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微波辅助双氧水氧化降解水中磺胺二甲嘧啶

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赵方, 张从良, 王岩. 微波辅助双氧水氧化降解水中磺胺二甲嘧啶[J]. 环境工程学报, 2012, 6(11): 4074-4078.
引用本文: 赵方, 张从良, 王岩. 微波辅助双氧水氧化降解水中磺胺二甲嘧啶[J]. 环境工程学报, 2012, 6(11): 4074-4078.
shu
Zhao Fang, Zhang Congliang, Wang Yan. Microwave assisted oxidative degradation of sulfamethazine in water with hydrogen peroxide[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 4074-4078.
Citation: Zhao Fang, Zhang Congliang, Wang Yan. Microwave assisted oxidative degradation of sulfamethazine in water with hydrogen peroxide[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 4074-4078.
shu

微波辅助双氧水氧化降解水中磺胺二甲嘧啶

  • 1.

    郑州大学化工与能源学院,郑州 450001

  • 基金项目:

    河南省自然科学基金资助项目(0611033400)

  • 中图分类号: X592

Microwave assisted oxidative degradation of sulfamethazine in water with hydrogen peroxide

  • 1.

    School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China

  • Fund Project:

摘要

  • 摘要: 采用微波辐照技术辅助双氧水氧化降解水中磺胺二甲嘧啶(SM2),研究了微波辅助双氧水氧化降解水中SM2的影响因素。结果表明,单纯使用微波辐照并不能显著降解SM2,而微波辐照可显著促进双氧水对SM2的氧化作用,提高SM2的降解率。在初始浓度为50 mg/L,微波功率为 900 W,加入0.25 mL质量分数为30%的双氧水,pH值为4的条件下辐照6 min,SM2的降解率可达96.5%,COD去除率为72%。
    Abstract: Using microwave assisted oxidative to degrade sulfamethazine (SM2) with hydrogen peroxide in the water, the impact factors of which were also studied. Experimental results show that the degradation effects of SM2 were not significant when only microwave irradiation was used. However, as hydrogen peroxide added, microwave irradiation can significantly promote the oxidation of SM2 using hydrogen peroxide, as well as improve the degradation efficiency. The rate of degradation and COD removal rate of 50 mg/L SM2 solution were 96.5% and 72%, respectively, under the conditions including microwave power of 900 W for 6 min, 0.25 mL of H2O2(concentration was 30%), pH of 4.
  • [1] Jorgensen S. E., Halling-Sorensen B. Drugs in the environment. Chemosphere, 2000, 40(7): 691-699
    [2] Jongdloed A. W., Lenis N. P. Encironmental concerns about animal manure. Anim. Sci., 1998, 76(10): 2641-2648
    [3] 刁晓平,孙英健,孙振钧,等.磺胺二甲基嘧啶对土壤微生物活动的影响.农业环境科学学报,2005,24(4):694-697 Diao X. P., Sun Y. J., Sun Z. J., et al. Effects of sulfamethazine on microbial activity in different types of soil. J. Agro-Environ. Sci., 2005, 24(4): 694-697(in Chinese)
    [4] 张树清,张夫道,刘秀梅,等.高温堆肥对畜禽粪中抗生素降解和重金属钝化的作用.中国农业科学,2006,39(2):337-343 Zhang S. Q., Zhang F. D., Liu X. M., et al. Degradation of antibiotics and passivation of heavy metals during thermophilic composting process. Scientia Agricultura Sinica, 2006, 39(2): 337-343(in Chinese)
    [5] 刘伟,王慧,陈小军,等.抗生素在环境中降解的研究进展.动物医学进展,2009,30(3):89-94 Liu W., Wang H., Chen X. J., et al. Progress on degradation of antibiotics in environment. Progress in Veterinary Medicine, 2009, 30(3): 89-94(in Chinese)
    [6] Hirsch R., Ternes T., Haberer K. Occurrence of antibiotics in the aquatic environment. Sci. Total. Environ., 1999, 255(1-2): 109-118
    [7] Hirsch R., Ternes T., Haberer K. Determination of antibiotic in different water compartments via liquid chromatography-electrospray tandern mass spectermetry. Chromatog A. 1998, 815(2): 213-223
    [8] Richardson M. L., Bowron J. M. The fate of pharmaceutical chemicals in the aquatic environment: A review. J. Pharm. Pharmacol., 1985, 37(1): 1-12
    [9] Hilton M. J., Thomas K. V. Determination of selected human pharmaceutical compounds in effluent and surface water samples by high-performance liquid chromatography-electrospray tandem mass spectrometry. J. Chromatogr. A. 2003, 1015(1-2): 129-141
    [10] 石晶,王红武,马鲁铭.国内磺胺类废水处理的研究现状.辽宁工学院学报,2006,26(5):326-331 Shi J, Wang H. W., Ma L. M. Actuality study on domestic sulfanilamide wastewater treatment. Journal of Liaoning Institute of Technology, 2006, 26(5): 326-331(in Chinese)
