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再生水灌溉区土壤对头孢噻肟的吸附特征

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虞敏达, 张媛, 张慧, 檀文炳, 高如泰, 席北斗, 杨津津. 再生水灌溉区土壤对头孢噻肟的吸附特征[J]. 环境工程学报, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
引用本文: 虞敏达, 张媛, 张慧, 檀文炳, 高如泰, 席北斗, 杨津津. 再生水灌溉区土壤对头孢噻肟的吸附特征[J]. 环境工程学报, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
shu
Yu Minda, Zhang Yuan, Zhang Hui, Tan Wenbing, Gao Rutai, Xi Beidou, Yang Jinjin. Adsorption characteristics of cefotaxime in reclaimed water irrigated soil[J]. Chinese Journal of Environmental Engineering, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
Citation: Yu Minda, Zhang Yuan, Zhang Hui, Tan Wenbing, Gao Rutai, Xi Beidou, Yang Jinjin. Adsorption characteristics of cefotaxime in reclaimed water irrigated soil[J]. Chinese Journal of Environmental Engineering, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
shu

再生水灌溉区土壤对头孢噻肟的吸附特征

  • 1.

    常州大学环境与安全工程学院, 常州 213164

  • 2.

    中国环境科学研究院地下水环境系统创新基地, 北京 100012

  • 3.

    武汉大学环境学院, 武汉 430072

  • 基金项目:

    国家"水体污染控制与治理"科技重大专项(2012ZX07203-003)

  • 中图分类号: X703

Adsorption characteristics of cefotaxime in reclaimed water irrigated soil

  • 1.

    School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China

  • 2.

    Innovation Base of Ground Water & Environmental System Engineering, Chinese Research Academy of Environmental Sciences, Beijing 100012, China

  • 3.

    Environmental College, Wuhan University, Wuhan 430072, China

  • Fund Project:

摘要

  • 摘要: 采用批吸附实验法比较了再生水灌溉区汪洋沟流域两种土壤和底泥对头孢噻肟的吸附及其动力学特性,并探讨了土壤与底泥不同pH、阳离子强度及可溶性腐殖酸对头孢噻肟吸附能力的影响。结果表明:汪洋沟段清水灌溉土壤、污水灌溉土壤及底泥均对头孢噻肟有较强的吸附能力,对头孢噻肟的吸附能力从强到弱依次为清水灌溉土壤>污水灌溉土壤>底泥。土壤与底泥对头孢噻肟的吸附行为通过等温吸附模型模拟,其中Freundlich方程拟合效果最好。在pH 4.0~9.0的范围内,土壤与底泥对头孢噻肟的吸附系数随着pH的增大而减少;随着土壤溶液中阳离子浓度的增加,头孢噻肟的吸附量呈非线性减少趋势;添加可溶性腐殖酸后的土壤对头孢噻肟的吸附能力减弱。
    Abstract: In this paper,the adsorption and dynamic characteristics of two kinds of soils and sediments from reclaimed water irrigated Wangyanggou basin on cefotaxime sodium were compared with batch sorption methods.The influences from pH value,positive ironic strength and soluble humic acid of soils and sediments on the adsorption capacity of cefotaxime sodium were studied.The results showed that both of the soils from fresh water and reclaimed water irrigated area,and sediments in Wangyanggou basin kept strong adsorption on cefotaxime sodium.The adsorption capacity from stronger to weaker was fresh water irrigated soil>reclaimed water irrigated soil>sediment.The adsorption behavior of soils and sediments on cefotaxime sodium was fitted by some isotherm models,and the Freundlich model was the best one.In the pH range of 4.0-9.0,the adsorption coefficients of soils and sediments on cefotaxime sodium decreased with the increase of pH value.As the positive ions increasing in the soil solution,the adsorption capacity on cefotaxime sodium appeared a non-linear downward trend.The adsorption capacity on cefotaxime sodium of soil with adding soluble humic acid became weaker.
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出版历程
  • 收稿日期:  2014-12-30
  • 刊出日期:  2016-01-25
虞敏达, 张媛, 张慧, 檀文炳, 高如泰, 席北斗, 杨津津. 再生水灌溉区土壤对头孢噻肟的吸附特征[J]. 环境工程学报, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
引用本文: 虞敏达, 张媛, 张慧, 檀文炳, 高如泰, 席北斗, 杨津津. 再生水灌溉区土壤对头孢噻肟的吸附特征[J]. 环境工程学报, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
shu
Yu Minda, Zhang Yuan, Zhang Hui, Tan Wenbing, Gao Rutai, Xi Beidou, Yang Jinjin. Adsorption characteristics of cefotaxime in reclaimed water irrigated soil[J]. Chinese Journal of Environmental Engineering, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
Citation: Yu Minda, Zhang Yuan, Zhang Hui, Tan Wenbing, Gao Rutai, Xi Beidou, Yang Jinjin. Adsorption characteristics of cefotaxime in reclaimed water irrigated soil[J]. Chinese Journal of Environmental Engineering, 2016, 10(1): 421-426. doi: 10.12030/j.cjee.20160170
shu

再生水灌溉区土壤对头孢噻肟的吸附特征

  • 1.  常州大学环境与安全工程学院, 常州 213164
  • 2.  中国环境科学研究院地下水环境系统创新基地, 北京 100012
  • 3.  武汉大学环境学院, 武汉 430072
  • 收稿日期:  2014-12-30
基金项目:

国家"水体污染控制与治理"科技重大专项(2012ZX07203-003)

摘要: 采用批吸附实验法比较了再生水灌溉区汪洋沟流域两种土壤和底泥对头孢噻肟的吸附及其动力学特性,并探讨了土壤与底泥不同pH、阳离子强度及可溶性腐殖酸对头孢噻肟吸附能力的影响。结果表明:汪洋沟段清水灌溉土壤、污水灌溉土壤及底泥均对头孢噻肟有较强的吸附能力,对头孢噻肟的吸附能力从强到弱依次为清水灌溉土壤>污水灌溉土壤>底泥。土壤与底泥对头孢噻肟的吸附行为通过等温吸附模型模拟,其中Freundlich方程拟合效果最好。在pH 4.0~9.0的范围内,土壤与底泥对头孢噻肟的吸附系数随着pH的增大而减少;随着土壤溶液中阳离子浓度的增加,头孢噻肟的吸附量呈非线性减少趋势;添加可溶性腐殖酸后的土壤对头孢噻肟的吸附能力减弱。

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