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类水滑石衍生金属混合氧化物在汽车尾气NOx存储/还原催化剂中的应用

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王强, 薛天山, 杨若研, 高艳珊. 类水滑石衍生金属混合氧化物在汽车尾气NOx存储/还原催化剂中的应用[J]. 环境工程学报, 2017, 11(3): 1305-1313. doi: 10.12030/j.cjee.201609238
引用本文: 王强, 薛天山, 杨若研, 高艳珊. 类水滑石衍生金属混合氧化物在汽车尾气NOx存储/还原催化剂中的应用[J]. 环境工程学报, 2017, 11(3): 1305-1313. doi: 10.12030/j.cjee.201609238
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WANG Qiang, XUE Tianshan, YANG Ruoyan, GAO Yanshan. Application of hydrotalcite-like compounds derived mixed oxides as NOx storage and reduction catalysts for vehicle NOx emission control[J]. Chinese Journal of Environmental Engineering, 2017, 11(3): 1305-1313. doi: 10.12030/j.cjee.201609238
Citation: WANG Qiang, XUE Tianshan, YANG Ruoyan, GAO Yanshan. Application of hydrotalcite-like compounds derived mixed oxides as NOx storage and reduction catalysts for vehicle NOx emission control[J]. Chinese Journal of Environmental Engineering, 2017, 11(3): 1305-1313. doi: 10.12030/j.cjee.201609238
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类水滑石衍生金属混合氧化物在汽车尾气NOx存储/还原催化剂中的应用

  • 1.

    北京林业大学环境科学与工程学院, 北京 100083

  • 基金项目:

    国家自然科学基金优秀青年项目（51622801）

  • 中图分类号: X701

Application of hydrotalcite-like compounds derived mixed oxides as NOx storage and reduction catalysts for vehicle NOx emission control

  • 1.

    College of Environmental Science and Engineering, Beijing Forestry University, Beijing 100083, China

  • Fund Project:

