废铁屑-改性粉煤灰联用处理铬渣渗滤液

李喜林, 赵雪, 周启星, 吴佳欢, 刘玲. 废铁屑-改性粉煤灰联用处理铬渣渗滤液[J]. 环境工程学报, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201
引用本文: 李喜林, 赵雪, 周启星, 吴佳欢, 刘玲. 废铁屑-改性粉煤灰联用处理铬渣渗滤液[J]. 环境工程学报, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201
Li Xilin, Zhao Xue, Zhou Qixing, Wu Jiahuan, Liu Ling. Treatment of chromite ore processing residue leachate by scrap iron combined with modified fly ash[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201
Citation: Li Xilin, Zhao Xue, Zhou Qixing, Wu Jiahuan, Liu Ling. Treatment of chromite ore processing residue leachate by scrap iron combined with modified fly ash[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201

废铁屑-改性粉煤灰联用处理铬渣渗滤液

  • 基金项目:

    国家自然科学基金资助项目(51304106,U1133006)

    国家高技术研究发展计划(863)项目(2013AA06A205)

    辽宁省大学生创新性实验计划项目(201410147051)

  • 中图分类号: X703.1

Treatment of chromite ore processing residue leachate by scrap iron combined with modified fly ash

  • Fund Project:
  • 摘要: 针对铬渣严重污染环境问题,以"以废治废"为研究目标,采用室内静态实验方法,进行废铁屑-改性粉煤灰联用处理铬渣渗滤液中Cr(Ⅵ)和总铬实验研究。实验结果表明,废铁屑与聚合氯化铝改性粉煤灰联用处理Cr(Ⅵ)和总铬效果优于单独采用其中一种物质;处理Cr(Ⅵ)浓度208 mg/L、总铬浓度260 mg/L的200 mL高浓度含铬废水最佳反应条件为:反应时间30 min,总投加量40 g,配比为1:1, pH值4.1,对应Cr(Ⅵ)去除率99.93%,总铬去除率99.72%。处理后水质满足《污水综合排放标准》(GB 8978-1996)要求。
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  • [1] 李喜林, 王来贵, 郝喆, 等. 粉质粘土和粉质砂土对铬渣渗滤液中Cr(Ⅵ)吸附特性. 环境工程学报, 2013, 7(12): 5019-5024 Li Xilin, Wang Laigui, Hao Zhe, et al. Absorption characteristics of Cr(VI) from leachate of chromium slag by silty clay and silty sand. Chinese Journal of Environmental Engineering, 2013, 7(12): 5019-5024(in Chinese)
    [2] Tinjum J. M., Benson C. H., Edi T. B. Mobilization of Cr(VI) from chromite ore processing residue through acid treatment. Science of the Total Environment, 2008, 391(1): 13-25
    [3] 刘荣香, 张焕祯, 刘峻平. 高岭土负载壳聚糖处理铬渣污染地下水. 工业水处理, 2012, 32(5): 44-47 Liu Rongxiang, Zhang Huanzhen, Liu Junping. Treatment of groundwater polluted by chromium residue with kaoline-chitosan compound adsorbent. Industrial Water Treatment, 2012, 32(5): 44-47(in Chinese)
    [4] Stewart D. I., Burke I. T., Hughes-berry D. V., et al. Microbially mediated chromate reduction in soil contaminated by highly alkaline leachate from chromium containing waste. Ecological Engineering, 2010, 36(2): 211-221
    [5] 常文越, 陈晓东, 冯晓斌, 等. 含铬(Ⅵ)废物堆放场所土壤/地下水的污染特点及土著微生物的初步生物解毒实验研究. 环境保护科学, 2002, 28(6): 31-33 Chang Wenyue, Chen Xiaodong, Feng Xiaobin, et al. Characteristic of soil/underground water of chromium waste stock and experimental study on biological detoxication of aboriginal microbe. Environmental Protection Science, 2002, 28(6): 31-33(in Chinese)
    [6] 李喜林, 王来贵, 赵奎, 等. 铬渣浸溶Cr(Ⅵ)溶解释放规律研究:以锦州堆场铬渣为例. 地球与环境, 2013, 41(5): 518-523 Li Xilin, Wang Laigui, Zhao Kui, et al. Research on Cr(VI) releasing mechanism by chromium slag dissolution as exemplified by the chromium slag of Jinzhou Yard. Earth and Environment, 2013, 41(5): 518-523(in Chinese)
    [7] Barrera-díaz C. E., Lugo-lugo V., Bilyeu B. A review of chemical, electrochemical and biological methods for aqueous Cr(VI) reduction. Journal of Hazardous Materials, 2012, 223-224: 1-12
    [8] Owlad M., Aroua M. K., Wan Daud W. A., et al. Removal of hexavalent chromium-contaminated water and wastewater: A review. Water, Air, and Soil Pollution, 2009, 200(1-4): 59-77
    [9] 刘玉玲, 陆君, 马晓云, 等. 电絮凝过程处理含铬废水的工艺及机理. 环境工程学报, 2014, 8(9): 3640-3644 Liu Yuling, Lu Jun, Ma Xiaoyun, et al. Technique and mechanism of electrocoagulation process for treatment of wastewater containing chromium. Chinese Journal of Environmental Engineering, 2014, 8(9): 3640-3644(in Chinese)
