串联补给式微生物燃料电池加速处理含铜废水

李静; 王晓慧; 王钊; 刘睿; 高艳梅; 海热提

doi:10.12030/j.cjee.201511024

环境工程学报

串联补给式微生物燃料电池加速处理含铜废水

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李静, 王晓慧, 王钊, 刘睿, 高艳梅, 海热提. 串联补给式微生物燃料电池加速处理含铜废水[J]. 环境工程学报, 2017, 11(5): 2666-2670. doi: 10.12030/j.cjee.201511024

引用本文:

李静, 王晓慧, 王钊, 刘睿, 高艳梅, 海热提. 串联补给式微生物燃料电池加速处理含铜废水[J]. 环境工程学报, 2017, 11(5): 2666-2670. doi: 10.12030/j.cjee.201511024

LI Jing, WANG Xiaohui, WANG Zhao, LIU Rui, GAO Yanmei, HAI Reti. Accelerating treatment of copper-containing wastewater by microbial fuel cells in series[J]. Chinese Journal of Environmental Engineering, 2017, 11(5): 2666-2670. doi: 10.12030/j.cjee.201511024

Citation:

LI Jing, WANG Xiaohui, WANG Zhao, LIU Rui, GAO Yanmei, HAI Reti. Accelerating treatment of copper-containing wastewater by microbial fuel cells in series[J]. Chinese Journal of Environmental Engineering, 2017, 11(5): 2666-2670. doi: 10.12030/j.cjee.201511024

串联补给式微生物燃料电池加速处理含铜废水

1.
北京化工大学, 北京市水处理环保材料工程技术研究中心, 北京 100029
2.
河北出入境检验检疫局检验检疫技术中心曹妃甸分中心, 唐山 063000
基金项目:
国家国际科技合作专项（2013DFR60250）

国家自然科学基金资助项目（51408020）

北京市科技计划项目（Z15111000210000）

中央高校基本科研业务费（JD1503）
中图分类号: X703

Accelerating treatment of copper-containing wastewater by microbial fuel cells in series

1.
Water Treatment and Environmental Protection Material Engineering Technology Research Center of Beijing, Beijing University of Chemical Technology, Beijing 100029, China
2.
Caofeidian Sub-Center of Hebei Entry-Exit Inspection and Quarantine Technical Center, Tangshan 063000, China
Fund Project:

摘要: 微生物燃料电池（microbial fuel cells，MFC）可用于处理有机废水并同时处理污水中的重金属。为了对MFC处理含铜废水进行优化，采用了KMnO4-MFC与Cu-MFC串联，通过前者产生的较高电压对后者处理含铜废水过程提供电压和功率的补给并获得额外电能，结果表明，KMnO4-MFC在KMnO4浓度为0.5、1、2 g·L-1时输出最大功率密度分别为288、433、700 mW·m-2，而Cu-MFC在Cu2+浓度为10 mg·L-1时最大功率密度仅为218.75 mW·m-2，二者串联能够明显加快Cu-MFC对Cu2+的回收速率，串联时Cu2+的回收率可达98%，24 h回收率可达91.7%，与单独Cu-MFC相比速率提高1倍。串联后，该种方法在加速铜回收过程的同时还能获得额外的电能，其最高输出功率可达143 mW。
- 微生物燃料电池 /
- 含铜废水 /
- 回收速率 /
- 高锰酸钾
Abstract: Microbial fuel cells (MFCs)can be used to treat metal-contaminated water. The use of two MFCs in series (KMnO4-MFC and Cu-MFC)successfully overcame the insufficient voltage and power for copper recovery from the Cu-MFC and provided additional electrical energy. The results showed that maximum output power densities of 288,433,and 700 mW·m-2 were achieved at KMnO4 concentrations of 0.5,1,and 2 g·L-1,respectively,in the KMnO4-MFC. The maximum output power density of the Cu-MFC alone was only 218.75 mW·m-2. This series arrangement can significantly accelerate Cu recovery from Cu-MFCs,with Cu recovery rates of up to 98% and 24 h Cu recoveries of up to 91.7%. Use of this method to accelerate copper recovery while still providing additional power led to a maximum output power of up to 143 mW.
- microbial fuel cells /
- copper wastewater /
- recovery rate /
- KMnO4