  • 摘要: 汽车尾气NOx污染物的排放，不仅是造成城市灰霾和光化学烟雾污染的重要原因，而且对人体健康危害极大。类水滑石衍生NSR催化剂体系由于其优越的NOx存储性能、热稳定性和抗硫性等特点受到广泛关注。为促进该技术的研究及应用，综述了类水滑石类催化剂应用于NSR技术的原理及研究成果，重点总结了化学组成、碱金属负载、贵金属负载、煅烧温度等因素对NOx存储还原性能的影响，指出了类水滑石类催化剂应用于NSR技术中存在的问题及发展方向。
    Abstract: NOx emitted from vehicles is very harmful to human health, and it has been recognized as one of the most critical reasons for the severe gray haze and photochemical smog. Recently, layered double hydroxides (LDHs) derived NOx storage and reduction (NSR) catalysts have attracted great attention due to excellent NOx storage capacity, thermal stability and sulfur resistance. The progresses in recent years have been summarized with emphasis on the effect of chemical composition of LDHs, alkali metal coating, noble metal doping, and the calcination temperature, etc. To further promote the application and intensive research of LDHs derived NSR catalysts, the problem and direction of LDHs derived NSR catalysts have been pointed out in detail.
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  • [1] WANG Q, PARK S, DUAN L, et al. Activity, stability and characterization of NO oxidation catalyst Co/KxTi2O5[J]. Applied Catalysis B Environmental, 2008, 85(1):10-16
    [2] LI S, LI S, WU C, et al. Characterization and properties of Pt/ZrO2CeO2 catalyst for purification of automotive exhaust[J]. Chinese Journal of Catalysis, 1999, 20(1):542-560
    [3] WANG Q, PARK S, JIN S, et al. Co/KxTi2O5 catalysts prepared by ion exchange method for NO oxidation to NO2[J]. Applied Catalysis B Environmental, 2008, 79(2):101-107
    [4] 谭镜明. 汽车尾气三效催化剂简介[J]. 广州环境科学, 2007, 22(1):20-21
    [5] XUE H, LI G, LIU P, et al. Review of catalysts for selective catalytic reduction(SCR) of NOx[J]. Advanced Materials Research, 2012, 550-553:119-123
    [6] NAKATSUJI T, YASUKAWA R, TABATA K, et al. A highly durable catalytic NOx reduction in the presence of SOx using periodic two steps, an operation in oxidizing conditions and a relatively short operation in reducing conditions[J]. Applied Catalysis B Environmental, 1999, 21(2):121-131
    [7] TAKAHASHI N, SHINJOH H, IIJIMA T, et al. The new concept 3-way catalyst for automotive lean-burn engine:NOx storage and reduction catalyst[J]. Catalysis Today, 1996, 27(1/2):63-69
    [8] 郭丽红, 刘咏, 孟明. 稀燃NOx储存-还原催化剂[J]. 化学进展, 2009, 21(5):964-970
    [9] AMBERNTSSON A, FRIDELL E, SKOGLUNDH M. Influence of platinum and rhodium composition on the NOx storage and sulphur tolerance of a barium based NOx storage catalyst[J]. Applied Catalysis B Environmental, 2003, 46(3):429-439
    [10] PIETA I, GARCIA-DIEGUEZ M, HERRERA C, et al. In situ DRIFTTRM study of simultaneous NOx and soot removal over Pt-Ba and Pt-K NSR catalysts[J]. Journal of Catalysis, 2010, 270(2):256-267
    [11] DIWELL A, RAJARAM R, SHAW H, et al. The role of ceria in three-way catalysts[J]. Studies in Surface Science & Catalysis, 1991, 71:139-152
    [12] HATANAKA M, TAKAHASHI N, TANAB T, et al. Ideal Pt loading for a Pt/CeO2-based catalyst stabilized by a Pt-O-Ce bond[J]. Applied Catalysis B Environmental, 2010, 99(1/2):336-342
    [13] ITO K, KAKINO S, IKEUE K, et al. NO adsorption/desorption property of TiO2-ZrO2 having tolerance to SO2 poisoning[J]. Applied Catalysis B Environmental, 2007, 74(1/2):137-143
    [14] CORBOS E, DUPREZ D, COURTOIS X, et al. Impact of support oxide and Ba loading on the NOx storage properties of Pt/Ba/support catalysts:CO2 and H2O effects[J]. Applied Catalysis B Environmental, 2007, 76(3/4):357-367
