高级搜索

Fenton法降解邻苯二甲酸二乙酯的动力学特征及其影响因素研究

,  ,  ,  ,  ,  , 

downloadPDF

上一篇

下一篇

章琴琴, 丁世敏, 封享华, 余友清, 王捷, 陈凤贵, 黄海燕. Fenton法降解邻苯二甲酸二乙酯的动力学特征及其影响因素研究[J]. 环境化学, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
引用本文: 章琴琴, 丁世敏, 封享华, 余友清, 王捷, 陈凤贵, 黄海燕. Fenton法降解邻苯二甲酸二乙酯的动力学特征及其影响因素研究[J]. 环境化学, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
shu
ZHANG Qinqin, DING Shimin, FENG Xianghua, YU Youqing, WANG Jie, CHEN Fenggui, HUANG Haiyan. Study on the degradation kinetic characteristics and influencing factors of diethyl phthalate by Fenton treatment[J]. Environmental Chemistry, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
Citation: ZHANG Qinqin, DING Shimin, FENG Xianghua, YU Youqing, WANG Jie, CHEN Fenggui, HUANG Haiyan. Study on the degradation kinetic characteristics and influencing factors of diethyl phthalate by Fenton treatment[J]. Environmental Chemistry, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
shu

Fenton法降解邻苯二甲酸二乙酯的动力学特征及其影响因素研究

  • 长江师范学院绿色智慧环境学院, 重庆, 408100

    • 通讯作者: 章琴琴, E-mail: zhangqinqin@yznu.edu.cn ; 
  • 基金项目:

    重庆市自然科学基金（cstc2019jcyj-msxmX0672），重庆市教委科学技术研究项目（KJ1712311，KJ1601209），国家留学基金委（201808505139），重庆市涪陵区科技计划项目（FLKJ2018BBB3020）和长江师范学院科研项目资助.

Study on the degradation kinetic characteristics and influencing factors of diethyl phthalate by Fenton treatment

  • Green Intelligent Environmental School, Yangtze Normal University, Chongqing, 408100, China

    • Corresponding author: ZHANG Qinqin, zhangqinqin@yznu.edu.cn ; 
  • Fund Project: Supported by the Natural Science Foundation of Chongqing (cstc2019jcyj-msxmX0672), the Science and Technology Research Program of Chongqing Municipal Education Commission (KJ1712311, KJ1601209), the National Scholarship Council (201808505139),the Science and Technology Project of Fuling District, Chongqing (FLKJ2018BBB3020) and the Research Project of Yangtze Normal University.

  • 摘要: 邻苯二甲酸二乙酯（diethyl phthalate，DEP）作为典型增塑剂，使用量巨大.DEP是一种环境激素，在环境中广泛检出，会影响生物体的生殖功能.本文研究了Fenton法降解环境浓度水平的典型增塑剂的动力学特征及其影响因素，研究表明，H2O2浓度、Fe2+浓度、pH值及DEP的初始浓度都会对DEP的动力学和降解特征产生不同程度的影响.在pH 3.0，DEP为50 μmol·L-1，亚铁浓度为100 μmol·L-1，过氧化氢浓度为500 μmol·L-1时，反应30 min后，DEP去除率为71%.增加Fe2+与H2O2浓度有利于DEP的去除；水中常见物质Cl-、NO3-、HCO3-与HA共存时，DEP的去除效率受到抑制；反应前9 min，一阶反应速率常数k1值与体系中DEP的初始浓度之间呈负线性相关关系.相对于一阶和二阶动力学，BMG动力学模型是描述Fenton法对低浓度DEP去除过程的最佳模型.DEP浓度、pH、[H2O2]/[Fe2+]摩尔比值与BMG模型中的1/m和1/b存在良好的相关关系（R2>0.9）.
    Abstract: As a typical plasticizer, diethyl phthalate (DEP) is used in a huge amount. DEP is an environmental hormone widely detected in the environment and affects the reproductive function of organisms. Fenton is a commonly used advanced oxidation technology for the removal of refractory organics. In this paper, the kinetic characteristics and influencing factors of typical plasticizer degradation in environmental concentration level by Fenton method were studied. The results showed that concentration of H2O2, concentration of Fe2+, pH value and initial concentration of DEP had different effects on the dynamics and degradation characteristics of DEP. When the pH was 3.0, the concentration of DEP was 50 μmol·L-1, the concentration of Fe2+ was 100 μmol·L-1, and concentration of H2O2 was 500 μmol·L-1, the removal efficiency of DEP reached 71% after 30 min. Increasing the concentrations of Fe2+ and H2O2 was beneficial to improve the removal efficiencies of DEP. When the common substances in water coexisted, such as Cl-, NO3-, HCO3- and HA, the removal efficiencies of DEP were inhibited; There was a negative linear correlation between the first-order reaction rate constant k1 value and the initial concentrations of DEP at the first 9 min. Compared to first-order and second-order kinetics, the BMG kinetic model was the best model to describe the removal of low-concentration DEP by Fenton method.
  • 加载中
  • [1] 章琴琴. 混凝-生物-高级氧化组合工艺处理垃圾渗滤液过程中PAEs的去除研究[D]. 北京:中国科学院大学, 2016. ZHANG Q. Study on technology and mechanism of PAEs in leachate by coagulation-biological-advanced oxidation combination processes[D]. Beijing:University of Chinese Academy of Sciences, 2016(in Chinese).
    [2] MERSIOWSKY I, WELLER M, EJLERTSSON J. Fate of plasticised PVC products under landfill conditions:A laboratory-scale landfill simulation reactor study[J]. Water Research,2001, 35(13):3063-3070.
    [3] 朱方. 环境激素DEP和DBP免疫分析方法研究及其在水环境风险评价中的应用[D]. 镇江:江苏大学, 2017. ZHU F. Study on environmental hormone DEP and DBP immunoassay methods and their application in water environmental risk assessment[D]. Zhenjiang:Jiangsu University, 2017(in Chinese).
    [4] LATINI G, DEL VECCHIO A, MASSARO M, et al. Phthalate exposure and male infertility[J]. Toxicology,2006, 226(2/3):90-98.
    [5] MATSUMOTO M, HIRATA-KOIZUMI M, EMA M. Potential adverse effects of phthalic acid esters on human health:A review of recent studies on reproduction[J]. Regulatory Toxicology and Pharmacology,2008, 50(1):37-49.
    [6] MENG X, WANG Y, XIANG N, et al. Flow of sewage sludge-borne phthalate esters (PAEs) from human release to human intake:Implication for risk assessment of sludge applied to soil[J]. Science of The Total Environment,2014, 476/477:242-249.
    [7] 王云海,张瑞娜,楼紫阳,等.Fenton氧化处理垃圾膜滤浓缩液[J].环境化学, 2017, 36(5):1104-1111.

