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基于响应曲面法的环境因素对生活污水三维荧光光谱的影响

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孙梅香, 吴曼, 刘会应, 刘文, 冯志江, 张业中, 戴捷. 基于响应曲面法的环境因素对生活污水三维荧光光谱的影响[J]. 环境工程学报, 2016, 10(10): 5491-5497. doi: 10.12030/j.cjee.201505105
引用本文: 孙梅香, 吴曼, 刘会应, 刘文, 冯志江, 张业中, 戴捷. 基于响应曲面法的环境因素对生活污水三维荧光光谱的影响[J]. 环境工程学报, 2016, 10(10): 5491-5497. doi: 10.12030/j.cjee.201505105
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SUN Meixiang, WU Man, LIU Huiying, LIU Wen, FENG Zhijiang, ZHANG Yezhong, DAI Jie. Effects of environmental factors on 3DEEMs of domestic sewage based on response surface methodology[J]. Chinese Journal of Environmental Engineering, 2016, 10(10): 5491-5497. doi: 10.12030/j.cjee.201505105
Citation: SUN Meixiang, WU Man, LIU Huiying, LIU Wen, FENG Zhijiang, ZHANG Yezhong, DAI Jie. Effects of environmental factors on 3DEEMs of domestic sewage based on response surface methodology[J]. Chinese Journal of Environmental Engineering, 2016, 10(10): 5491-5497. doi: 10.12030/j.cjee.201505105
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基于响应曲面法的环境因素对生活污水三维荧光光谱的影响

  • 1.

    长江大学化学与环境工程学院, 荆州 434023

  • 基金项目:

    国家自然科学基金资助项目（21173026）

    湖北省自然科学基金重点项目（2013CFA107）

  • 中图分类号: X703.1

Effects of environmental factors on 3DEEMs of domestic sewage based on response surface methodology

  • 1.

    College of Chemistry and Environmental Engineering, Yangtze University, Jingzhou 434023, China

  • Fund Project:

