铁炭微电解法降解布洛芬的研究

朱宏, 胡翔. 铁炭微电解法降解布洛芬的研究[J]. 环境工程学报, 2013, 7(5): 1735-1738.
引用本文: 朱宏, 胡翔. 铁炭微电解法降解布洛芬的研究[J]. 环境工程学报, 2013, 7(5): 1735-1738.
Zhu Hong, Hu Xiang. Study on degradation of ibuprofen by iron-carbon micro-electrolysis[J]. Chinese Journal of Environmental Engineering, 2013, 7(5): 1735-1738.
Citation: Zhu Hong, Hu Xiang. Study on degradation of ibuprofen by iron-carbon micro-electrolysis[J]. Chinese Journal of Environmental Engineering, 2013, 7(5): 1735-1738.

铁炭微电解法降解布洛芬的研究

  • 基金项目:

    国家自然科学基金资助项目(50878014)

    北京市自然科学基金资助项目(8082019)

    北京市教委重点学科共建项目(环境工程)

  • 中图分类号: X703.1

Study on degradation of ibuprofen by iron-carbon micro-electrolysis

  • Fund Project:
  • 摘要: 药品和个人护理用品(PPCPs)是一类新兴有机污染物,对环境存在潜在的威胁,已引起国内外的广泛关注。以典型PPCPs物质-布洛芬(2-(4-异丁基苯基)丙酸)作为研究对象,采用铁炭微电解法对其进行降解处理,考察了影响布洛芬去除效率的主要因素,确定了各影响因素的最佳操作条件为:离子浓度0.8 g/L,反应时间120 min,铁屑用量1.5 g/L,铁炭质量比2:1,pH为4.0;在此条件下,布洛芬去除率可达80%以上,布洛芬降解过程符合一级反应动力学。
  • [1] Suarez S., Lerna J. M., Omil F. Pre-treatment of hospital wastewater by coagulation-flocculation and flotation. Bioresource Technology, 2009, 100(7): 2138-2146
    [2] Nowotny N., Epp B., Von S. C., et al. Quantification and modeling of the elimination behavior of ecologically problematic wastewater micropollutants by adsorption on powdered and granulated activated carbon. Environmental Science & Technology, 2007, 41(6): 2050-2055
    [3] Yoon Y., Westerhoff P., Snyder S. A., et al. Nanofiltration and ultrafiltration of endocrine disrupting compounds, pharmaceuticals and personal care products. Journal of Membrane Science, 2006, 270(1-2): 88-100
    [4] Nakada N., Shinohara H., Murata A., et al. Removal of selected pharmaceuticals and personal care products (PPCPs) and endocrine-disrupting chemicals (EDCs) during sand filtration and ozonation at a municipal sewage treatment plant. Water Research, 2007, 41(19): 4373-4382
    [5] Esplugas S., Bila D. M., Krause L. G. T. Ozonation and advanced oxidation technologies to remove endocrine disrupting chemicals (EDCs) and pharmaceuticals and personal care products (PPCPs) in water effluents. Journal of Hazardous Materials, 2007, 149(3): 631-642
    [6] Suarez S., Carballa M. How are pharmaceutical and personal care products (PPCPs) removal from urban wastewater. Reviews in Environmental Science & Biotechnology, 2008, 7(2): 125-138
    [7] Matamoros V., Garcia J., Bayona J. M. Organic micropollutant removal in a full-scale surface flow constructed wetland fed with secondary effluent. Water Research, 2008, 42(3): 653-660
    [8] Matamoros V., Bayona J. M. Behavior of emerging pollutants in constructed wetlands. The Handbook of Environment Chemistry, 2008, 5S(2): 199-217