    WANG Y H, ZHANG R N, LOU Z Y, et al.Fenton oxidation process of concentrated landfill leachate[J].Environmental Chemistry,2017, 36(5):1104-1111(in Chinese).

    [8] 章琴琴,宋诚,华亚妮,等. Fenton法降解垃圾渗滤液中的溶解性有机质[J]. 环境工程学报,2017, 11(4):2219-2226.

    ZHANG Q Q, SONG C, HUA Y N, et al. Study on degradation of dissolved organic matter in landfill leachate by Fenton treatment[J]. Chinese Journal of Environmental Engineering, 2017, 11(4):2219-2226(in Chinese).

    [9] 徐金兰,郭阳,刘博雅. H2O2分次投加对Fenton氧化修复石油污染土壤及后续生物降解的影响[J].环境化学, 2019, 38(6):1266-1273.

    XU J L, GUO Y, LIU B Y. Impact of stepwise addition of H2O2 on Fenton oxidation and subsequent biodegradation of oil-contaminated soil[J]. Environmental Chemistry, 2019,38(6):1266-1273(in Chinese).

    [10] WONGNIRAMAIKUL W, LIAO C, KANATHARANA P. Diisobutyl phthalate degradation by Fenton treatment[J]. Journal of Environmental Science and Health, Part A,2007, 42(5):567-572.
    [11] ZHANG Q Q, WANG C, LEI Y M. Fenton's oxidation kinetics, pathway, and toxicity evaluation of diethyl phthalate in aqueous solution[J]. Journal of Advanced Oxidation Technologies,2016, 19(1):125-133.
    [12] YUAN S Y, LIU C, LIAO C S, et al. Occurrence and microbial degradation of phthalate esters in Taiwan river sediments[J]. Chemosphere,2002, 49(10):1295-1299.
    [13] 吕来,胡春. 多相芬顿催化水处理技术与原理[J]. 化学进展,2017, 29(9):981-999.

    LU L, HU C. Heterogeneous Fenton catalytic water treatment technology and mechanism[J]. Progress in Chemistry, 2017, 29(9):981-999(in Chinese).

    [14] MORAES P B, BERTAZZOLI R. Electrodegradation of landfill leachate in a flow electrochemical reactor[J]. Chemosphere, 2005, 58(1):41-46.
    [15] 郭劲松,林佳琪. 屏蔽氯离子干扰高盐榨菜废水中COD的测定方法[J].重庆大学学报自然科学版,2014, 37(1):117-122.

    GUO J S, LIN J Q. The chloride mask in COD determination of pickled mustard wastewater with high salt[J]. Journal of Chongqing University, 2014, 37(1):117-122(in Chinese).

    [16] BEHNAJADY M A, MODIRSHAHLA N, GHANBARY F. A kinetic model for the decolorization of C.I. Acid Yellow 23 by Fenton process[J]. Journal of Hazardous Materials. 2007, 148(1-2):98-102.
    [17] 李鹏程, 孙文全,刘舒华,等. 光催化氧化技术在饮用水处理中的应用及研究进展[J]. 宁夏农林科技, 2011,52(5):63-64.

    LI P C, SUN W Q, LIU S H, et al. Application and research development of photocatalytic oxidation technology in water treatment[J]. Ningxia Journal of Agriculture and Forestry Science and Technology, 2011, 52(5):63-64(in Chinese).

