Study on sedimentation rule of iron ion of FGD absorbent liquor
- Received Date: 20/08/2008
- Accepted Date: 09/04/2008
-
Key words:
- sodium alkali /
- FGD /
- neutral membrane electrolysis /
- iron ion sedimentation
Abstract: Sodium bisulfite and sodium sulfite were dissolved in water according to certain proportion to simulate the liquor, and a two-compartment electrolysis cell equipped with a neutral-exchange membrane was used. On basis of the sedimentation phenomenon of iron ion on the cathode, sedimentation rule of iron ion and the relationship between sedimentation of iron ion and various parameters, such as electrolytic voltage, sulfur-to-alkali ration, were investigated. It was showed that the sediment on the cathode was FeS and sedimentation mass was found to increase with the increment in electrolytic voltage and the rate of sulfur and alkali. In addition, voltage dropout of cathode cell decreased and the voltage dropout of neutral-exchange membrane increased with the increase of the sedimentation mass of iron ion on the membrane and cathode in the membrane electrolysis process.