  • 摘要: 采用响应曲面法（RSM）研究温度（10~35℃）、pH（3~11）、稀释倍数（1~10）及交互作用对生活污水溶解性有机物（DOM）三维荧光光谱特性的影响规律。研究表明：生活污水DOM主要含有类色氨酸蛋白质、类酪氨酸蛋白质和类富里酸荧光峰；响应曲面分析表明，温度、pH、稀释倍数其交互作用对于类色氨酸蛋白质荧光强度的影响强弱顺序为：稀释倍数 > pH > 温度、pH-稀释倍数 > 温度-pH > 温度-稀释倍数，其中温度-pH和温度-稀释倍数对其荧光强度的影响为拮抗作用，pH-稀释倍数为协同作用；对于类酪氨酸蛋白质，单因素影响顺序为：pH > 稀释倍数 > 温度，其他情况与类色氨酸蛋白质相似；对于类富里酸，温度、pH、稀释倍数及其交互作用对其影响规律与对类色氨酸蛋白质的相似，但交互作用类型与类色氨酸蛋白质情况相反。
    Abstract: Response surface methodology (RSM) was used to examine the effects of temperature (10 to 35℃),pH (3 to 11),diluted multiples (1 to 10) and their interactions with each other on the three dimensional excitation-emission matrix (3DEEM) fluorescence spectrum of dissolved organic matter (DOM) in domestic sewage.The investigation found that three remarkable fluorescence peaks existed according to the 3DEEM,indicating tryptophan-like proteins,tyrosine-like proteins,and fulvic-like.Results of the RSM analysis showed that the effects of the three factors (temperature,pH,and diluted multiples) and their interactions with each other on the fluorescence intensity (FI) of the tryptophan-like proteins were ranked as follows:diluted multiples > pH > temperature and pH-diluted multiples > temperature-pH > temperature-diluted multiples,respectively.The interactions of temperature-pH and temperature-diluted multiples were antagonistic,whereas the interaction of pH-diluted multiples was synergistic.In terms of the tyrosine-like proteins,the rankings were:pH > diluted multiples > temperature,and the other situations were similar those of the tryptophan-like proteins.The rankings of effect of the three factors on the FI of the fulvic-like were similar to that of the tryptophan-like proteins,but the rankings of the interactions of these two peaks were exactly the opposite.
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  • [1] TANG Bin,WEI Biao,WU Decao,et al.Experimental research of turbidity influence on water quality monitoring of COD in UV-visible spectroscopy.Spectroscopy and Spectral Analysis,2014,34(11):3020-3024(in Chinese)
    [2] SICARD C.,GLEN C.,AUBIE B.,et al.Tools for water quality monitoring and mapping using paper-based sensors and cell phones.Water Research,2015,70:360-369
    [3] TANAKA K.,SHI Chaohong,NAKAGOSHI N.Water quality monitoring of Jialing-River in Chongqing using advanced ion chromatographic system.Chinese Journal of Chromatography,2012,30(4):350-355
    [4] TANG Xin,WU Qianyuan,ZHAO Xin,et al.A fingerprint analysis method for characterization of dissolved organic matter in secondary effluents of municipal wastewater treatment plant.Environmental Science and Pollution Research,2014,21(24):14211-14218
    [5] LEENHEER J.A.,CROUé J.P.Characterizing aquatic dissolved organic matter.Environment Science & Technology,2003,37(1):18A-26A
    [6] CARSTEA E.M.,BAKER A.,BIEROZA M.,et al.Characterisation of dissolved organic matter fluorescence properties by PARAFAC analysis and thermal quenching.Water Research,2014,61:152-161
    [7] DAOUK S.,FREGE C.,BLANC N.,et al.Fluorescence spectroscopy to study dissolved organic matter interactions with agrochemicals applied in Swiss vineyards.Environmental Science and Pollution Research,2015,22(12):9284-9292
    [8] WANG Ying,ZHANG Di,SHEN Zhenyao,et al.Investigation of the interaction between As and Sb species and dissolved organic matter in the Yangtze Estuary,China,using excitation-emission matrices with parallel factor analysis.Environmental Science and Pollution Research,2015,22(3):1819-1830
    [9] GUO Liang,LU Mingmin,LI Qianqian,et al.Three-dimensional fluorescence excitation-emission matrix (EEM) spectroscopy with regional integration analysis for assessing waste sludge hydrolysis treated with multi-enzyme and thermophilic bacteria.Bioresource Technology,2014,171:22-28
    [10] 徐慧敏,何国富,象伟宁,等.浓度和离子强度及pH对城市污水3DEEMs特性影响.环境科学与技术,2014,37(9):110-115 XU Huimin,HE Guofu,XIANG Weining,et al.Characteristics study of influent and effluent of municipal wastewater treatment plant by 3DEEM fluorescence spectroscopy:Influences of concentration,ionic strength and pH.Environmental Science & Technology,2014,37(9):110-115(in Chinese)
    [11] ESTEVES DA SILVA J.C.G.,MACHADO A.A.S.C.,OLIVEIRA C.J.S.,et al.Fluorescence quenching of anthropogenic fulvic acids by Cu(II),Fe(III) and UO2+2.Talanta,1998,45(6):1155-1165
    [12] HANRAHAN G.,LU K.Application of factorial and response surface methodology in modern experimental design and optimization.Critical Reviews in Analytical Chemistry,2006,36(3/4):141-151
    [13] FU Haiyan,XU Pengcheng,HUANG Guohe,et al.Effects of aeration parameters on effluent quality and membrane fouling in a submerged membrane bioreactor using Box-Behnken response surface methodology.Desalination,2012,302:33-42
    [14] BAŞ D.,BOYACI İ.H.Modeling and optimization I:Usability of response surface methodology.Journal of Food Engineering,2007,78(3):836-845
    [15] GUO Wanqian,MENG Zhaohui,REN Nanqi,et al.Optimization of key variables for the enhanced production of hydrogen by Ethanoligenens harbinense W1 using response surface methodology.International Journal of Hydrogen Energy,2011,36(10):5843-5848
    [16] 国家环境保护总局.水和废水监测分析方法.4版.北京:中国环境科学出版社,2002
    [17] 施俊,王志刚,肖永辉,等.城市生活污水处理厂进出水三维荧光光谱特征分析.大气与环境光学学报,2012,7(1):31-37 SHI Jun,WANG Zhigang,XIAO Yonghui,et al.Three-dimensional excitation-emission matrix fluorescence spectral characteristics analysis of influent and effluent from urban domestic sewage treatment plant.Journal of Atmospheric and Environmental Optics,2012,7(1):31-37(in Chinese)
    [18] 郝瑞霞,曹可心,邓亦文.城市污水处理过程中有机污染物三维荧光特性的变化规律.分析测试学报,2007,26(6):789-792 HAO Ruixia,CAO Kexin,DENG Yiwen.The variation trend of three-dimensional characteristic fluorescence of dissolved organic matter in the wastewater treatment process.Journal of Instrumental Analysis,2007,26(6):789-792(in Chinese)
    [19] 傅平青,吴丰昌,刘丛强.洱海沉积物间隙水中溶解有机质的地球化学特性.水科学进展,2005,16(3):338-344 FU Pingqing,WU Fengchang,LIU Congqiang.Geochemical characteristics of dissolved organic matter in the sediment pore water of Erhai Lake.Advances in Water Science,2005,16(3):338-344(in Chinese)
    [20] 王新安,郭黎,马爱军,等.基于响应面法分析温度和盐度及其交互作用对大菱鲆幼鱼抗氧化酶活性的影响.海洋科学,2014,38(6):17-23 WANG Xin'an,GUO Li,MA Aijun,et al.Effects of temperature,salinity and their interaction on the activities of antioxidant enzymes of juvenile turbot Scophthalmus maximus based on response surface methodology.Marine Sciences,2014,38(6):17-23(in Chinese)
    [21] 孟瑞军,杨玺萌,李鑫,等.响应曲面优化法合成CTMAB-膨润土吸附剂.环境工程学报,2013,7(7):2517-2522 MENG Ruijun,YANG Ximeng,LI Xin,et al.Preparation of CTMAB-bentonite adsorbent with response surface methodology.Chinese Journal of Environmental Engineering,2013,7(7):2517-2522(in Chinese)
    [22] HENDERSON R.K.,BAKER A.,MURPHY K.R.,et al.Fluorescence as a potential monitoring tool for recycled water systems:A review.Water Research,2009,43(4):863-881
    [23] 傅平青,刘丛强,尹祚莹,等.腐殖酸三维荧光光谱特性研究.地球化学,2004,33(3):301-308 FU Pingqing,LIU Congqiang,YIN Zuoying,et al.Characterization of humic acid by three-dimensional excitation emission matrix fluorescence spectroscopy.Geochimica,2004,33(3):301-308(in Chinese)
    [24] 陈东,刘文清,张玉钧,等.污染水体溶解有机物诱导荧光猝灭特性的实验研究.光谱学与光谱分析,2006,26(12):2283-2286 CHEN Dong,LIU Wenqing,ZHANG Yujun,et al.Experimental investigation on the quenching characters of induced fluorescence of dissolved organic matter in polluted water.Spectroscopy and Spectral Analysis,2006,26(12):2283-2286(in Chinese)
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出版历程
  • 收稿日期:  2015-07-20
  • 刊出日期:  2016-10-20