    [18] LI A, ZHANG Z, LI P, et al. Nitrogen dioxide radicals mediated mineralization of perfluorooctanoic acid in aqueous nitrate solution with UV irradiation[J]. Chemosphere, 2017, 188:367-374.
    [19] SUN J H, SHI S H, LEE Y F, et al. Fenton oxidative decolorization of the azo dye Direct Blue 15 in aqueous solution[J]. Chemical Engineering Journal,2009, 155(3):680-683.
    [20] XU H, SHI T, WU L, et al. Discoloration of methyl orange in the presence of schorl and H2O2:Kinetics and mechanism[J]. Water, Air, & Soil Pollution,2013, 224(10):1-11.
    [21] XU H, YU T, WANG J, et al. Online monitoring of Fenton-mediated reactive red 6B oxidation kinetics[J]. Environmental Progress & Sustainable Energy,2015, 34(4):1019-1027.
    [22] TUNÇ S, GÜRKAN T, DUMAN O. On-line spectrophotometric method for the determination of optimum operation parameters on the decolorization of Acid Red 66 and Direct Blue 71 from aqueous solution by Fenton process[J]. Chemical Engineering Journal,2012, 181-182:431-442.
    [23] EMAMI F, TEHRANI-BAGHA A R, GHARANJIG K, et al. Kinetic study of the factors controlling Fenton-promoted destruction of a non-biodegradable dye[J]. Desalination,2010, 257:124-128.
    [24] PARK C M, HEO J, YOON Y. Oxidative degradation of bisphenol A and 17α-ethinyl estradiol by Fenton-like activity of silver nanoparticles in aqueous solution[J]. Chemosphere, 2017, 168:617-622.
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  2375
  • HTML全文浏览数:  2375
  • PDF下载数:  49
  • 施引文献:  0
出版历程
  • 收稿日期:  2019-08-22
章琴琴, 丁世敏, 封享华, 余友清, 王捷, 陈凤贵, 黄海燕. Fenton法降解邻苯二甲酸二乙酯的动力学特征及其影响因素研究[J]. 环境化学, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
引用本文: 章琴琴, 丁世敏, 封享华, 余友清, 王捷, 陈凤贵, 黄海燕. Fenton法降解邻苯二甲酸二乙酯的动力学特征及其影响因素研究[J]. 环境化学, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
shu
ZHANG Qinqin, DING Shimin, FENG Xianghua, YU Youqing, WANG Jie, CHEN Fenggui, HUANG Haiyan. Study on the degradation kinetic characteristics and influencing factors of diethyl phthalate by Fenton treatment[J]. Environmental Chemistry, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
Citation: ZHANG Qinqin, DING Shimin, FENG Xianghua, YU Youqing, WANG Jie, CHEN Fenggui, HUANG Haiyan. Study on the degradation kinetic characteristics and influencing factors of diethyl phthalate by Fenton treatment[J]. Environmental Chemistry, 2020, (11): 3009-3016. doi: 10.7524/j.issn.0254-6108.2019082201
shu

Fenton法降解邻苯二甲酸二乙酯的动力学特征及其影响因素研究

    通讯作者: 章琴琴, E-mail: zhangqinqin@yznu.edu.cn ; 
  • 长江师范学院绿色智慧环境学院, 重庆, 408100
  • 收稿日期:  2019-08-22
基金项目:

重庆市自然科学基金（cstc2019jcyj-msxmX0672），重庆市教委科学技术研究项目（KJ1712311，KJ1601209），国家留学基金委（201808505139），重庆市涪陵区科技计划项目（FLKJ2018BBB3020）和长江师范学院科研项目资助.

摘要: 邻苯二甲酸二乙酯（diethyl phthalate，DEP）作为典型增塑剂，使用量巨大.DEP是一种环境激素，在环境中广泛检出，会影响生物体的生殖功能.本文研究了Fenton法降解环境浓度水平的典型增塑剂的动力学特征及其影响因素，研究表明，H2O2浓度、Fe2+浓度、pH值及DEP的初始浓度都会对DEP的动力学和降解特征产生不同程度的影响.在pH 3.0，DEP为50 μmol·L-1，亚铁浓度为100 μmol·L-1，过氧化氢浓度为500 μmol·L-1时，反应30 min后，DEP去除率为71%.增加Fe2+与H2O2浓度有利于DEP的去除；水中常见物质Cl-、NO3-、HCO3-与HA共存时，DEP的去除效率受到抑制；反应前9 min，一阶反应速率常数k1值与体系中DEP的初始浓度之间呈负线性相关关系.相对于一阶和二阶动力学，BMG动力学模型是描述Fenton法对低浓度DEP去除过程的最佳模型.DEP浓度、pH、[H2O2]/[Fe2+]摩尔比值与BMG模型中的1/m和1/b存在良好的相关关系（R2>0.9）.

English Abstract

    全文HTML

参考文献 (24)

返回顶部

目录

/

返回文章
返回

Copyright © 2019 中国科学院生态环境研究中心