    [15] LI X, CHEN J, LIN P, et al. A study of the NOx storage catalyst of Ba-Fe-O complex oxide[J]. Catalysis Communications, 2004, 5(1):25-28
    [16] MILT V, QUERINI C, MIRO E. Thermal analysis of Kx/La2O3, active catalysts for the abatement of diesel exhaust contaminants[J]. Thermochimica Acta, 2011, 125(1):145-156
    [17] CASAPU M, GRUNWALDT J, MACIEJEWSKI M, et al. Comparative study of structural properties and NOx storage-reduction behavior of Pt/Ba/CeO2 and Pt/Ba/Al2O3[J]. Applied Catalysis B Environmental, 2008, 78(3/4):288-300
    [18] 王立秋, 张守臣,刘长厚. 类水滑石复合产物催化消除氮氧化物的研究进展[J]. 化工进展, 2003, 22(10):1076-1080
    [19] HE L, HUANG Y, WANG A, et al. Surface modification of Ni/Al2O3 with Pt:Highly efficient catalysts for H2 generation via selective decomposition of hydrous hydrazine[J]. Journal of Catalysis, 2013, 298(1):1-9
    [20] WANG Q, DERMOT O. Recent advances in the synthesis and application of layered double hydroxide(LDH) nanosheets[J]. Chemical Reviews, 2012, 112(7):4124-4155
    [21] WANG Q, TAY H, WEI NG D, et al. The effect of trivalent cations on the performance of Mg-M-CO3 layered double hydroxides for high-temperature CO2 capture[J]. ChemSusChem, 2010, 3(8):965-973
    [22] WANG Q, TAY H, CHEN L, et al. Preparation and CO2 capture capacity of alkali metal carbonates promoted hydrotalcite[J]. Journal of Nanoengineering & Nanomanufacturing, 2011, 1(3):298-303
    [23] WANG Q, HUI H, GUO Z, et al. Morphology and composition controllable synthesis of Mg-Al-CO3 hydrotalcites by tuning the synthesis pH and the CO2 capture capacity[J]. Applied Clay Science, 2012, 55(1):18-26
    [24] WANG Q, LUO J, ZHONG Z, et al. CO2 Capture by solid-adsorbents and their applications:Current status and new trends[J]. Energy & Environmental Science, 2011, 4(1):42-55
    [25] ZHENG H, WANG Q, LONG Y, et al. Enhancing the luminescence of carbon dots with a reduction pathway[J]. Chemical Communications, 2011, 47(38):10650-10652
    [26] LIETTI L, FORZATTI P, NOVA I, et al. NOx storage reduction over Pt-Ba/gamma-Al2O3 catalyst[J]. Journal of Catalysis, 2001, 204(1):175-191
    [27] LIM S, ZHENG Y, ZOU S, et al. Uptake of arsenate by an alginate-encapsulated magnetic sorbent:Process performance and characterization of adsorption chemistry[J]. Journal of Colloid & Interface Science, 2009, 333(1):33-39
    [28] YU J, CHENG J, MA C, et al. NOx decomposition, storage and reduction over novel mixed oxide catalysts derived from hydrotalcite-like compounds[J]. Journal of Colloid & Interface Science, 2009, 333(2):423-430
    [29] FORNASARI G, TRIFIRO F, VACCARI A, et al. Novel low temperature NOx storage-reduction catalysts for diesel light-duty engine emissions based on hydrotalcite compounds[J]. Catalysis Today, 2002, 75(1/2/3/4):421-429
    [30] CENTI G, ARENA G, PERATHONER S. Nanostructured catalysts for NOx storage-reduction and N2O decomposition[J]. Journal of Catalysis, 2003, 216(1/2):443-454
    [31] KANG S, LI J, FU L, et al. NOx storage and decomposition behavior of Cu-Mg-Al catalyst[J]. Environmental Science, 2007, 28(5):958-962
    [32] 於俊杰, 朱玲, 周波, 等. Zn取代类水滑石衍生复合氧化物上N2O的催化分解[J]. 物理化学学报, 2009, 25(2):353-359
    [33] LI D, YU J, HAO Z, et al. Novel Ru-Mg-Al-O catalyst derived from hydrotalcite-like compound for NO storage/decomposition/reduction[J]. Journal of Physical Chemistry C, 2007, 111(28):10552-10559
