Li Yue, Wang Peng, Zhao Baoxiu. Kinetic and photo-electro cooperation effect on degrading dimethy phthalate in TiO2 /Ni PECO system[J]. Chinese Journal of Environmental Engineering, 2009, 3(2): 293-297.
Citation: Li Yue, Wang Peng, Zhao Baoxiu. Kinetic and photo-electro cooperation effect on degrading dimethy phthalate in TiO2 /Ni PECO system[J]. Chinese Journal of Environmental Engineering, 2009, 3(2): 293-297.

Kinetic and photo-electro cooperation effect on degrading dimethy phthalate in TiO2 /Ni PECO system

  • Received Date: 25/07/2008
    Accepted Date: 12/06/2008
    Fund Project:
  • A TiO2 /Ni photoelectrocatalytic oxdition (PECO) system was established with TiO2/Ni photoelectrode prepared by microwaveassisted method as anode, graphite felt(GF) as cathode and saturated calomel electrode (SCE)as reference electrode. DMP (dimethy phthalate) was used as target compound to investigate the photoelectrocatalytic degradation kinetics and photoelectro cooperation effect. The result shows that degradation of DMP accords with pseudo firstorder kinetics law. When initial concentration of DMP was kept constant, factors influencing the photoelectrocatalytic degradation rate were obtained, which were, from strong to weak, effective area of TiO2/Ni photoelectrode, UV light intensity, oxygenation rate and external deflection voltage. Photoelectric had a synergistic effect on the degradation of DMP.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Kinetic and photo-electro cooperation effect on degrading dimethy phthalate in TiO2 /Ni PECO system

Fund Project:

Abstract: A TiO2 /Ni photoelectrocatalytic oxdition (PECO) system was established with TiO2/Ni photoelectrode prepared by microwaveassisted method as anode, graphite felt(GF) as cathode and saturated calomel electrode (SCE)as reference electrode. DMP (dimethy phthalate) was used as target compound to investigate the photoelectrocatalytic degradation kinetics and photoelectro cooperation effect. The result shows that degradation of DMP accords with pseudo firstorder kinetics law. When initial concentration of DMP was kept constant, factors influencing the photoelectrocatalytic degradation rate were obtained, which were, from strong to weak, effective area of TiO2/Ni photoelectrode, UV light intensity, oxygenation rate and external deflection voltage. Photoelectric had a synergistic effect on the degradation of DMP.

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