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LI Ping, YI Chengwu, LI Wenhao, LI Jue, WANG Jing. Chemical reaction kinetics simulation of NO removal by strong ionization discharge[J]. Chinese Journal of Environmental Engineering, 2017, 11(9): 5078-5083. doi: 10.12030/j.cjee.201609250
Citation: LI Ping, YI Chengwu, LI Wenhao, LI Jue, WANG Jing. Chemical reaction kinetics simulation of NO removal by strong ionization discharge[J]. Chinese Journal of Environmental Engineering, 2017, 11(9): 5078-5083. doi: 10.12030/j.cjee.201609250
shu

Chemical reaction kinetics simulation of NO removal by strong ionization discharge

  • 1.

    School of Environmental and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

  • Received Date: 19/12/2016
    Accepted Date: 30/09/2016
    Available Online: 26/08/2017
    Fund Project:
  • The removal of NO by strong ionization discharge is an interdisciplinary subject, which involves chemistry, physics and environmental engineering. The removal process is a series of essentially micro process. It is difficult to research through experiments directly. Therefore, a chemical model was developed to obtain NO removal mechanism by using MATLAB to carry out numerical simulation. Results obtained from the model indicated that ·O and ·OH were produced in a large amount at 800 μs, while the amount of ·N was rather small. Thus, the removal of NO was mainly achieved by reacting with ·O and ·OH. In the process of removal, NO was firstly oxidized into NO2 and eventually converted into HNO3.Concurrently, the validity of the model was verified by experiments. Experimental results showed that the NO removal rate decreased gradually with the increase of NO initial concentration and increased significantly with the increase of oxygen content.
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Chemical reaction kinetics simulation of NO removal by strong ionization discharge

  • Received Date: 19/12/2016
  • Accepted Date: 30/09/2016
  • Available Online: 26/08/2017
Fund Project:

Abstract: The removal of NO by strong ionization discharge is an interdisciplinary subject, which involves chemistry, physics and environmental engineering. The removal process is a series of essentially micro process. It is difficult to research through experiments directly. Therefore, a chemical model was developed to obtain NO removal mechanism by using MATLAB to carry out numerical simulation. Results obtained from the model indicated that ·O and ·OH were produced in a large amount at 800 μs, while the amount of ·N was rather small. Thus, the removal of NO was mainly achieved by reacting with ·O and ·OH. In the process of removal, NO was firstly oxidized into NO2 and eventually converted into HNO3.Concurrently, the validity of the model was verified by experiments. Experimental results showed that the NO removal rate decreased gradually with the increase of NO initial concentration and increased significantly with the increase of oxygen content.

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