    [34] LU P, ZHANG X, WANG Z, et al. Hydrotalcites-derived well-dispersed mixed oxides for NOx adsorption and desorption[J]. Science of Advanced Materials, 2016, 8(8):1656-1667
    [35] YU J, XIAO P, YAN X, et al. Effective NOx decomposition and storage/reduction over mixed oxides derived from layered double hydroxides[J]. Industrial & Engineering Chemistry Research, 2007, 46(17):5794-5797
    [36] YU J, CHENG J, MA C, et al. NOx decomposition, storage and reduction over novel mixed oxide catalysts derived from hydrotalcite-like compounds[J]. Journal of Colloid & Interface Science, 2009, 333(2):423-430
    [37] WANG Z, LU P, ZHANG X, et al. NO storage and soot combustion over well-dispersed mesoporous mixed oxides via hydrotalcite-like precursors[J]. RSC Advances, 2015, 5(65):52743-52753
    [38] LI Q, MENG M, TSUBAKI N, et al. Performance of K-promoted hydrotalcite-derived CoMgAlO catalysts used for soot combustion, NOx storage and simultaneous soot-NOx removal[J]. Applied Catalysis B Environmental, 2009, 91(1):406-415
    [39] WALSPURGER S, BOELS L, PAUL D, et al. The crucial role of the K+-aluminium oxide interaction in K+-promoted alumina- and hydrotalcite-based materials for CO2 sorption at high temperatures[J]. ChemSusChem, 2008, 1(7):643-650
    [40] WANG Y, HAN X, JI A, et al. Basicity of potassium-salt modified hydrotalcite studied by 1 H MAS NMR using pyrrole as a probe molecule[J]. Microporous & Mesoporous Materials, 2005, 77(2):139-145
    [41] 张业新, 苏庆运, 王仲鹏, 等. 钾对镁铝水滑石复合氧化物的表面改性[J]. 物理化学学报, 2010, 26(4):921-926
    [42] LI Q, MENG M, DAI F, et al. Multifunctional hydrotalcite-derived K/MnMgAlO catalysts used for soot combustion, NOx storage and simultaneous soot-NOx removal[J]. Chemical Engineering Journal, 2012, 184(2):106-112
    [43] CENTI G, FORNASARI G, GOBBI C, et al. NOx storage-reduction catalysts based on hydrotalcite:Effect of Cu in promoting resistance to deactivation[J]. Catalysis Today, 2002, 73(3):287-296
    [44] SILLETTI B, ADAMS R, SIGMON S, et al. A novel Pd/MgAlOx catalyst for NOx storage-reduction[J]. Catalysis Today, 2006, 114(1):64-71
    [45] ZHANG Y, WANG X, WANG Z, et al. Direct spectroscopic evidence of CO spillover and subsequent reaction with preadsorbed NOx on Pd and K cosupported Mg-Al mixed oxides[J]. Environmental Science & Technology, 2012, 46(17):9614-9619
    [46] 康守方, 蒋政, 郝郑平. Cu对Pt/Cu-Mg-Al-O催化剂上NOx储存性能的影响[J]. 物理化学学报, 2005, 21(3):278-282
    [47] WANG T, ZHEN L, YANG S, et al. Ag/Mg-Al-O composite for low temperature NOx storage[J]. Chemical Research in Chinese Universities, 2011, 27(5):734-738
    [48] MEI X, WANG J, YANG R, et al. Synthesis of Pt doped Mg-Al layered double oxide/graphene oxide hybrid as novel NOx storage-reduction catalyst[J]. RSC Advances, 2015, 5(49):437-441
    [49] ZHANG S, LIU W, WANG C, et al. Improving the NOx decomposition and storage activity through co-incorporating ammonium and copper ions into Mg/Al hydrotalcites[J]. RSC Advances, 2016, 6(51):45127-45134
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  • 收稿日期:  2016-12-14
  • 刊出日期:  2017-03-10

类水滑石衍生金属混合氧化物在汽车尾气NOx存储/还原催化剂中的应用

  • 1. 北京林业大学环境科学与工程学院, 北京 100083
  • 收稿日期:  2016-12-14
基金项目:

国家自然科学基金优秀青年项目（51622801）

摘要: 汽车尾气NOx污染物的排放，不仅是造成城市灰霾和光化学烟雾污染的重要原因，而且对人体健康危害极大。类水滑石衍生NSR催化剂体系由于其优越的NOx存储性能、热稳定性和抗硫性等特点受到广泛关注。为促进该技术的研究及应用，综述了类水滑石类催化剂应用于NSR技术的原理及研究成果，重点总结了化学组成、碱金属负载、贵金属负载、煅烧温度等因素对NOx存储还原性能的影响，指出了类水滑石类催化剂应用于NSR技术中存在的问题及发展方向。

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