation reactions. Physical Chemistry, 1995, 99(15):5633-5638

    Google Scholar Pub Med

    [10] Zhi-Ming Dai, Gerald Burgeth, Francesco Parrino, et al. Visible light photocatalysis by a titania-rhodium(Ⅲ) complex. Journal of Organometallic Chemistry, 2009, 694(7-8): 1049-1054

    Google Scholar Pub Med

    [11] Min Liang, Shiqun Sun, Shuchuan Peng, et al. Study on preparation and improvement of palygorskite-TiO2 as a photocatalytist. Journal of Hefei University of Technology (Nature Science), 2009,32(2): 145-149

    Google Scholar Pub Med

    [12] Rajesh J.Tayade, Ramchandra G. Kulkarni, Raksh V. Jasra. Enhanced photocatalytic activity of TiO2-cated NaY and HY zeolites for the degradation od methylene blue in water. Industry Engineering Chemistry Research, 2007, 46(2): 369-376

    Google Scholar Pub Med

    [13] Tsoukleris D. S., Maggos T., Vassilakos C., et al.Photocatalytic degradation of volatile organics on TiO2 embedded glass spherules. Catalysis Today, 2007, 129(1-2): 96-101

    Google Scholar Pub Med

    [14] 黄徽, 杜玉扣, 戴兢陶, 等. TiO2/ACF 的制备及光催化降解四氯乙烯性能. 感光科学与光化学, 2007,25(2): 123-129Hui Huang, Yukou Du, Jingtao Dai, et al. Prepartation of TiO2/ACF catalysts and their photodegradation on thtrachloroethylene. Photographic Science and Photochemistry, 2007, 25(2):123-129 (in Chinese)

    Google Scholar Pub Med

    [15] Hoffmann M. R., Martin S. T., Choi W., et al. Environmental applications of semiconductor photocatalysis. Chemistry Rev., 1995, 95(1): 69-96

    Google Scholar Pub Med

    [16] jingjing Xu, Yanhui Ao, Degang Fu, et al. Photocatalytic activity on TiO2-coated side-glowing optical fiber reactor under solar light. Photochemistry and Photobiology A: Chemistry, 2008, 199(2-3):165-169

    Google Scholar Pub Med

    [17] Fuxiang Zhang, Xiu Zhang, Jixin Chen, et al. Preparation and characterization of Ag/TiO2 nanoparticle catalyst and its photocatalytic activity. Chinese Journal of Catalysis, 2003,24(11): 877-880

    Google Scholar Pub Med

    [18] Goswami D. Y. A review of engineering developments of aqueous phase solar photocatalytic detoxification and disinfection processes. Journal of Solar Energy Engineering, 1997,119(2): 101-107

    Google Scholar Pub Med

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Photocatalytic degradation of methylene blue via side-glowing optical fiber under visible light

  • Received Date: 11/10/2011
  • Accepted Date: 12/07/2011
  • Available Online: 18/03/2013
Fund Project:

Abstract: The photocatalytic system of side-glowing optical fibers (SOFs) was used to treat dyeing wastewater with high concentration and chroma. In this study, methylene blue (MB) was chosen as goal degradant. Ag+/TiO2 powder was prepared by sol-gel method, and characterized by ultraviolet visible spectroscopy of solid diffuse reflectance (UV-Vis DRS), X-ray diffraction (XRD). Ag+/TiO2 catalytic activity under the visible light irradiation was evaluated. The authors investigated different reaction conditions between quartz core and plastic side-glowing optical fiber system. The impact factors include the dosage of catalyst, quantity of optical fiber, illumination intensity, and pH and so on. The changes of MB degradation efficiency was discussed. The results show that the MB was degraded by more than 90% within 8 h under the conditions that the dosage of Ag+/TiO2 was 11.67 g/L, initial concentration of MB was 20 mg/L, the quality of SOFs was 500, pH was about 11 and the external light source was 300 W.

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