隔膜电解海水氧化耦合吸收脱硫脱硝净化船舶尾气技术

张欢, 钟鹭斌, 苑志华, 陈进生, 郑煜铭. 隔膜电解海水氧化耦合吸收脱硫脱硝净化船舶尾气技术[J]. 环境工程学报, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111
引用本文: 张欢, 钟鹭斌, 苑志华, 陈进生, 郑煜铭. 隔膜电解海水氧化耦合吸收脱硫脱硝净化船舶尾气技术[J]. 环境工程学报, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111
ZHANG Huan, ZHONG Lubin, YUAN Zhihua, CHEN Jinsheng, ZHENG Yuming. Simultaneous desulfurization and denitration of ship exhaust gas by diaphragm electrolysis technology with coupled process of oxidation and absorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111
Citation: ZHANG Huan, ZHONG Lubin, YUAN Zhihua, CHEN Jinsheng, ZHENG Yuming. Simultaneous desulfurization and denitration of ship exhaust gas by diaphragm electrolysis technology with coupled process of oxidation and absorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111

隔膜电解海水氧化耦合吸收脱硫脱硝净化船舶尾气技术

  • 基金项目:

    厦门南方海洋研究中心项目(14GQT60HJ30)

    中国科学院“百人计划”项目

Simultaneous desulfurization and denitration of ship exhaust gas by diaphragm electrolysis technology with coupled process of oxidation and absorption

  • Fund Project:
  • 摘要: 采用隔膜电解技术对海水进行改性,生成的氧化液和碱性液分别喷淋进入氧化洗涤塔和碱式吸收塔,通过耦合的二段式反应研究脱除模拟船舶尾气中NO与SO2的性能,实验详细考察了NO与SO2的气体流量与初始浓度、海水电解时间和氧化液有效氯浓度对SO2和NO脱除效率的影响。结果表明:隔膜电解海水能够高效地脱除船舶尾气中的SO2和NO;SO2脱除效率高,在实验条件范围内几乎不受各因素的影响;NO脱除效率随NO初始浓度、海水电解时间、氧化液有效氯浓度的提升而增大,随SO2初始浓度、气体流量的提升而减小。当气体流量为1 m3·h-1,初始SO2、NO浓度分别为600 mL·m-3和900 mL·m-3,海水电解时间为60 min,氧化液有效氯浓度为540 mg·L-1时,模拟船舶尾气中SO2和NO的去除效率可以分别达到98.6%和84.4%。
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  • [1] AN S,NISHIDA O.New application of seawater and electrolyzed seawater in air pollution control of marine diesel engine[J].JSME International Journal,2003,6(1):206-213
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    [8] MONDAL M K,CHELLUBOYANA V R.New experimental results of combined SO2 and NO removal from simulated gas stream by NaClO as low-cost absorbent[J].Chemical Engineering Journal,2013,7:48-53
    [9] CAIAZZO G,LANGELLA G,MICCIO F,et al.An experimental investigation on seawater SO2 scrubbing for marine application[J].Environmental Progress & Sustainable Energy,2013,2(4):1179-1186
    [10] ZHAO Y,HAO R L,WANG T H,et al.Follow-up research for integrative process of pre-oxidation and post-absorption cleaning flue gas:Absorption of NO2, NO and SO2[J].Chemical Engineering Journal,2015,3:55-65
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  • 刊出日期:  2018-01-14
张欢, 钟鹭斌, 苑志华, 陈进生, 郑煜铭. 隔膜电解海水氧化耦合吸收脱硫脱硝净化船舶尾气技术[J]. 环境工程学报, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111
引用本文: 张欢, 钟鹭斌, 苑志华, 陈进生, 郑煜铭. 隔膜电解海水氧化耦合吸收脱硫脱硝净化船舶尾气技术[J]. 环境工程学报, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111
ZHANG Huan, ZHONG Lubin, YUAN Zhihua, CHEN Jinsheng, ZHENG Yuming. Simultaneous desulfurization and denitration of ship exhaust gas by diaphragm electrolysis technology with coupled process of oxidation and absorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111
Citation: ZHANG Huan, ZHONG Lubin, YUAN Zhihua, CHEN Jinsheng, ZHENG Yuming. Simultaneous desulfurization and denitration of ship exhaust gas by diaphragm electrolysis technology with coupled process of oxidation and absorption[J]. Chinese Journal of Environmental Engineering, 2018, 12(1): 164-171. doi: 10.12030/j.cjee.201703111

隔膜电解海水氧化耦合吸收脱硫脱硝净化船舶尾气技术

  • 1. 中国科学院城市环境研究所,中国科学院区域大气环境研究卓越创新中心,厦门 361021
  • 2. 中国科学院城市环境研究所,中国科学院城市污染物转化重点实验室,厦门 361021
  • 3. 中国科学院大学资源与环境学院,北京 100049
基金项目:

厦门南方海洋研究中心项目(14GQT60HJ30)

中国科学院“百人计划”项目

摘要: 采用隔膜电解技术对海水进行改性,生成的氧化液和碱性液分别喷淋进入氧化洗涤塔和碱式吸收塔,通过耦合的二段式反应研究脱除模拟船舶尾气中NO与SO2的性能,实验详细考察了NO与SO2的气体流量与初始浓度、海水电解时间和氧化液有效氯浓度对SO2和NO脱除效率的影响。结果表明:隔膜电解海水能够高效地脱除船舶尾气中的SO2和NO;SO2脱除效率高,在实验条件范围内几乎不受各因素的影响;NO脱除效率随NO初始浓度、海水电解时间、氧化液有效氯浓度的提升而增大,随SO2初始浓度、气体流量的提升而减小。当气体流量为1 m3·h-1,初始SO2、NO浓度分别为600 mL·m-3和900 mL·m-3,海水电解时间为60 min,氧化液有效氯浓度为540 mg·L-1时,模拟船舶尾气中SO2和NO的去除效率可以分别达到98.6%和84.4%。

English Abstract

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