合成碳羟基磷灰石对水中双酚A的吸附性能研究

唐文清; 曾荣英; 冯泳兰; 曾光明; 李小明; 余润兰

环境工程学报

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唐文清, 曾荣英, 冯泳兰, 曾光明, 李小明, 余润兰. 合成碳羟基磷灰石对水中双酚A的吸附性能研究[J]. 环境工程学报, 2009, 3(11): 1961-1964.

引用本文:

唐文清, 曾荣英, 冯泳兰, 曾光明, 李小明, 余润兰. 合成碳羟基磷灰石对水中双酚A的吸附性能研究[J]. 环境工程学报, 2009, 3(11): 1961-1964.

Tang Wenqing, Zeng Rongying, Feng Yonglan, Zeng Guangming, Li Xiaoming, Yu Runlan. Study on adsorption characteristic of carbonate hydroxylapatite for biphenol-A from aqueous solution[J]. Chinese Journal of Environmental Engineering, 2009, 3(11): 1961-1964.

Citation:

Tang Wenqing, Zeng Rongying, Feng Yonglan, Zeng Guangming, Li Xiaoming, Yu Runlan. Study on adsorption characteristic of carbonate hydroxylapatite for biphenol-A from aqueous solution[J]. Chinese Journal of Environmental Engineering, 2009, 3(11): 1961-1964.

合成碳羟基磷灰石对水中双酚A的吸附性能研究

1.
衡阳师范学院化学与材料科学系，衡阳 421008
2.
湖南大学环境科学与工程学院，长沙 410082
3.
中南大学资源加工与生物工程学院，长沙 410083
基金项目:
国家“863”高技术研究发展计划项目(2004AA649370)

国家杰出青年科学基金项目(50425927，50225926)

新世纪优秀人才计划支持项目(NCET-04-0770)

湖南省自然科学基金资助项目（07JJ6013）

湖南省重点建设学科资助项目
中图分类号: O647.32,X703.1

Study on adsorption characteristic of carbonate hydroxylapatite for biphenol-A from aqueous solution

1.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008,China
2.
College of Environmental Science and Engineering, Hunan University, Changsha 410082,China
3.
School of Minerals Processing and Bio-Engineering, Central South University，Changsha 410083,China
Fund Project:

摘要: 利用废弃蛋壳为原料、尿素为添加剂，合成纳米碳羟基磷灰石(CHAP)用于吸附水中双酚A（BPA）。利用红外光谱、扫描电镜和X射线能谱测试技术对CHAP样品表面化学进行了表征，同时考察了环境因子pH值、吸附时间和BPA初始浓度对吸附的影响。实验结果表明，CHAP对BPA去除率在酸性（pH=3～6）溶液中较好，而在中性和碱性环境中减弱。通过静态吸附实验数据计算分析得知，CHAP对BPA吸附符合Langmuir和Freundlich等温式，准二级动力学模型比准一级动力学模型能更好地描述CHAP对BPA吸附动力学行为。
- 碳羟基磷灰石 /
- 双酚A /
- 吸附机理
Abstract: The adsorption of biphenol-A（BPA） from aqueous solution by home-made carbonate hydroxylapatite(CHAP) synthesized by using abandoned eggshell and urea was characterized by FT-IR,SEM and EDS. Factors that might influence the adsorption performance were investigated, such as pH values, adsorption period, biphenol-A initial concentration from aqueous solution.The results showed that absorption of biphenol-A on the CHAP was better pH=3～6 than pH>6 from aqueous solution. The equilibrium sorption datas could be described by the Langmuir and Freundlich isotherm models. The second-order kinetic model provided the best correlation of the used experimental data compared to the first-order kinetic model.
- carbonate hydroxylpatite /
- biphenol-A /
- adsorption mechanisms

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唐文清, 曾荣英, 冯泳兰, 曾光明, 李小明, 余润兰. 合成碳羟基磷灰石对水中双酚A的吸附性能研究[J]. 环境工程学报, 2009, 3(11): 1961-1964.

引用本文:

唐文清, 曾荣英, 冯泳兰, 曾光明, 李小明, 余润兰. 合成碳羟基磷灰石对水中双酚A的吸附性能研究[J]. 环境工程学报, 2009, 3(11): 1961-1964.

Citation:

Tang Wenqing, Zeng Rongying, Feng Yonglan, Zeng Guangming, Li Xiaoming, Yu Runlan. Study on adsorption characteristic of carbonate hydroxylapatite for biphenol-A from aqueous solution[J]. Chinese Journal of Environmental Engineering, 2009, 3(11): 1961-1964.

合成碳羟基磷灰石对水中双酚A的吸附性能研究

1. 衡阳师范学院化学与材料科学系，衡阳 421008
2. 湖南大学环境科学与工程学院，长沙 410082
3. 中南大学资源加工与生物工程学院，长沙 410083

收稿日期: 2009-02-03

基金项目:

国家“863”高技术研究发展计划项目(2004AA649370)

国家杰出青年科学基金项目(50425927，50225926)

新世纪优秀人才计划支持项目(NCET-04-0770)

湖南省自然科学基金资助项目（07JJ6013）

湖南省重点建设学科资助项目

关键词:

摘要: 利用废弃蛋壳为原料、尿素为添加剂，合成纳米碳羟基磷灰石(CHAP)用于吸附水中双酚A（BPA）。利用红外光谱、扫描电镜和X射线能谱测试技术对CHAP样品表面化学进行了表征，同时考察了环境因子pH值、吸附时间和BPA初始浓度对吸附的影响。实验结果表明，CHAP对BPA去除率在酸性（pH=3～6）溶液中较好，而在中性和碱性环境中减弱。通过静态吸附实验数据计算分析得知，CHAP对BPA吸附符合Langmuir和Freundlich等温式，准二级动力学模型比准一级动力学模型能更好地描述CHAP对BPA吸附动力学行为。

English Abstract

Study on adsorption characteristic of carbonate hydroxylapatite for biphenol-A from aqueous solution

1. Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008,China
2. College of Environmental Science and Engineering, Hunan University, Changsha 410082,China
3. School of Minerals Processing and Bio-Engineering, Central South University，Changsha 410083,China

Received Date: 2009-02-03

Fund Project:

Keywords:

Abstract: The adsorption of biphenol-A（BPA） from aqueous solution by home-made carbonate hydroxylapatite(CHAP) synthesized by using abandoned eggshell and urea was characterized by FT-IR,SEM and EDS. Factors that might influence the adsorption performance were investigated, such as pH values, adsorption period, biphenol-A initial concentration from aqueous solution.The results showed that absorption of biphenol-A on the CHAP was better pH=3～6 than pH>6 from aqueous solution. The equilibrium sorption datas could be described by the Langmuir and Freundlich isotherm models. The second-order kinetic model provided the best correlation of the used experimental data compared to the first-order kinetic model.

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合成碳羟基磷灰石对水中双酚A的吸附性能研究

Study on adsorption characteristic of carbonate hydroxylapatite for biphenol-A from aqueous solution

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合成碳羟基磷灰石对水中双酚A的吸附性能研究

English Abstract

Study on adsorption characteristic of carbonate hydroxylapatite for biphenol-A from aqueous solution

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