重庆长江流域水体中8种典型环境雌激素污染特征

卓丽, 许榕发, 石运刚, 严骁, 庄僖, 胡凤琦, 刘强, 黄道建. 重庆长江流域水体中8种典型环境雌激素污染特征[J]. 生态毒理学报, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001
引用本文: 卓丽, 许榕发, 石运刚, 严骁, 庄僖, 胡凤琦, 刘强, 黄道建. 重庆长江流域水体中8种典型环境雌激素污染特征[J]. 生态毒理学报, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001
Zhuo Li, Xu Rongfa, Shi Yungang, Yan Xiao, Zhuang Xi, Hu Fengqi, Liu Qiang, Huang Daojian. Estrogens in Surface Water of the Yangtze River in Chongqing Section[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001
Citation: Zhuo Li, Xu Rongfa, Shi Yungang, Yan Xiao, Zhuang Xi, Hu Fengqi, Liu Qiang, Huang Daojian. Estrogens in Surface Water of the Yangtze River in Chongqing Section[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001

重庆长江流域水体中8种典型环境雌激素污染特征

    作者简介: 卓丽(1984-),女,硕士,研究方向为化学品管理与风险防控,E-mail:zhuoli729@163.com
  • 基金项目:

    重庆市生态环境局科研项目"长江干流重庆段环境激素化学品源解析与环境风险评估"(CQGGZX2019008)

  • 中图分类号: X171.5

Estrogens in Surface Water of the Yangtze River in Chongqing Section

  • Fund Project:
  • 摘要: 选择重庆市长江流域为研究区域,调查平水期和蓄水期水体中8种典型环境雌激素雌酮(E1)、雌二醇(E2)、雌三醇(E3)、已烯雌酚(DES)、炔雌醇(EE2)、4-壬基酚(4-NP)、4-辛基酚(4-t-OP)和双酚A(BPA)的浓度、组成和分布特征,并对其雌激素活性进行风险评价。结果表明,重庆市长江流域水体中除E2外,其余7种环境雌激素均有检出,总浓度范围为46.16~10 985.79 ng·L-1,主要污染物为4-NP和BPA。平水期4-t-OP、BPA浓度显著高于蓄水期,而4-NP则相反。空间分布上,各采样位点的环境雌激素污染状况相差较大,并未表现出明显的流向变化趋势或干支流差异。风险评估结果表明,平水期52%的位点及蓄水期22%的位点雌激素总活性高于1 ng·L-1,提示具有高雌激素活性风险,其中,E1为平水期主要雌激素活性贡献物质,而4-NP为蓄水期主要雌激素活性贡献物质。
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  • 收稿日期:  2019-08-07
卓丽, 许榕发, 石运刚, 严骁, 庄僖, 胡凤琦, 刘强, 黄道建. 重庆长江流域水体中8种典型环境雌激素污染特征[J]. 生态毒理学报, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001
引用本文: 卓丽, 许榕发, 石运刚, 严骁, 庄僖, 胡凤琦, 刘强, 黄道建. 重庆长江流域水体中8种典型环境雌激素污染特征[J]. 生态毒理学报, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001
Zhuo Li, Xu Rongfa, Shi Yungang, Yan Xiao, Zhuang Xi, Hu Fengqi, Liu Qiang, Huang Daojian. Estrogens in Surface Water of the Yangtze River in Chongqing Section[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001
Citation: Zhuo Li, Xu Rongfa, Shi Yungang, Yan Xiao, Zhuang Xi, Hu Fengqi, Liu Qiang, Huang Daojian. Estrogens in Surface Water of the Yangtze River in Chongqing Section[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 149-157. doi: 10.7524/AJE.1673-5897.20190807001

重庆长江流域水体中8种典型环境雌激素污染特征

    作者简介: 卓丽(1984-),女,硕士,研究方向为化学品管理与风险防控,E-mail:zhuoli729@163.com
  • 1. 重庆市固体废物管理中心, 重庆 400020;
  • 2. 生态环境部华南环境科学研究所, 国家环境保护环境污染健康风险评价重点实验室, 广州 510655
基金项目:

重庆市生态环境局科研项目"长江干流重庆段环境激素化学品源解析与环境风险评估"(CQGGZX2019008)

摘要: 选择重庆市长江流域为研究区域,调查平水期和蓄水期水体中8种典型环境雌激素雌酮(E1)、雌二醇(E2)、雌三醇(E3)、已烯雌酚(DES)、炔雌醇(EE2)、4-壬基酚(4-NP)、4-辛基酚(4-t-OP)和双酚A(BPA)的浓度、组成和分布特征,并对其雌激素活性进行风险评价。结果表明,重庆市长江流域水体中除E2外,其余7种环境雌激素均有检出,总浓度范围为46.16~10 985.79 ng·L-1,主要污染物为4-NP和BPA。平水期4-t-OP、BPA浓度显著高于蓄水期,而4-NP则相反。空间分布上,各采样位点的环境雌激素污染状况相差较大,并未表现出明显的流向变化趋势或干支流差异。风险评估结果表明,平水期52%的位点及蓄水期22%的位点雌激素总活性高于1 ng·L-1,提示具有高雌激素活性风险,其中,E1为平水期主要雌激素活性贡献物质,而4-NP为蓄水期主要雌激素活性贡献物质。

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