高碱度水库水混凝过程中残留铝控制

郭婷婷, 刘锐平, 易秀, 陈桂霞, 胡承志. 高碱度水库水混凝过程中残留铝控制[J]. 环境工程学报, 2013, 7(3): 836-842.
引用本文: 郭婷婷, 刘锐平, 易秀, 陈桂霞, 胡承志. 高碱度水库水混凝过程中残留铝控制[J]. 环境工程学报, 2013, 7(3): 836-842.
Guo Tingting, Liu Ruiping, Yi Xiu, Chen Guixia, Hu Chengzhi. Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 836-842.
Citation: Guo Tingting, Liu Ruiping, Yi Xiu, Chen Guixia, Hu Chengzhi. Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 836-842.

高碱度水库水混凝过程中残留铝控制

  • 基金项目:

    国家"水体污染控制与治理"科技重大专项(2009ZX07419-005)

    北京市教育委员会共建项目专项资助

  • 中图分类号: X524

Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity

  • Fund Project:
  • 摘要: 针对高碱度水库水源的某水厂残留铝超标问题,选取碱化度(B)与Alb含量不同的3种铝盐絮凝剂,研究不同投量与pH值下混凝效果与残留铝浓度水平。结果表明,碱化度和Alb含量显著影响混凝效果。DOC和浊度的去除率随着3种絮凝剂AlCl3(B=0)、PACl-1(B=1.2)、PACl-2(B=2.2)投量增大而升高。3种絮凝剂投量在1.5~2.0 mg/L(以铝计)范围内,总铝和溶解铝含量最低。对于该水厂自制的絮凝剂PACl-2,可通过降低絮凝剂碱化度,或将水的pH值降低至7~7.5之间,以此可以提高PACl-2混凝效果,而且可以降低出厂水残留铝浓度。考虑工程应用可行性,可优先考虑调整絮凝剂生产工艺。
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    [6] 汪光焘.城市供水行业2000年技术进步发展规划.北京:中国建筑工业出版社,1999
    [7] 崔福义,李名锐,王志红,等.饮用水中铝的危害、来源及现状.哈尔滨建筑大学学报,1997,30(6):51-54 Cui Fuyi,Li Mingrui,Wang Zhihong,et al. The harm,resource and status of aluminum in drinking water. Journal of Harbin University of Civil Engineering and Architecture,1997,30(6):51-54 (in Chinese)
    [8] Shi B.,Wei Q., Wang D.,et al. Coagulation of humic acid: the performance of preformed and non-preformed Al species. Colloids Surf. A, 2007,296(7):141-148
    [9] Zhonglian Yang,Bao Yu Gao, Qin Yan Yue,et al. Effect of pH on the coagulation performance of Al-based coagulants and residual aluminum speciation during the treatment of humic acid-kaolin synthetic water. Journal of Hazardous Materials,2010,178 (2): 596-603
    [10] Steve Kvech,Marc Edwards. Solubility controls on aluminum in drinking water at relatively low and high pH. Water Research,2002,36(2): 4356-4368
    [11] 胡承志. 富含Al13与活性氯絮凝剂的电解制备及性能研究. 北京:中国科学院生态环境研究中心博士学位论文, 2006 Hu Chengzhi. Electrochemical preparation and examination of a coagulant containing high content of Al13 and active chlorine. Beijing: Doctor Dissertation of Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences,2006 (in Chinese)
    [12] Yan M.,Wang D.,Qu J.,et al. Relative importance of hydrolyzed Al(Ⅲ) species (Ala, Alb, and Alc) during coagulation with polyaluminum chloride: A case study with the typical micro-polluted source waters. J. Colloid Interface Sci.,2007,316 (7):482-489
    [13] Bertsch P.M., Thomas G. W., Barnhisel R. I. Characterization hydroxy-aluminum solutions by aluminum-27 nuclear magnetic resonance spectroscopy. Soil Sci.Soc.Am.J,1986, 50(6):825-830
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出版历程
  • 收稿日期:  2012-05-04
  • 刊出日期:  2013-03-18
郭婷婷, 刘锐平, 易秀, 陈桂霞, 胡承志. 高碱度水库水混凝过程中残留铝控制[J]. 环境工程学报, 2013, 7(3): 836-842.
引用本文: 郭婷婷, 刘锐平, 易秀, 陈桂霞, 胡承志. 高碱度水库水混凝过程中残留铝控制[J]. 环境工程学报, 2013, 7(3): 836-842.
Guo Tingting, Liu Ruiping, Yi Xiu, Chen Guixia, Hu Chengzhi. Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 836-842.
Citation: Guo Tingting, Liu Ruiping, Yi Xiu, Chen Guixia, Hu Chengzhi. Control of residual aluminum during coagulation in treatment of reservoir source water with high alkalinity[J]. Chinese Journal of Environmental Engineering, 2013, 7(3): 836-842.

高碱度水库水混凝过程中残留铝控制

  • 1.  中国科学院生态环境研究中心环境水质学国家重点实验室,北京 100085
  • 2.  长安大学环境科学与工程学院, 西安 710064
  • 3.  华北水利水电学院环境与市政工程学院,郑州 450011
基金项目:

国家"水体污染控制与治理"科技重大专项(2009ZX07419-005)

北京市教育委员会共建项目专项资助

摘要: 针对高碱度水库水源的某水厂残留铝超标问题,选取碱化度(B)与Alb含量不同的3种铝盐絮凝剂,研究不同投量与pH值下混凝效果与残留铝浓度水平。结果表明,碱化度和Alb含量显著影响混凝效果。DOC和浊度的去除率随着3种絮凝剂AlCl3(B=0)、PACl-1(B=1.2)、PACl-2(B=2.2)投量增大而升高。3种絮凝剂投量在1.5~2.0 mg/L(以铝计)范围内,总铝和溶解铝含量最低。对于该水厂自制的絮凝剂PACl-2,可通过降低絮凝剂碱化度,或将水的pH值降低至7~7.5之间,以此可以提高PACl-2混凝效果,而且可以降低出厂水残留铝浓度。考虑工程应用可行性,可优先考虑调整絮凝剂生产工艺。

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