    [10] 贺玉晓, 朱利霞, 王海邻, 等. 铁屑-粉煤灰与Fe0-粉煤灰处理地下水中Cr(Ⅵ)的对比试验研究. 能源环境保护, 2009, 23(2): 33-36 He Yuxiao, Zhu Lixia, Wang Hailing, et al. Comparative study of removing Cr(Ⅵ) by waste iron chippings-fly ash and Fe0-fly ash. Energy Environmental Protection, 2009, 23(2): 33-36(in Chinese)
    [11] Dhal B., Thatol H. N., Das N. N., et al. Chemical and microbial remediation of hexavalent chromium from contaminated soil and mining/metallurgical solid waste: A review. Journal of Hazardous Materials, 2013, 250-251: 272-291
    [12] 孔国栋, 孟凡伟. 铬渣渗滤液处理方法及应用现状. 中国资源综合利用, 2008, 26(2): 26-28 Kong Guodong, Meng Fanwei. Technology of leachate treatment of chromium residue. China Resources Comprehensive Utilization, 2008, 26(2): 26-28(in Chinese)
    [13] Mohan D., Pittman C. U. Jr. Activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water. Journal of Hazardous Materials, 2006, 137: 762-811
    [14] Geelhoed J. S., Meeussen J. C. L., Roe M. J., et al. Chromium remediation or release? Effect of iron(II) sulfate addition on chromium(VI) leaching from columns of chromite ore processing residue. Environmental Science & Technology, 2003, 37(14): 3206-3213
    [15] 李喜林, 赵雪, 项莹雪, 等. 改性粉煤灰吸附含铬废水中Cr(Ⅵ)和Cr(Ⅲ)试验研究. 非金属矿, 2015, 38(4): 75-77 Li Xilin, Zhao Xue, Xiang Yingxue, et al. Experimental study on adsorption Cr(Ⅵ) and Cr(Ⅲ) of chromium-containing wastewater by modified fly ash. Non-Metallic Mines, 2015, 38(4): 75-77(in Chinese)
    [16] Stathi P., Litina K., Gournis D., et al. Physicochemical study of novel organoclays as heavy metal ion adsorbents for environmental remediation. Journal of Colloid and Interface Science, 2007, 316(2): 298-309
    [17] 韩洪军, 刘彦忠, 杜冰. 铁屑-炭粒法处理纺织印染废水. 工业水处理, 1997, 17(6): 15-17 Han Hongjun, Liu Yanzhong, Du Bing. Researches on the dyeing wastewater treatment with iron chips and carbon particles. Industrial Water Treatment, 1997, 17(6): 15-17(in Chinese)
    [18] 张鑫, 张焕祯, 刘光英, 等. 铁屑粉煤灰组合处理含磷废水. 环境工程学报, 2013, 7(8): 2844-2848 Zhang Xin, Zhang Huanzhen, Liu Guangying, et al. Scrap iron combined with fly ash for treatment of phosphorus wastewater. Chinese Journal of Environmental Engineering, 2013, 7(8): 2844-2848(in Chinese)
    [19] 邱明亮, 罗丹, 丁晓静, 等. 化学沉淀法处理含铬废水的成本比较. 环境保护与循环经济, 2012(3): 61-62 Qiu Mingliang, Luo Dan, Ding Xiaojing, et al. The comparison of the cost in treating chromium-containing wastewater by chemical reduction and subsequent precipitation method. Environmental Protection and Circular Economy, 2012(3): 61-62(in Chinese)
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出版历程
  • 收稿日期:  2015-12-13
  • 刊出日期:  2016-06-03
李喜林, 赵雪, 周启星, 吴佳欢, 刘玲. 废铁屑-改性粉煤灰联用处理铬渣渗滤液[J]. 环境工程学报, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201
引用本文: 李喜林, 赵雪, 周启星, 吴佳欢, 刘玲. 废铁屑-改性粉煤灰联用处理铬渣渗滤液[J]. 环境工程学报, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201
Li Xilin, Zhao Xue, Zhou Qixing, Wu Jiahuan, Liu Ling. Treatment of chromite ore processing residue leachate by scrap iron combined with modified fly ash[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201
Citation: Li Xilin, Zhao Xue, Zhou Qixing, Wu Jiahuan, Liu Ling. Treatment of chromite ore processing residue leachate by scrap iron combined with modified fly ash[J]. Chinese Journal of Environmental Engineering, 2016, 10(6): 2793-2799. doi: 10.12030/j.cjee.201508201

废铁屑-改性粉煤灰联用处理铬渣渗滤液

  • 1.  辽宁工程技术大学建筑工程学院, 阜新 123000
  • 2.  南开大学环境科学与工程学院, 天津 300071
基金项目:

国家自然科学基金资助项目(51304106,U1133006)

国家高技术研究发展计划(863)项目(2013AA06A205)

辽宁省大学生创新性实验计划项目(201410147051)

摘要: 针对铬渣严重污染环境问题,以"以废治废"为研究目标,采用室内静态实验方法,进行废铁屑-改性粉煤灰联用处理铬渣渗滤液中Cr(Ⅵ)和总铬实验研究。实验结果表明,废铁屑与聚合氯化铝改性粉煤灰联用处理Cr(Ⅵ)和总铬效果优于单独采用其中一种物质;处理Cr(Ⅵ)浓度208 mg/L、总铬浓度260 mg/L的200 mL高浓度含铬废水最佳反应条件为:反应时间30 min,总投加量40 g,配比为1:1, pH值4.1,对应Cr(Ⅵ)去除率99.93%,总铬去除率99.72%。处理后水质满足《污水综合排放标准》(GB 8978-1996)要求。

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