    [11] 田莹莹,尹应武,崔建斌.磺胺含酸废水资源化处理新工艺.硅酸盐通报,2009,28(2):391-394 Tian Y. Y., Yin Y. W., Cui J. B. New technology for treating sulfanilamide wastewater. Bulletin of the Chinese Ceramic Society, 2009, 28(2): 391-394(in Chinese)
    [12] 张敏,李铁,敖永华,等.土壤中磺胺类兽药残留的生态效应及转归.中国农学通报,2011, 27(3):369-373 Zhang M., Li T., Ao Y. H., et al. Ecological effects and fate of veterinary sulfonamide antibiotics residue in soil. Chinese Agricultural Science Bulletin, 2011, 27(3): 369-373(in Chinese)
    [13] 王晔,王光龙.微波降解水相中的多氯联苯.化工进展,2008,27(7):1085-1089 Wang Y., Wang G. L. Degradation of polychlorinated biphenyls in water by microwave irradiation. Chemical Industry and Engineering Progress, 2008, 27(7): 1085-1089(in Chinese)
    [14] 张爱涛,卜龙利,廖建波,等.微波辅助工艺处理天然气净化废水的应用研究.环境工程学报,2010,4(8):1779-1784 Zhang A. T., Bo L. L., Liao J. B., et al. Application study on treatment of natural gas purification wastewater by microwave assisted processes. Chinese Journal of Environmental Engineering, 2010, 4(8): 1779-1784(in Chinese)
    [15] 卜尤利,全燮,陈硕,等.微波辅助催化氧化高浓度含醛废水应用研究.大连理工大学学报,2006, 46(1):25-29 Bo L. L., Juan X., Chen S., et al. Research on application of microwave assisted catalytic oxidation in treatment of high concentration aldehydic wastewater. Journal of Dalian University of Technology, 2006, 46(1): 25-29(in Chinese)
    [16] 赵德明,金宁人,吴纯鑫.微波/过氧化氢系统催化降解苯酚水溶液.化工学报,2007,58(7): 1736-1740 Zhao D. M., Jin N. R., Wu C. X. Degradation of phenol aqueous solution using MW/H2O2 system. Journal of Chemical Industry and Engineering(China), 2007, 58(7): 1736-1740(in Chinese)
    [17] 赵德明,费可方.微波/过氧化氢协同降解苯酚动力学.化工学报,2008,59(1):101-105 Zhao D. M., Fei K. F. Synergetic kinetics of phenol degradation in water by using microwave/H2O2 system. Journal of Chemical Industry and Engineering(China), 2008, 59(1): 101-105(in Chinese)
    [18] 张丽,朱晓东,张燕峰,等.微波强化Fenton氧化处理邻氨基苯甲酸废水.环境科学研究,2009, 22(5):516-520 Zhang L., Zhu X. D., Zhang Y. F., et al. Experimental study on treatment of o-aminobenzoic acid wastewater by microwave-assisted Fenton oxidation process. Research of Environmental Sciences, 2009, 22(5): 516-520(in Chinese)
    [19] 曹俐,李小明,杨麒,等.微波强化氧化处理垃圾渗滤液工艺研究.环境工程学报,2010,4(3):547-551 Cao L., Li X. M, Yang Q., et al. Study on treatment of landfill leachate by microwave enhanced oxidant process. Chinese Journal of Environmental Engineering, 2010, 4(3): 547-551(in Chinese)
    [20] 关卫省,丁湛,刘建,等.微波催化载铁GAC处理乳化油废水研究.郑州大学学报(工学版),2009,30(2):35-39 Guan W. S., Ding Z., Liu J., et al. Experimental research on emulsified oil wastewater treating by microwave catalysis oxidation on GAC carrying Fe-ion. Journal of Zhengzhou University(Engineering Science), 2009, 30(2): 35-39(in Chinese)
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出版历程
  • 收稿日期:  2012-04-05
  • 刊出日期:  2012-11-09
赵方, 张从良, 王岩. 微波辅助双氧水氧化降解水中磺胺二甲嘧啶[J]. 环境工程学报, 2012, 6(11): 4074-4078.
引用本文: 赵方, 张从良, 王岩. 微波辅助双氧水氧化降解水中磺胺二甲嘧啶[J]. 环境工程学报, 2012, 6(11): 4074-4078.
shu
Zhao Fang, Zhang Congliang, Wang Yan. Microwave assisted oxidative degradation of sulfamethazine in water with hydrogen peroxide[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 4074-4078.
Citation: Zhao Fang, Zhang Congliang, Wang Yan. Microwave assisted oxidative degradation of sulfamethazine in water with hydrogen peroxide[J]. Chinese Journal of Environmental Engineering, 2012, 6(11): 4074-4078.
shu

微波辅助双氧水氧化降解水中磺胺二甲嘧啶

  • 1. 郑州大学化工与能源学院,郑州 450001
  • 收稿日期:  2012-04-05
基金项目:

河南省自然科学基金资助项目(0611033400)

摘要: 采用微波辐照技术辅助双氧水氧化降解水中磺胺二甲嘧啶(SM2),研究了微波辅助双氧水氧化降解水中SM2的影响因素。结果表明,单纯使用微波辐照并不能显著降解SM2,而微波辐照可显著促进双氧水对SM2的氧化作用,提高SM2的降解率。在初始浓度为50 mg/L,微波功率为 900 W,加入0.25 mL质量分数为30%的双氧水,pH值为4的条件下辐照6 min,SM2的降解率可达96.5%,COD去除率为72%。

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