青霉素G钾在蔬菜地土壤中的降解动力学研究

张紫琴, 张洪昌, 沈根祥, 胡双庆, 顾海蓉, 赵晓祥. 青霉素G钾在蔬菜地土壤中的降解动力学研究[J]. 生态毒理学报, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003
引用本文: 张紫琴, 张洪昌, 沈根祥, 胡双庆, 顾海蓉, 赵晓祥. 青霉素G钾在蔬菜地土壤中的降解动力学研究[J]. 生态毒理学报, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003
Zhang Ziqin, Zhang Hongchang, Shen Genxiang, Hu Shuangqing, Gu Hairong, Zhao Xiaoxiang. Degradation Kinetics of Penicillin G Potassium in a Vegetable Soil System with Compost Application[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003
Citation: Zhang Ziqin, Zhang Hongchang, Shen Genxiang, Hu Shuangqing, Gu Hairong, Zhao Xiaoxiang. Degradation Kinetics of Penicillin G Potassium in a Vegetable Soil System with Compost Application[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003

青霉素G钾在蔬菜地土壤中的降解动力学研究

    作者简介: 张紫琴(1996-),女,硕士研究生,研究方向为抗生素对土壤微生物的作用,E-mail:zhangziqin185@163.com
  • 基金项目:

    基国家水体污染控制与治理科技重大专项资助项目(2017ZX07207002);上海市2016年度"科技创新行动计划"社会发展领域项目(16DZ1204700);长江水环境教育部重点实验室开放课题项目(YRWEF201803)

  • 中图分类号: X171.5

Degradation Kinetics of Penicillin G Potassium in a Vegetable Soil System with Compost Application

  • Fund Project:
  • 摘要: 为确定青霉素G钾(penicillin G potassium,PG)在土壤中的半衰期和降解动力学,选择灭菌与未灭菌、施肥与未施肥蔬菜地土壤作为基质,研究了PG在不同基质中的降解曲线,并拟合了降解动力学方程。结果表明,PG在蔬菜地土壤中的半衰期为1.61~1.67 d,最终降解率均达到99.7%以上,但PG不会完全降解,仍会以较低的水平(21~73 μ g·kg-1)在土壤中长期存在。降解动力学方程拟合结果表明,PG的初始浓度会对降解速率产生影响,初始浓度越高,降解速率越快。在灭菌与未灭菌土壤中降解曲线显示其降解过程受生物和非生物作用共同影响,但添加有机肥的降解过程和未添加组没有显著差异。由于PG在土壤中不能被完全降解,从而增加了诱导抗性基因产生及转移的风险。
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  • 收稿日期:  2019-09-23
张紫琴, 张洪昌, 沈根祥, 胡双庆, 顾海蓉, 赵晓祥. 青霉素G钾在蔬菜地土壤中的降解动力学研究[J]. 生态毒理学报, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003
引用本文: 张紫琴, 张洪昌, 沈根祥, 胡双庆, 顾海蓉, 赵晓祥. 青霉素G钾在蔬菜地土壤中的降解动力学研究[J]. 生态毒理学报, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003
Zhang Ziqin, Zhang Hongchang, Shen Genxiang, Hu Shuangqing, Gu Hairong, Zhao Xiaoxiang. Degradation Kinetics of Penicillin G Potassium in a Vegetable Soil System with Compost Application[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003
Citation: Zhang Ziqin, Zhang Hongchang, Shen Genxiang, Hu Shuangqing, Gu Hairong, Zhao Xiaoxiang. Degradation Kinetics of Penicillin G Potassium in a Vegetable Soil System with Compost Application[J]. Asian Journal of Ecotoxicology, 2020, 15(3): 218-226. doi: 10.7524/AJE.1673-5897.20190923003

青霉素G钾在蔬菜地土壤中的降解动力学研究

    作者简介: 张紫琴(1996-),女,硕士研究生,研究方向为抗生素对土壤微生物的作用,E-mail:zhangziqin185@163.com
  • 1. 东华大学环境科学与工程学院, 上海 201620;
  • 2. 上海市环境科学研究院, 上海 200233
基金项目:

基国家水体污染控制与治理科技重大专项资助项目(2017ZX07207002);上海市2016年度"科技创新行动计划"社会发展领域项目(16DZ1204700);长江水环境教育部重点实验室开放课题项目(YRWEF201803)

摘要: 为确定青霉素G钾(penicillin G potassium,PG)在土壤中的半衰期和降解动力学,选择灭菌与未灭菌、施肥与未施肥蔬菜地土壤作为基质,研究了PG在不同基质中的降解曲线,并拟合了降解动力学方程。结果表明,PG在蔬菜地土壤中的半衰期为1.61~1.67 d,最终降解率均达到99.7%以上,但PG不会完全降解,仍会以较低的水平(21~73 μ g·kg-1)在土壤中长期存在。降解动力学方程拟合结果表明,PG的初始浓度会对降解速率产生影响,初始浓度越高,降解速率越快。在灭菌与未灭菌土壤中降解曲线显示其降解过程受生物和非生物作用共同影响,但添加有机肥的降解过程和未添加组没有显著差异。由于PG在土壤中不能被完全降解,从而增加了诱导抗性基因产生及转移的风险。

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