    [9] Hordern B. K., Dinsdale R. M., Guwy A. J. The removal of pharmaceuticals, personal care products, endocrine disruptors and illicit drugs during wastewater treatment and its impact on the quality of receiving waters. Water Research, 2009, 43(2): 363-380.
    [10] Carballa M., Omil F., Ternes T., et al. Fate of pharmaceutical and personal care products (PPCPs) during anaerobic digestion of sewage sludge. Water Research, 2007, 41(10): 2139-2150
    [11] 张丽杰, 陈建中. 抗生素制药废水的处理研究. 有色金属, 2005, 55(增刊): 143-146 Zhang L. J., Chen J. Z. Treatment of effluent from antibiotic production. Nonferrous Metal, 2005, 55(supplement):143-146 (in Chinese)
    [12] 何明, 梁振驹, 李红进. 铁屑内电解法处理PCB络合废水.水处理技术, 2008, 34(6): 84-86 He M., Liang Z. J., Li H. J. Treatment of complex wastewater from printed circuit board processing by internal electrolysis with iron filings. Technology of Water Treatment, 2008, 34(6): 84-86 (in Chinese)
    [13] 刘国秀, 程爱华, 王志盈. 微电解法强化生物脱氮的实验及反应. 环境工程学报, 2008, 2(7): 927-931 Liu G. X., Cheng A. H., Wang Z. Y. Research on enhanced biological nitrogen removal by m icro-electrolysis method. Chinese Journal of Environmental Engineering, 2008, 2(7): 927-931 (in Chinese)
    [14] 陈郁, 全燮. 零价铁处理污水的机理及应用. 环境科学研究, 2000, 13(5): 24-26 Chen Y., Quan X. The mechanism of the treatment of wastewater using zero-valent iron and its application. Research of Environmental Sciences, 2000, 13(5): 24-26 (in Chinese)
    [15] 郑土才. 布洛芬、右旋布洛芬及其衍生物的合成进展. 精细化工中间体, 2010, 40(3): 1-7 Zheng T. C. Advances on the synthesis of ibuprofen,dexibuprofen and their derivatives. Fine Chemical Intermediates, 2010, 40(3):1-7 (in Chinese)
    [16] Moldovan Z. Occurrences of pharmaceutical and personal care products as micropollutants in rivers from Romania. Chemosphere, 2006, 64(11): 1808-1817
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出版历程
  • 收稿日期:  2011-12-18
  • 刊出日期:  2013-05-22
朱宏, 胡翔. 铁炭微电解法降解布洛芬的研究[J]. 环境工程学报, 2013, 7(5): 1735-1738.
引用本文: 朱宏, 胡翔. 铁炭微电解法降解布洛芬的研究[J]. 环境工程学报, 2013, 7(5): 1735-1738.
Zhu Hong, Hu Xiang. Study on degradation of ibuprofen by iron-carbon micro-electrolysis[J]. Chinese Journal of Environmental Engineering, 2013, 7(5): 1735-1738.
Citation: Zhu Hong, Hu Xiang. Study on degradation of ibuprofen by iron-carbon micro-electrolysis[J]. Chinese Journal of Environmental Engineering, 2013, 7(5): 1735-1738.

铁炭微电解法降解布洛芬的研究

  • 1. 北京化工大学化学工程学院,北京 100029
基金项目:

国家自然科学基金资助项目(50878014)

北京市自然科学基金资助项目(8082019)

北京市教委重点学科共建项目(环境工程)

摘要: 药品和个人护理用品(PPCPs)是一类新兴有机污染物,对环境存在潜在的威胁,已引起国内外的广泛关注。以典型PPCPs物质-布洛芬(2-(4-异丁基苯基)丙酸)作为研究对象,采用铁炭微电解法对其进行降解处理,考察了影响布洛芬去除效率的主要因素,确定了各影响因素的最佳操作条件为:离子浓度0.8 g/L,反应时间120 min,铁屑用量1.5 g/L,铁炭质量比2:1,pH为4.0;在此条件下,布洛芬去除率可达80%以上,布洛芬降解过程符合一级反应动力学。

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