[1]	LOGAN B E. Microbial Fuel Cells[M]. Hoboken, NJ:John Wiley & Sons, 2008
[2]	申中正, 赵华章, 薛安. 微生物燃料电池-零价铁耦合工艺的构建及除砷性能[J]. 环境工程学报, 2013, 7(5):1646-1650
[3]	REN Lijiao, AHN Y, LOGAN B E. A two-stage microbial fuel cell and anaerobic fluidized bed membrane bioreactor (MFC-AFMBR)system for effective domestic wastewater treatment[J]. Environmental Science & Technology, 2014, 48(7):4199-4206
[4]	HEIJNE A T, LIU Fei, VAN DER WEIJDEN R, et al. Copper recovery combined with electricity production in a microbial fuel cell[J]. Environmental Science & Technology, 2010, 44(11):4376-4381
[5]	TAO H C, LIANG Min, LI Wei, et al. Removal of copper from aqueous solution by electrodeposition in cathode chamber of microbial fuel cell[J]. Journal of Hazardous Materials, 2011, 189(1/2):186-192
[6]	印霞棐, 刘维平, 姜璐. 利用微生物燃料电池回收含铜废水中的铜[J]. 环境工程, 2014, 32(9):152-157
[7]	张金娜. 三种不同阴极类型微生物燃料电池产电性能研究[D]. 哈尔滨:哈尔滨工业大学, 2009
[8]	蔡慧. 双室微生物燃料电池碳基阳极材料的制备及其产电特性的研究[D]. 南京:南京理工大学, 2013
[9]	朱宁正. 同步废水处理及产能的微生物燃料电池[D]. 哈尔滨:哈尔滨工程大学, 2009
[10]	WU Dan, PAN Yuzhen, HUANG Liping, et al. Complete separation of Cu(Ⅱ), Co(Ⅱ)and Li(Ⅰ)using self-driven MFCs-MECs with stainless steel mesh cathodes under continuous flow conditions[J]. Separation and Purification Technology, 2015, 147:114-124
[11]	HE Chuanshu, MU Zhexuan, YANG Houyun, et al. Electron acceptors for energy generation in microbial fuel cells fed with wastewaters:A mini-review[J]. Chemosphere, 2015, 140:12-17
[12]	CHOI C, HU Naixu, LIM B. Cadmium recovery by coupling double microbial fuel cells[J]. Bioresource Technology, 2014, 170:361-369
[13]	NANCHARAIAH Y V, MOHAN S V, LENS P N A. Metals removal and recovery in bioelectrochemical systems:A review[J]. Bioresource Technology, 2015, 195:102-114
[14]	LI Weiqing, ZHANG Shaohui, CHEN Gang, et al. Simultaneous electricity generation and pollutant removal in microbial fuel cell with denitrifying biocathode over nitrite[J]. Applied Energy, 2014, 126:136-141
[15]	TAO Qinqin, LUO Jingjing, ZHOU Juan, et al. Effect of dissolved oxygen on nitrogen and phosphorus removal and electricity production in microbial fuel cell[J]. Bioresource Technology, 2014, 164:402-407

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李静, 王晓慧, 王钊, 刘睿, 高艳梅, 海热提. 串联补给式微生物燃料电池加速处理含铜废水[J]. 环境工程学报, 2017, 11(5): 2666-2670. doi: 10.12030/j.cjee.201511024

引用本文:

李静, 王晓慧, 王钊, 刘睿, 高艳梅, 海热提. 串联补给式微生物燃料电池加速处理含铜废水[J]. 环境工程学报, 2017, 11(5): 2666-2670. doi: 10.12030/j.cjee.201511024

Citation:

串联补给式微生物燃料电池加速处理含铜废水

1. 北京化工大学, 北京市水处理环保材料工程技术研究中心, 北京 100029
2. 河北出入境检验检疫局检验检疫技术中心曹妃甸分中心, 唐山 063000

收稿日期: 2016-01-26

基金项目:

国家国际科技合作专项（2013DFR60250）

国家自然科学基金资助项目（51408020）

北京市科技计划项目（Z15111000210000）

中央高校基本科研业务费（JD1503）

关键词:

摘要: 微生物燃料电池（microbial fuel cells，MFC）可用于处理有机废水并同时处理污水中的重金属。为了对MFC处理含铜废水进行优化，采用了KMnO4-MFC与Cu-MFC串联，通过前者产生的较高电压对后者处理含铜废水过程提供电压和功率的补给并获得额外电能，结果表明，KMnO4-MFC在KMnO4浓度为0.5、1、2 g·L-1时输出最大功率密度分别为288、433、700 mW·m-2，而Cu-MFC在Cu2+浓度为10 mg·L-1时最大功率密度仅为218.75 mW·m-2，二者串联能够明显加快Cu-MFC对Cu2+的回收速率，串联时Cu2+的回收率可达98%，24 h回收率可达91.7%，与单独Cu-MFC相比速率提高1倍。串联后，该种方法在加速铜回收过程的同时还能获得额外的电能，其最高输出功率可达143 mW。

English Abstract

Accelerating treatment of copper-containing wastewater by microbial fuel cells in series

1. Water Treatment and Environmental Protection Material Engineering Technology Research Center of Beijing, Beijing University of Chemical Technology, Beijing 100029, China
2. Caofeidian Sub-Center of Hebei Entry-Exit Inspection and Quarantine Technical Center, Tangshan 063000, China

Received Date: 2016-01-26

Fund Project:

Keywords:

Abstract: Microbial fuel cells (MFCs)can be used to treat metal-contaminated water. The use of two MFCs in series (KMnO4-MFC and Cu-MFC)successfully overcame the insufficient voltage and power for copper recovery from the Cu-MFC and provided additional electrical energy. The results showed that maximum output power densities of 288,433,and 700 mW·m-2 were achieved at KMnO4 concentrations of 0.5,1,and 2 g·L-1,respectively,in the KMnO4-MFC. The maximum output power density of the Cu-MFC alone was only 218.75 mW·m-2. This series arrangement can significantly accelerate Cu recovery from Cu-MFCs,with Cu recovery rates of up to 98% and 24 h Cu recoveries of up to 91.7%. Use of this method to accelerate copper recovery while still providing additional power led to a maximum output power of up to 143 mW.

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串联补给式微生物燃料电池加速处理含铜废水

Accelerating treatment of copper-containing wastewater by microbial fuel cells in series

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串联补给式微生物燃料电池加速处理含铜废水

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Accelerating treatment of copper-containing wastewater by microbial fuel cells in series

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