基于响应曲面法的环境因素对生活污水三维荧光光谱的影响

  • 1. 长江大学化学与环境工程学院, 荆州 434023
  • 收稿日期:  2015-07-20
基金项目:

国家自然科学基金资助项目（21173026）

湖北省自然科学基金重点项目（2013CFA107）

摘要: 采用响应曲面法（RSM）研究温度（10~35℃）、pH（3~11）、稀释倍数（1~10）及交互作用对生活污水溶解性有机物（DOM）三维荧光光谱特性的影响规律。研究表明：生活污水DOM主要含有类色氨酸蛋白质、类酪氨酸蛋白质和类富里酸荧光峰；响应曲面分析表明，温度、pH、稀释倍数其交互作用对于类色氨酸蛋白质荧光强度的影响强弱顺序为：稀释倍数 > pH > 温度、pH-稀释倍数 > 温度-pH > 温度-稀释倍数，其中温度-pH和温度-稀释倍数对其荧光强度的影响为拮抗作用，pH-稀释倍数为协同作用；对于类酪氨酸蛋白质，单因素影响顺序为：pH > 稀释倍数 > 温度，其他情况与类色氨酸蛋白质相似；对于类富里酸，温度、pH、稀释倍数及其交互作用对其影响规律与对类色氨酸蛋白质的相似，但交互作用类型与类色氨酸蛋白质情况相反。

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