摘要:
旨在为桑园及周围农田合理选择和使用农药提供科学依据,采用食下毒叶法测定了农业生产上常用的21种杀菌剂对家蚕的急性毒性,并进行了风险评价。急性毒性测定结果表明:20%苯醚甲环唑微乳剂、10%氟硅唑水乳剂、12.5%腈菌唑水乳剂、12.5%烯唑醇可湿性粉剂和70%噁霉灵可湿性粉剂对家蚕的96 h-LC50值为46.5(41.9~54.0)~154(124~207) mg·L-1,属于中毒级;20%叶枯唑可湿性粉剂、720 g·L-1百菌清悬浮剂、10%醚菌酯水乳剂、2%春雷霉素水分散粒剂、430 g·L-1戊唑醇悬浮剂、400 g·L-1嘧霉胺悬浮剂、40%丙环唑微乳剂、45%咪鲜胺微乳剂、80%烯酰吗啉水分散粒剂、24%井冈霉素可溶性粉剂、250 g·L-1己唑醇悬浮剂、15%三唑酮水乳剂、70%苯醚甲环唑·咪鲜胺可湿性粉剂、50%苯甲·丙环唑乳油、36%丙环·咪鲜胺水乳剂和600 g·L-1烯酰·百菌清悬浮剂16种杀菌剂对家蚕的96 h-LC50值均大于200 mg·L-1,属于低毒级。急性风险评价结果表明:20%叶枯唑可湿性粉剂、720 g·L-1百菌清悬浮剂、24%井冈霉素可溶性粉剂和600 g·L-1烯酰·百菌清悬浮剂对家蚕的96 h-LC50值均大于2 000 mg·L-1,故没有进行风险评价,20%苯醚甲环唑微乳剂、10%氟硅唑水乳剂、12.5%腈菌唑水乳剂、70%噁霉灵可湿性粉剂、400 g·L-1嘧霉胺悬浮剂、45%咪鲜胺微乳剂和80%烯酰吗啉水分散粒剂7种药剂对家蚕具有高风险,其他10种药剂对家蚕具有中等风险。因此,在桑园和桑园附近大田使用杀菌剂时,应采取适宜措施降低其对家蚕的急性毒性风险,以免对桑蚕生产造成危害。
关键词:
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杀菌剂
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家蚕
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急性毒性
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风险评价
Abstract:
To provide scientific basis for appropriate selection and application of pesticides in mulberry gardens as well as surrounding agricultural fields, acute toxicities of 21 commonly used fungicides to silkworm (Bombyx mori) were evaluated in the laboratory using the leaf dipping method, and the risk assessment for these fungicides was also made accordingly. The toxicity test results indicated that the 96 h-LC50 values of 20% ME difenoconazole, 10% EW flusilazole, 12.5% EW myclobutanil, 12.5% WP diniconazole and 70% WP hymexazol ranged between 46.5(41.9-54.0) and 154 (124-207) mg·L -1, which were classified as middle-level toxicity, and the 96 h-LC50 values of 20% WP bismerthiazol, 720 g·L -1 SC chlorothalonil, 10% EW kresoxim-methyl, 2% WG kasugamycin, 430 g·L-1 SC tebuconazole, 400 g·L-1 SC pyrimethanil, 40% ME propiconazol, 45% ME prochloraz, 80% WG dimethomorph, 24% SP jingangmycin, 250 g·L-1 SC hexaconazole, 15% EW triadimefon, 70% WP difenoconazole prochloraz, 50% EC difenoconazole propiconazol, 36% EW propiconazol prochloraz and 600 g·L-1 SC dimethomorph chlorothalonil were higher than 200 mg·L-1, which were classified as low-level toxicity. The acute risk assessment results showed that (1) because the 96 h-LC50 values of 20% WP bismerthiazol, 720 g·L-1 SC chlorothalonil, 24% SP jingangmycin and 600 g·L-1 SC dimethomorph chlorothalonil were higher than 2 000 mg·L-1, no risk assessment for these four fungicides were made; (2) the acute risk of seven fungicides such as 10% EW flusilazole, 12.5% EW myclobutanil, 20% ME difenoconazole, 70% WP hymexazol, 400 g·L-1 SC pyrimethanil, 45% ME prochloraz and 80% WG dimethomorph were high; (3) the acute risk of the other ten fungicides were intermediate. It is indicated that when fungicides are applied in or near mulberry fields, measures should be taken to reduce the risk of acute toxicity to silkworm caused by fungicides in order to avoid harm to the silk production.